**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 616-45-5 |2-Pyrrolidinone | 98% | 210-483-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 36/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes and skin.Hygroscopic
(absorbs moisture from the air).The toxicological properties of this
material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
May cause cardiac disturbances. The toxicological properties of this
substance have not been fully investigated. May cause central
nervous system depression.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. May cause cardiac
abnormalities. Inhalation at high concentrations may cause CNS
depression and asphixiation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined
areas. Containers may explode when heated. Combustible material; may
burn but does not ignite readily. Runoff from fire control or
dilution water may cause pollution.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Do NOT get water
inside containers. For small fires, use dry chemical, carbon
dioxide, or water spray. For large fires, use dry chemical, carbon
dioxide, alcohol-resistant foam, or water spray.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Keep container tightly closed. Avoid
ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 616-45-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: 13.3 cP 25.00 deg
Boiling Point: 245 deg C @ 760.00mmHg
Freezing/Melting Point: 23.00 - 25.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: 138 deg C ( 280.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: miscible
Specific Gravity/Density: 1.1200g/cm3
Molecular Formula: C4H7NO
Molecular Weight: 85.11
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Strong acids, strong bases, strong oxidizing agents, strong reducing
agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 616-45-5: UY5715000
LD50/LC50:
CAS# 616-45-5: Oral, rat: LD50 = 328 mg/kg.
Carcinogenicity:
2-Pyrrolidinone -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 616-45-5: 1
Canada
CAS# 616-45-5 is listed on Canada's DSL List.
CAS# 616-45-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 616-45-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
4-Hydroxybenzophenone, 99+%
| 1137-42-4 |
|
Chlorobenzene, 99+%
| 108-90-7 |
|
Chlorobenzene, Reagent ACS, 99.5% (GC)
| 108-90-7 |
|
Chloroform, preserved with 0.75% Ethanol
| 64-17-5 |
|
Chloroform, Reagent ACS, 99.8% (GC)
| 67-66-3 |
|
2-Amino-6-Methoxybenzothiazole, Tech.
| 1747-60-0 |
|
Cholesterol, 95%
| 57-88-5 |
|
Choline Chloride, 99%
| 67-48-1 |
|
Chromium(VI) oxide, flakes, 99+%
| 1333-82-0 |
|
N,N-Dimethylindoaniline (Pract), 78% (UV-Vis)
| 2150-58-5 |
|
Chromium(VI) oxide, reagent ACS, 98+%
| 1333-82-0 |
|
Methylene violet (bernthsen), high purity biological stain
| 2516-05-4 |
|
3-Dimethylaminopropylamine, 99%
| 109-55-7 |
|
Cobalt (II) Nitrate Hexahydrate, 99%
| 10026-22-9 |
|
Cobalt(II) Nitrate, Hexahydrate, Reagent ACS (Crystals)
| 10026-22-9 |
|
D(+)-trehalose dihydrate min. 99% (hplc)
| 6138-23-4 |
|
Cobalt(II) chloride hexahydrate, p.a.
| 7791-13-1 |
|
Cobalt(II) chloride, hexahydrate, reagent ACS
| 7791-13-1 |
|
Copper, 99%, -45 Micron Powder
| 7440-50-8 |
|
Cupferron, P.A.
| 135-20-6 |
|
Copper (II) Oxide, 99.999%
| 1317-38-0 |
|
Copper (II) Oxide, P.A.
| 1317-38-0 |
|
Copper (II) Oxide, Black, Reagent ACS (Powder)
| 1317-38-0 |
|
Copper(II) sulfate, anhydrous, p.a.
| 7758-98-7 |
|
Beta-Apo-Oxytetracycline,"Can be Used as Secondary Standard"
| 18751-99-0 |
|
Tolylene-2,4-Diisocyanate, Tech., 80%
| 584-84-9 |
|
Copper(II) sulfate pentahydrate, p.a.
| 7758-98-7 |
|
Copper(II) sulfate pentahydrate, reagent ACS
| 7758-98-7 |
|
N,N'-Di-N-Butylthiourea, 99%
| 109-46-6 |
|
5-Aminosalicylic Acid, 95%
| 89-57-6 |
|
Butyl Benzoate, 98%
| 136-60-7 |
|
Dl-sec-phenethyl alcohol, 99+%
| 98-85-1 |
|
D-(-)-Fructose, 98%
| 57-48-7 |
|
D-Sorbitol, 97%
| 50-70-4 |
|
Decahydronaphthalene, mixture of cis and trans, 98%
| 91-17-8 |
|
2,6-Di-tert-butyl-4-methylphenol, 99%
| 128-37-0 |
|
2-Aminothiophenol, 98% (GC)
| 137-07-5 |
|
2-Methyl-beta-naphthothiazole, 98%
| 2682-45-3 |
|
Di-n-butylamine 99%
| 111-92-2 |
|
tert-Butyl bromoacetate, 99%
| 5292-43-3 |
|
1,4-Dimethoxybenzene, 99+%
| 150-78-7 |
|
5-Chloro-2-Methylbenzoxazole, 99+% (GC)
| 19219-99-9 |
|
Ammonium oxalate, monohydrate, p.a.
| 1113-38-8 |
|
L-Lactic Acid, 20 Wt. % Solution in Water
| 79-33-4 |
|
Benzenesulfonic acid, tech., 90%
| 98-11-3 |
|
Molybdic acid p.a.
| 7782-91-4 |
|
Poly(phenylene sulfide) nominal m.w. 10000 ,powder
| 9016-75-5 |
|
2-Pyrrolidinone, 98%
| 616-45-5 |
|
Ethyl Caprate, 99+%
| 110-38-3 |
|
2,4-Dihydroxybenzoic acid, 97%
| 89-86-1 |
|
|