**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1317-38-0 |COPPER (II) OXIDE | 99.999 | 215-269-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed.
Potential Health Effects
Eye:
Causes eye irritation. May result in corneal injury. May cause
conjunctivitis.
Skin:
Causes skin irritation. May cause skin discoloration.
Ingestion:
May cause central nervous system depression, kidney damage, and
liver damage. May cause gastrointestinal irritation with nausea,
vomiting and diarrhea. May cause circulatory system failure. May
cause vascular collapse and damage.
Inhalation:
Causes respiratory tract irritation. May cause ulceration and
perforation of the nasal septum if inhaled in excessive quantities.
Inhalation of fumes may cause metal fume fever, which is
characterized by flu-like symptoms with metallic taste, fever,
chills, cough, weakness, chest pain, muscle pain and increased white
blood cell count.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Individuals
with Wilson's disease are unable to metabolize copper. Thus, copper
accumulates in various tissues and may result in liver, kidney, and
brain damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Antidote:
The use of d-Penicillamine as a chelating agent should be determined
by qualified medical personnel.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use
extinguishing media appropriate to the surrounding fire. Substance is
noncombustible.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with skin
and eyes. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 1317-38-0:
United Kingdom, WEL - TWA: (listed as copper): 0.2 mg/m3 TWA (fum
1 mg/m3 TWA (dust and mist)
United Kingdom, WEL - STEL: (listed as copper): 0.6 mg/m3 STEL
(fume); 2 mg/m3 STEL (dust and mist)
United States OSHA: 0.1 mg/m3 TWA (fume); 1 mg/m3 TWA (dusts and
mists) (listed under Copper).
Belgium - TWA: (listed as copper): 0.2 mg/m3 VLE (fume); 1 mg/m3
(dust and mist)
France - VME: (listed as copper): 0.2 mg/m3 VME (fume); 1 mg/m3 V
(dust, as Cu)
France - VLE: (listed as copper): 2 mg/m3 VLE (dust, as Cu)
Germany: (listed as copper): 0.2 mg/m3 VME (fume); 1 mg/m3 VME (d
as Cu)
Malaysia: (listed as copper): 0.2 mg/m3 TWA (fume, as Cu); 1 mg/m
TWA (dust and mist, as Cu)
Netherlands: (listed as copper): 0.2 mg/m3 MAC (smoke); 1 mg/m3 M
(dust)
Russia: (listed as copper): 1 mg/m3 TWA (dust)
Russia: (listed as copper): 0.5 mg/m3 STEL (dust)
Spain: (listed as copper): 0.2 mg/m3 VLA-ED (fume); 1 mg/m3 VLA-E
(dust and mist, as Cu)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: black to brown black
Odor: odorless
pH: Not available.
Vapor Pressure: Not applicable.
Viscosity: Not applicable.
Boiling Point: Not available.
Freezing/Melting Point: 1326 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Insoluble in water
Specific Gravity/Density: 6.3-6.5
Molecular Formula: CuO
Molecular Weight: 79.5454
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, moisture, temperatures above 100C.
Incompatibilities with Other Materials:
Aluminum, boron, cesium acetylene carbide, hydrazine, magnesium,
phospham, potassium, rubidium acetylene carbide, sodium, titanium,
and zirconium. Forms explosive acetylides with acetylene in caustic
solutions. Exposure to moist air at > 212F can result in spontaneous
combustion.
Hazardous Decomposition Products:
Copper fumes.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1317-38-0: GL7900000
LD50/LC50:
CAS# 1317-38-0: Oral, rat: LD50 = 470 mg/kg.
Carcinogenicity:
COPPER (II) OXIDE -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 1317-38-0: 0
Canada
CAS# 1317-38-0 is listed on Canada's DSL List.
CAS# 1317-38-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1317-38-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
4-Hydroxybenzophenone, 99+%
| 1137-42-4 |
|
Chlorobenzene, 99+%
| 108-90-7 |
|
Chlorobenzene, Reagent ACS, 99.5% (GC)
| 108-90-7 |
|
Chloroform, preserved with 0.75% Ethanol
| 64-17-5 |
|
Chloroform, Reagent ACS, 99.8% (GC)
| 67-66-3 |
|
2-Amino-6-Methoxybenzothiazole, Tech.
| 1747-60-0 |
|
Cholesterol, 95%
| 57-88-5 |
|
Choline Chloride, 99%
| 67-48-1 |
|
Chromium(VI) oxide, flakes, 99+%
| 1333-82-0 |
|
N,N-Dimethylindoaniline (Pract), 78% (UV-Vis)
| 2150-58-5 |
|
Chromium(VI) oxide, reagent ACS, 98+%
| 1333-82-0 |
|
Methylene violet (bernthsen), high purity biological stain
| 2516-05-4 |
|
3-Dimethylaminopropylamine, 99%
| 109-55-7 |
|
Cobalt (II) Nitrate Hexahydrate, 99%
| 10026-22-9 |
|
Cobalt(II) Nitrate, Hexahydrate, Reagent ACS (Crystals)
| 10026-22-9 |
|
D(+)-trehalose dihydrate min. 99% (hplc)
| 6138-23-4 |
|
Cobalt(II) chloride hexahydrate, p.a.
| 7791-13-1 |
|
Cobalt(II) chloride, hexahydrate, reagent ACS
| 7791-13-1 |
|
Copper, 99%, -45 Micron Powder
| 7440-50-8 |
|
Cupferron, P.A.
| 135-20-6 |
|
Copper (II) Oxide, 99.999%
| 1317-38-0 |
|
Copper (II) Oxide, P.A.
| 1317-38-0 |
|
Copper (II) Oxide, Black, Reagent ACS (Powder)
| 1317-38-0 |
|
Copper(II) sulfate, anhydrous, p.a.
| 7758-98-7 |
|
Beta-Apo-Oxytetracycline,"Can be Used as Secondary Standard"
| 18751-99-0 |
|
Tolylene-2,4-Diisocyanate, Tech., 80%
| 584-84-9 |
|
Copper(II) sulfate pentahydrate, p.a.
| 7758-98-7 |
|
Copper(II) sulfate pentahydrate, reagent ACS
| 7758-98-7 |
|
N,N'-Di-N-Butylthiourea, 99%
| 109-46-6 |
|
5-Aminosalicylic Acid, 95%
| 89-57-6 |
|
Butyl Benzoate, 98%
| 136-60-7 |
|
Dl-sec-phenethyl alcohol, 99+%
| 98-85-1 |
|
D-(-)-Fructose, 98%
| 57-48-7 |
|
D-Sorbitol, 97%
| 50-70-4 |
|
Decahydronaphthalene, mixture of cis and trans, 98%
| 91-17-8 |
|
2,6-Di-tert-butyl-4-methylphenol, 99%
| 128-37-0 |
|
2-Aminothiophenol, 98% (GC)
| 137-07-5 |
|
2-Methyl-beta-naphthothiazole, 98%
| 2682-45-3 |
|
Di-n-butylamine 99%
| 111-92-2 |
|
tert-Butyl bromoacetate, 99%
| 5292-43-3 |
|
1,4-Dimethoxybenzene, 99+%
| 150-78-7 |
|
5-Chloro-2-Methylbenzoxazole, 99+% (GC)
| 19219-99-9 |
|
Ammonium oxalate, monohydrate, p.a.
| 1113-38-8 |
|
L-Lactic Acid, 20 Wt. % Solution in Water
| 79-33-4 |
|
Benzenesulfonic acid, tech., 90%
| 98-11-3 |
|
Molybdic acid p.a.
| 7782-91-4 |
|
Poly(phenylene sulfide) nominal m.w. 10000 ,powder
| 9016-75-5 |
|
2-Pyrrolidinone, 98%
| 616-45-5 |
|
Ethyl Caprate, 99+%
| 110-38-3 |
|
2,4-Dihydroxybenzoic acid, 97%
| 89-86-1 |
|
|