**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 89-08-7 |1,2-Benzenedicarboxylic Acid, 4-Sulfo-| 50 | 201-881-6 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 50 | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.The toxicological properties of this material
have not been fully investigated.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. The toxicological properties of this
substance have not been fully investigated.
Inhalation:
Causes chemical burns to the respiratory tract. The toxicological
properties of this substance have not been fully investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid. Do NOT allow victim to rub eyes or keep eyes
closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Use extinguishing media
appropriate to the surrounding fire. Substance is noncombustible.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire. Use water spray, dry chemical, carbon
dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Keep container tightly closed. Do not
ingest or inhale. Discard contaminated shoes.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 89-08-7:
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: light orange
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: None.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.2950g/cm3
Molecular Formula: C8H6O7S
Molecular Weight: 246.20
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, iron, iron salts.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, sulfur oxides (SOx), including sulfur oxide and sulfur
dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 89-08-7 unlisted.
CAS# 7732-18-5: ZC0110000
LD50/LC50:
Not available.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
1,2-Benzenedicarboxylic Acid, 4-Sulfo- -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3265
Packing Group: III
IMO
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 28 After contact with skin, wash immediately
with...
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 89-08-7: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 89-08-7 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 89-08-7 is not listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 89-08-7 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 5/24/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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| 515-83-3 |
|
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| 2396-65-8 |
|
Silver benzoate, 99%
| 532-31-0 |
|
1,8-Dichlorooctane, 98%
| 2162-99-4 |
|
Isoamylbutyrate 99+ %
| 106-27-4 |
|
Cis-4-Heptenal, 96+%
| 6728-31-0 |
|
Lithium tetrafluoroborate, anhydrous, 98%
| 14283-07-9 |
|
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| 1450-72-2 |
|
Aza-18-Crown-6, 98%
| 33941-15-0 |
|
Diphenylamine Sulfate, 98% (UV-Vis)
| 587-84-8 |
|
Indole-5-Carboxylic Acid, 98%
| 1670-81-1 |
|
Phenylmercuric Acetate, 98.0-100.5% (Titr)
| 62-38-4 |
|
Strontium Atomic Absorption Standard Solution, 1 mg/ml Sr in 2% HCl
| 1633-05-2 |
|
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| 61262-96-2 |
|
Imidurea, 26-28% nitrogen
| 39236-46-9 |
|
bis(Cyclopentadienyl)titanium dichloride, 97%
| 1271-19-8 |
|
P-Tert.-Butylbenzyl Alcohol, 98%
| 877-65-6 |
|
Tungsten atomic absorption standard solution, 1 mg/ml W in 5% HF
| 7440-33-7 |
|
2-Chloroacrylonitrile, 99%, stabilized with ca 500 ppm hydroquinone
| 123-31-9 |
|
1,2-Diaminopropane-N,N,N',N'-Tetraacetic Acid, 98+%
| 4408-81-5 |
|
4-Chloro-2-Methylanisole, 99%
| 3260-85-3 |
|
1-Bromo-4-chlorobutane, 99% (gc)
| 6940-78-9 |
|
Diethyl Sulfite, 98%
| 623-81-4 |
|
3-Bromochlorobenzene, 99%
| 108-37-2 |
|
3-Methyl-2-Phenylpyridine, 97+%
| 10273-90-2 |
|
2-(4-Biphenylyl)-6-phenylbenzoxazole, scintillation grade
| 17064-47-0 |
|
Piperidineacetonitrile
| 3010-03-5 |
|
3,5-Dinitrobenzoyl Chloride
| 99-33-2 |
|
3-Quinolinecarboxylic acid, 98%
| 6480-68-8 |
|
4-Sulfophthalic Acid (Pract) (50% in Water)
| 89-08-7 |
|
Triethyl orthoformate, 99+% (gc)
| 122-51-0 |
|
Tri-O-Tolylphosphine
| 6163-58-2 |
|
4-Bromophenylboric acid/anhydride
| 5467-74-3 |
|
Cis-3,3,5-Trimethylcyclohexanol, 98+% Cis
| 933-48-2 |
|
3-Phenylpropyl isobutyrate, 98+%
| 103-58-2 |
|
6-Thio-2-hydroxypurine, 98%
| 0-01-1 |
|
4-(Diethylaminomethyl)-2,5-dimethylphenol, 98%
| 69286-57-3 |
|
2-Fluorophenyl isocyanate
| 16744-98-2 |
|
4-Chloro-2-Phenylquinazoline 97%
| 6484-25-9 |
|
Tristearin
| 555-43-1 |
|
Rhodamine 116 Perchlorate, Laser Grade
| 62669-77-6 |
|
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| 2013-12-9 |
|
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| 28903-71-1 |
|
Biurea, 99% (EX N)
| 110-21-4 |
|
3-Methyl-2-nitrobenzoic acid, 98%
| 5437-38-7 |
|
2-Chloro-1,4-dimethoxybenzene, 99+%
| 2100-42-7 |
|
4-Bromo-2-fluorobenzaldehyde, 96%
| |
|
Cyanuric acid, 98%
| 108-80-5 |
|
LITHIUM TETRAPHENYLBORATE
| 14485-20-2 |
|
4-Quinolinecarboxaldehyde, 95%
| 4363-93-3 |
|
|