**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 126-33-0 |Nitronium tetrafluoroborate, 0.5M solu| | 204-783-1 |
|----------------|--------------------------------------|----------|-----------|
| 13826-86-3 |Nitronium tetrafluoroborate, 0.5M solu| 6.6% | 237-533-5 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns. May cause irreversible eye injury.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Irritation may lead to chemical pneumonitis and pulmonary edema.
Causes chemical burns to the respiratory tract.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Get medical aid immediately. Do NOT induce vomiting. If conscious
and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Do not breathe dust, vapor, mist, or
gas. Do not get in eyes, on skin, or on clothing. Use only in a
chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Keep under a nitrogen blanket. Keep refrigerated. (Store below
4C/39F.)
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower.
Exposure Limits
CAS# 126-33-0:
Russia: 40 mg/m3 TWA
CAS# 13826-86-3:
Personal Protective Equipment
Eyes:
Wear safety glasses and chemical goggles if splashing
is possible.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear a chemical apron.
Respirators:
A NIOSH/MSHA approved air purifying dust or mist
respirator or European Standard EN 149.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: not available
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: may decompose
Specific Gravity/Density: 1.2680g/cm3
Molecular Formula: BF4NO2
Molecular Weight: 132.81
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Exposure to moist air or water.
Incompatibilities with Other Materials:
Moist air or water, strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide,
hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 126-33-0: XN0700000
CAS# 13826-86-3: QX8620000
LD50/LC50:
CAS# 126-33-0: Draize test, rabbit, eye: 253 mg Mild; Oral, mouse:
LD50 = 1900 mg/kg; Oral, rat: LD50 = 1540 uL/kg; Skin, rabbit: LD50 =
3180 uL/kg; Skin, rat: LD50 = >3800 mg/kg.
CAS# 13826-86-3.
Carcinogenicity:
Nitronium tetrafluoroborate, 0.5M solution in sulfolane -
Not listed by ACGIH, IARC, or NTP.
Nitronium tetrafluoroborate, 0.5M solution in sulfolane -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 126-33-0: 1
CAS# 13826-86-3: No information available.
Canada
CAS# 126-33-0 is listed on Canada's DSL List.
CAS# 13826-86-3 is listed on Canada's NDSL List.
CAS# 126-33-0 is not listed on Canada's Ingredient Disclosure List.
CAS# 13826-86-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 126-33-0 is listed on the TSCA inventory.
CAS# 13826-86-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Fast Green FCF (Cert)
| 2353-45-9 |
|
Sodium Tetraborate Decahydrate, Reagent ACS
| 1303-96-4 |
|
Rose bengal (techn), 60% (grav.)
| 632-69-9 |
|
Sodium Tetraborate Decahydrate, P.A.
| 1303-96-4 |
|
n-Phenylglycine, 93%
| 103-01-5 |
|
Sodium Tetraborate Decahydrate, Reagent ACS (Powder)
| 1303-96-4 |
|
n-Tosylpyrrole, 99+%
| 17639-64-4 |
|
Copper (II) Acetate Monohydrate, P.A.
| 6046-93-1 |
|
Copper (II) Acetate Monohydrate, Reagent ACS
| 6046-93-1 |
|
Maleimide, 90-95% (titr.), balance mainly volatiles
| 541-59-3 |
|
d-(+)-Allose
| 2595-97-3 |
|
n-Butyl nitrite, stabilized, 95%
| 544-16-1 |
|
Tridecanal, tech., 90% (gc)
| 10486-19-8 |
|
Tetrabutylammonium hydroxide titrant (0.4m in water), hplc grade
| 2052-49-5 |
|
Tetrabutylammonium hydroxide, 40 wt% solution in water
| 2052-49-5 |
|
Tetrabutylammonium hydroxide, 0.1N solution in toluene/methanol for
| 67-56-1 |
|
Methyl alcohol, 99.9%, spectrophotometric grade
| 67-56-1 |
|
Boron trichloride, 1M solution in hexane
| 110-54-3 |
|
Methyl alcohol, for HPLC
| 67-56-1 |
|
Methyl Alcohol, Dried; Maximum Water Content 0.02%
| 67-56-1 |
|
Methyl alcohol, 99+%
| 67-56-1 |
|
Dodecyl sulfate, lithium salt
| 2044-56-6 |
|
Methyl alcohol, p.a.
| 67-56-1 |
|
Nitronium tetrafluoroborate, 0.5m solution in sulfolane
| 126-33-0 |
|
Dodecyl Sulfate Sodium Salt Electrophoresis Grade, 98% (GC)
| 151-21-3 |
|
Methyl alcohol, reagent ACS, 99.8%, spectrophotometric grade
| 67-56-1 |
|
Methyl alcohol, reagent ACS, 99.8%
| 67-56-1 |
|
Methyl alcohol-d, 99.00 atom % D
| 67-56-1 |
|
Poly(vinyl chloride), carboxylated, average M.W. 200,000, average
| 25702-80-1 |
|
Malachite Green Oxalate, High Purity Biological Stain
| 2437-29-8 |
|
Guanosine, 99% (UV-Vis)
| 118-00-3 |
|
Methyl-d3 alcohol-d, 100.0 atom % D
| 67-56-1 |
|
Methyl-d3 alcohol-d, packaged in 0.50 ml ampules, 100.0 atom % D
| 67-56-1 |
|
Poly(dimethylsiloxane), secondary standard , typical M.W. 93700,
| 9016-00-6 |
|
Poly(dimethylsiloxane), secondary standard typical M.W. 273.500,
| 9016-00-6 |
|
4-Methylphthalic Anhydride, 96% (Titr.)
| 19438-61-0 |
|
2-Undecanone, 97.5% (GC)
| 112-12-9 |
|
Isonicotinic Acid Hydrazide, 99%
| 54-85-3 |
|
Triethyl phosphonoacetate, 98.5% (gc)
| 867-13-0 |
|
Trans-1,4-Cyclohexanedimethanol, 98% (GC)
| 105-08-8 |
|
l-Threo-tert-butylserine monohydrate
| |
|
Poly(isobutylene), approximate MW 840,000
| 9003-27-4 |
|
Poly(isobutylene), approximate MW 900,000
| 9003-27-4 |
|
Terephthaldehyde monodiethylacetal, 97% stabilized with 0.1%
| 121-44-8 |
|
Tyramine hydrochloride, >99% (titr.)
| 60-19-5 |
|
Poly(isobutylene), approximate MW 1,400,000
| 9003-27-4 |
|
Poly(isobutylene), approximate MW 4,700,000
| 9003-27-4 |
|
p-Morpholinoaniline, 97.3%
| 2524-67-6 |
|
6-Methoxy-2-tetralone, 95%
| 2472-22-2 |
|
D-Methionine Methylsulfonium Bromide, 99%
| |
|
|