**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 2437-29-8 |Malachite Green Oxalate | 100.0 | 219-441-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes, respiratory system and
skin.Toxic.
Potential Health Effects
Eye:
Causes eye irritation. This product contains a cationic dye.
Similar dyes have caused permanent injury to the cornea and
conjunctiva in documented exposure cases with human or rabbit eyes.
May cause chemical conjunctivitis.
Skin:
Causes skin irritation. Prolonged and/or repeated contact may cause
irritation and/or dermatitis.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated. Can produce delayed
pulmonary edema.
Chronic:
May cause fetal effects. Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. SPEEDY ACTION IS CRITICAL!
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting
unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Wash area with soap and water. Clean up spills immediately,
observing precautions in the Protective Equipment section. Sweep up,
then place into a suitable container for disposal. Avoid generating
dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Avoid contact with eyes, skin, and clothing. Keep
container tightly closed. Avoid ingestion and inhalation. Use with
adequate ventilation. Wash clothing before reuse.
Storage:
Keep from contact with oxidizing materials. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 2437-29-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant a respirator's use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: green
Odor: None reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 164 deg C
Solubility in water: Soluble in water.
Specific Gravity/Density: Not available.
Molecular Formula: C52H54N4O12
Molecular Weight: 926.3976
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
High temperatures, incompatible materials, dust generation, excess
heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 2437-29-8: BQ1190000
LD50/LC50:
CAS# 2437-29-8: Draize test, rabbit, eye: 76 mg Severe; Oral, rat:
LD50 = 275 mg/kg.
Carcinogenicity:
Malachite Green Oxalate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28 After contact with skin, wash immediately
with...
WGK (Water Danger/Protection)
CAS# 2437-29-8: 3
Canada
CAS# 2437-29-8 is listed on Canada's DSL List.
CAS# 2437-29-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2437-29-8 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/15/1999 Revision #2 Date: 12/03/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Fast Green FCF (Cert)
| 2353-45-9 |
|
Sodium Tetraborate Decahydrate, Reagent ACS
| 1303-96-4 |
|
Rose bengal (techn), 60% (grav.)
| 632-69-9 |
|
Sodium Tetraborate Decahydrate, P.A.
| 1303-96-4 |
|
n-Phenylglycine, 93%
| 103-01-5 |
|
Sodium Tetraborate Decahydrate, Reagent ACS (Powder)
| 1303-96-4 |
|
n-Tosylpyrrole, 99+%
| 17639-64-4 |
|
Copper (II) Acetate Monohydrate, P.A.
| 6046-93-1 |
|
Copper (II) Acetate Monohydrate, Reagent ACS
| 6046-93-1 |
|
Maleimide, 90-95% (titr.), balance mainly volatiles
| 541-59-3 |
|
d-(+)-Allose
| 2595-97-3 |
|
n-Butyl nitrite, stabilized, 95%
| 544-16-1 |
|
Tridecanal, tech., 90% (gc)
| 10486-19-8 |
|
Tetrabutylammonium hydroxide titrant (0.4m in water), hplc grade
| 2052-49-5 |
|
Tetrabutylammonium hydroxide, 40 wt% solution in water
| 2052-49-5 |
|
Tetrabutylammonium hydroxide, 0.1N solution in toluene/methanol for
| 67-56-1 |
|
Methyl alcohol, 99.9%, spectrophotometric grade
| 67-56-1 |
|
Boron trichloride, 1M solution in hexane
| 110-54-3 |
|
Methyl alcohol, for HPLC
| 67-56-1 |
|
Methyl Alcohol, Dried; Maximum Water Content 0.02%
| 67-56-1 |
|
Methyl alcohol, 99+%
| 67-56-1 |
|
Dodecyl sulfate, lithium salt
| 2044-56-6 |
|
Methyl alcohol, p.a.
| 67-56-1 |
|
Nitronium tetrafluoroborate, 0.5m solution in sulfolane
| 126-33-0 |
|
Dodecyl Sulfate Sodium Salt Electrophoresis Grade, 98% (GC)
| 151-21-3 |
|
Methyl alcohol, reagent ACS, 99.8%, spectrophotometric grade
| 67-56-1 |
|
Methyl alcohol, reagent ACS, 99.8%
| 67-56-1 |
|
Methyl alcohol-d, 99.00 atom % D
| 67-56-1 |
|
Poly(vinyl chloride), carboxylated, average M.W. 200,000, average
| 25702-80-1 |
|
Malachite Green Oxalate, High Purity Biological Stain
| 2437-29-8 |
|
Guanosine, 99% (UV-Vis)
| 118-00-3 |
|
Methyl-d3 alcohol-d, 100.0 atom % D
| 67-56-1 |
|
Methyl-d3 alcohol-d, packaged in 0.50 ml ampules, 100.0 atom % D
| 67-56-1 |
|
Poly(dimethylsiloxane), secondary standard , typical M.W. 93700,
| 9016-00-6 |
|
Poly(dimethylsiloxane), secondary standard typical M.W. 273.500,
| 9016-00-6 |
|
4-Methylphthalic Anhydride, 96% (Titr.)
| 19438-61-0 |
|
2-Undecanone, 97.5% (GC)
| 112-12-9 |
|
Isonicotinic Acid Hydrazide, 99%
| 54-85-3 |
|
Triethyl phosphonoacetate, 98.5% (gc)
| 867-13-0 |
|
Trans-1,4-Cyclohexanedimethanol, 98% (GC)
| 105-08-8 |
|
l-Threo-tert-butylserine monohydrate
| |
|
Poly(isobutylene), approximate MW 840,000
| 9003-27-4 |
|
Poly(isobutylene), approximate MW 900,000
| 9003-27-4 |
|
Terephthaldehyde monodiethylacetal, 97% stabilized with 0.1%
| 121-44-8 |
|
Tyramine hydrochloride, >99% (titr.)
| 60-19-5 |
|
Poly(isobutylene), approximate MW 1,400,000
| 9003-27-4 |
|
Poly(isobutylene), approximate MW 4,700,000
| 9003-27-4 |
|
p-Morpholinoaniline, 97.3%
| 2524-67-6 |
|
6-Methoxy-2-tetralone, 95%
| 2472-22-2 |
|
D-Methionine Methylsulfonium Bromide, 99%
| |
|
|