**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1271-19-8 |Bis(cyclopentadienyl)titanium dichlori| 97% | 215-035-9 |
| |de, 97% | | |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Use with
adequate ventilation. Avoid breathing dust, vapor, mist, or gas.
Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 1271-19-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: red to brown
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 289 - 291 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: slightly soluble
Specific Gravity/Density:
Molecular Formula: C10H10Cl2Ti
Molecular Weight: 249.00
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, moist air or water.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide, titanium/titanium
oxides.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1271-19-8: XR2050000
LD50/LC50:
Not available.
Carcinogenicity:
Bis(cyclopentadienyl)titanium dichloride, 97% -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 1271-19-8: No information available.
Canada
CAS# 1271-19-8 is listed on Canada's NDSL List.
CAS# 1271-19-8 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1271-19-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,2,2-Trichloro-1-ethoxyethanol
| 515-83-3 |
|
1,8-Nonadiyne, 98%
| 2396-65-8 |
|
Silver benzoate, 99%
| 532-31-0 |
|
1,8-Dichlorooctane, 98%
| 2162-99-4 |
|
Isoamylbutyrate 99+ %
| 106-27-4 |
|
Cis-4-Heptenal, 96+%
| 6728-31-0 |
|
Lithium tetrafluoroborate, anhydrous, 98%
| 14283-07-9 |
|
2'-Hydroxy-5'-methylacetophenone, 98%
| 1450-72-2 |
|
Aza-18-Crown-6, 98%
| 33941-15-0 |
|
Diphenylamine Sulfate, 98% (UV-Vis)
| 587-84-8 |
|
Indole-5-Carboxylic Acid, 98%
| 1670-81-1 |
|
Phenylmercuric Acetate, 98.0-100.5% (Titr)
| 62-38-4 |
|
Strontium Atomic Absorption Standard Solution, 1 mg/ml Sr in 2% HCl
| 1633-05-2 |
|
(6s,2z)-6,7-isopropylidenedioxy-3,7-dimeth yl-2-octen-1-ol, 97%
| 61262-96-2 |
|
Imidurea, 26-28% nitrogen
| 39236-46-9 |
|
bis(Cyclopentadienyl)titanium dichloride, 97%
| 1271-19-8 |
|
P-Tert.-Butylbenzyl Alcohol, 98%
| 877-65-6 |
|
Tungsten atomic absorption standard solution, 1 mg/ml W in 5% HF
| 7440-33-7 |
|
2-Chloroacrylonitrile, 99%, stabilized with ca 500 ppm hydroquinone
| 123-31-9 |
|
1,2-Diaminopropane-N,N,N',N'-Tetraacetic Acid, 98+%
| 4408-81-5 |
|
4-Chloro-2-Methylanisole, 99%
| 3260-85-3 |
|
1-Bromo-4-chlorobutane, 99% (gc)
| 6940-78-9 |
|
Diethyl Sulfite, 98%
| 623-81-4 |
|
3-Bromochlorobenzene, 99%
| 108-37-2 |
|
3-Methyl-2-Phenylpyridine, 97+%
| 10273-90-2 |
|
2-(4-Biphenylyl)-6-phenylbenzoxazole, scintillation grade
| 17064-47-0 |
|
Piperidineacetonitrile
| 3010-03-5 |
|
3,5-Dinitrobenzoyl Chloride
| 99-33-2 |
|
3-Quinolinecarboxylic acid, 98%
| 6480-68-8 |
|
4-Sulfophthalic Acid (Pract) (50% in Water)
| 89-08-7 |
|
Triethyl orthoformate, 99+% (gc)
| 122-51-0 |
|
Tri-O-Tolylphosphine
| 6163-58-2 |
|
4-Bromophenylboric acid/anhydride
| 5467-74-3 |
|
Cis-3,3,5-Trimethylcyclohexanol, 98+% Cis
| 933-48-2 |
|
3-Phenylpropyl isobutyrate, 98+%
| 103-58-2 |
|
6-Thio-2-hydroxypurine, 98%
| 0-01-1 |
|
4-(Diethylaminomethyl)-2,5-dimethylphenol, 98%
| 69286-57-3 |
|
2-Fluorophenyl isocyanate
| 16744-98-2 |
|
4-Chloro-2-Phenylquinazoline 97%
| 6484-25-9 |
|
Tristearin
| 555-43-1 |
|
Rhodamine 116 Perchlorate, Laser Grade
| 62669-77-6 |
|
d-(-)-Norvaline, 99%
| 2013-12-9 |
|
Cobalt Tetramethoxyphenylporphyrin, 94% (Titr.)
| 28903-71-1 |
|
Biurea, 99% (EX N)
| 110-21-4 |
|
3-Methyl-2-nitrobenzoic acid, 98%
| 5437-38-7 |
|
2-Chloro-1,4-dimethoxybenzene, 99+%
| 2100-42-7 |
|
4-Bromo-2-fluorobenzaldehyde, 96%
| |
|
Cyanuric acid, 98%
| 108-80-5 |
|
LITHIUM TETRAPHENYLBORATE
| 14485-20-2 |
|
4-Quinolinecarboxaldehyde, 95%
| 4363-93-3 |
|
|