**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 99-33-2 |Benzoyl chloride, 3,5-dinitro- | 99 | 202-750-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns. Lachrymator (substance which increases the flow of tears).
Skin:
Exposure may cause irritation and possible burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema. Causes chemical burns to the respiratory tract.
Inhalation may be fatal as a result of spasm, inflammation, edema of
the larynx and bronchi, chemical pneumonitis and pulmonary edema.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use of
water will produce irritating and toxic vapors of hydrogen chloride.
Hydrochloric acid solutions react with most metals, forming flammable
hydrogen gas.
Extinguishing Media:
Use carbon dioxide or dry chemical. DO NOT USE WATER!
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Do not get in eyes,
on skin, or on clothing. Do not ingest or inhale.
Storage:
Store in a cool, dry place. Corrosives area. Store protected from
moisture. Storage under inert gas has been recommended.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use process enclosure,
local exhaust ventilation, or other engineering controls to control
airborne levels.
Exposure Limits
CAS# 99-33-2:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles. Wear appropriate
protective eyeglasses or chemical safety goggles as
described by OSHA's eye and face protection
regulations in 29 CFR 1910.133 or European Standard
EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use. Follow the OSHA
respirator regulations found in 29 CFR 1910.134 or
European Standard EN 149. Use a NIOSH/MSHA or
European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or
other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: yellow
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 196 deg C @ 11 mm Hg
Freezing/Melting Point: 67-70 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Reacts with water.
Specific Gravity/Density: Not available.
Molecular Formula: C7H3ClN2O5
Molecular Weight: 230.56
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Material hydrolyzes
in contact with moisture/water releasing toxic and corrosive fumes
of hydrogen chloride and aqueous hydrochloric acid.
Conditions to Avoid:
Mechanical shock, dust generation, excess heat, exposure to moist air
or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Phosgene, carbon monoxide, oxides of nitrogen, carbon dioxide,
hydrogen gas.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 99-33-2: DM6637000
LD50/LC50:
Not available.
Carcinogenicity:
Benzoyl chloride, 3,5-dinitro- -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3261
Packing Group: II
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 99-33-2: No information available.
Canada
CAS# 99-33-2 is listed on Canada's DSL List.
CAS# 99-33-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 99-33-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/30/1999 Revision #3 Date: 9/30/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
| ALL MSDS PAGES IN THIS GROUP
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|
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|
Isoamylbutyrate 99+ %
| 106-27-4 |
|
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| 6728-31-0 |
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| 1450-72-2 |
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| 33941-15-0 |
|
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| 1670-81-1 |
|
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|
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| 1633-05-2 |
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| 39236-46-9 |
|
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| 1271-19-8 |
|
P-Tert.-Butylbenzyl Alcohol, 98%
| 877-65-6 |
|
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| 7440-33-7 |
|
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| 123-31-9 |
|
1,2-Diaminopropane-N,N,N',N'-Tetraacetic Acid, 98+%
| 4408-81-5 |
|
4-Chloro-2-Methylanisole, 99%
| 3260-85-3 |
|
1-Bromo-4-chlorobutane, 99% (gc)
| 6940-78-9 |
|
Diethyl Sulfite, 98%
| 623-81-4 |
|
3-Bromochlorobenzene, 99%
| 108-37-2 |
|
3-Methyl-2-Phenylpyridine, 97+%
| 10273-90-2 |
|
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| 17064-47-0 |
|
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| 3010-03-5 |
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| 99-33-2 |
|
3-Quinolinecarboxylic acid, 98%
| 6480-68-8 |
|
4-Sulfophthalic Acid (Pract) (50% in Water)
| 89-08-7 |
|
Triethyl orthoformate, 99+% (gc)
| 122-51-0 |
|
Tri-O-Tolylphosphine
| 6163-58-2 |
|
4-Bromophenylboric acid/anhydride
| 5467-74-3 |
|
Cis-3,3,5-Trimethylcyclohexanol, 98+% Cis
| 933-48-2 |
|
3-Phenylpropyl isobutyrate, 98+%
| 103-58-2 |
|
6-Thio-2-hydroxypurine, 98%
| 0-01-1 |
|
4-(Diethylaminomethyl)-2,5-dimethylphenol, 98%
| 69286-57-3 |
|
2-Fluorophenyl isocyanate
| 16744-98-2 |
|
4-Chloro-2-Phenylquinazoline 97%
| 6484-25-9 |
|
Tristearin
| 555-43-1 |
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| 62669-77-6 |
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| 28903-71-1 |
|
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| 110-21-4 |
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| 5437-38-7 |
|
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| 2100-42-7 |
|
4-Bromo-2-fluorobenzaldehyde, 96%
| |
|
Cyanuric acid, 98%
| 108-80-5 |
|
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| 14485-20-2 |
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4-Quinolinecarboxaldehyde, 95%
| 4363-93-3 |
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|