**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7440-50-8 |COPPER | 100 | 231-159-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Air sensitive.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May cause skin discoloration.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause liver and kidney damage.
Inhalation:
Dust is irritating to the respiratory tract. Inhalation of fumes may
cause metal fume fever, which is characterized by flu-like symptoms
with metallic taste, fever, chills, cough, weakness, chest pain,
muscle pain and increased white blood cell count.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. May cause
liver and kidney damage. May cause lung damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting
unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Individuals with Wilson's disease are more susceptible to chronic
copper poisoning.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Material can spontaneously ignite (pyrophoric) when
exposed to air at normal or slightly elevated temperatures.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use with adequate ventilation. Minimize dust generation and
accumulation. Avoid contact with skin and eyes. Keep container
tightly closed. Avoid ingestion and inhalation. Wash clothing before
reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Do not expose
to air.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 7440-50-8:
United Kingdom, WEL - TWA: 0.2 mg/m3 TWA (fume); 1 mg/m3 TWA (dus
and mist)
United Kingdom, WEL - STEL: 0.6 mg/m3 STEL (fume); 2 mg/m3 STEL (
and mist)
United States OSHA: 0.1 mg/m3 TWA (fume); 1 mg/m3 TWA (dusts and
mists)
Belgium - TWA: 0.2 mg/m3 VLE (fume); 1 mg/m3 VLE (dust and mist)
France - VME: 0.2 mg/m3 VME (fume); 1 mg/m3 VME (dust, as Cu)
France - VLE: 2 mg/m3 VLE (dust, as Cu)
Germany: 1 mg/m3 TWA (inhalable fraction); 0.1 mg/m3 TWA (respira
fraction, smoke)
Malaysia: 0.2 mg/m3 TWA (fume, as Cu); 1 mg/m3 TWA (dust and mist
Cu)
Netherlands: 0.2 mg/m3 MAC (smoke); 1 mg/m3 MAC (dust)
Russia: 1 mg/m3 TWA (dust)
Russia: 0.5 mg/m3 STEL (dust)
Spain: 0.2 mg/m3 VLA-ED (fume); 1 mg/m3 VLA-ED (dust and mist, as
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: crimson to reddish brown
Odor: Not available.
pH: Not available.
Vapor Pressure: 1 mm Hg @1628C
Viscosity: Not available.
Boiling Point: 2595 deg C @ 760.00mm Hg
Freezing/Melting Point: 1083 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density: 8.9200g/cm3
Molecular Formula: Cu
Molecular Weight: 63.54
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions. Explosive peroxides may form on
concentration. Peroxides can be detonated by friction, impact, or
heating.
Conditions to Avoid:
Incompatible materials, dust generation, moisture, exposure to air.
Incompatibilities with Other Materials:
Liquid copper explodes on contact with water. Reacts violently with
ammonium nitrate, bromates, iodates, chlorates, ethylene oxide,
hydrazoic acid, potassium oxide, dimethyl sulfoxide + trichloroacetic
acid, hydrogen peroxide, sodium peroxide, sodium azide, sulfuric
acid, hydrogen sulfide + air, and lead azide. Ignites on contact
with chlorine, fluorine (above 121C), chlorine trifluoride, and
hydrazinium nitrate (above 70C). Incompatible with 1-bromo-2-propyne,
potassium dioxide, and actylenic compounds.
Hazardous Decomposition Products:
Copper fumes.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7440-50-8: GL5325000 GL7440000 GL7590000
LD50/LC50:
Not available.
Carcinogenicity:
COPPER -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
USA RQ: CAS# 7440-50-8: 5000 lb final RQ (no reporting of releases of this hazar
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 7440-50-8: 0
Canada
CAS# 7440-50-8 is listed on Canada's DSL List.
CAS# 7440-50-8 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7440-50-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/29/1998 Revision #2 Date: 12/03/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
4-Hydroxybenzophenone, 99+%
| 1137-42-4 |
|
Chlorobenzene, 99+%
| 108-90-7 |
|
Chlorobenzene, Reagent ACS, 99.5% (GC)
| 108-90-7 |
|
Chloroform, preserved with 0.75% Ethanol
| 64-17-5 |
|
Chloroform, Reagent ACS, 99.8% (GC)
| 67-66-3 |
|
2-Amino-6-Methoxybenzothiazole, Tech.
| 1747-60-0 |
|
Cholesterol, 95%
| 57-88-5 |
|
Choline Chloride, 99%
| 67-48-1 |
|
Chromium(VI) oxide, flakes, 99+%
| 1333-82-0 |
|
N,N-Dimethylindoaniline (Pract), 78% (UV-Vis)
| 2150-58-5 |
|
Chromium(VI) oxide, reagent ACS, 98+%
| 1333-82-0 |
|
Methylene violet (bernthsen), high purity biological stain
| 2516-05-4 |
|
3-Dimethylaminopropylamine, 99%
| 109-55-7 |
|
Cobalt (II) Nitrate Hexahydrate, 99%
| 10026-22-9 |
|
Cobalt(II) Nitrate, Hexahydrate, Reagent ACS (Crystals)
| 10026-22-9 |
|
D(+)-trehalose dihydrate min. 99% (hplc)
| 6138-23-4 |
|
Cobalt(II) chloride hexahydrate, p.a.
| 7791-13-1 |
|
Cobalt(II) chloride, hexahydrate, reagent ACS
| 7791-13-1 |
|
Copper, 99%, -45 Micron Powder
| 7440-50-8 |
|
Cupferron, P.A.
| 135-20-6 |
|
Copper (II) Oxide, 99.999%
| 1317-38-0 |
|
Copper (II) Oxide, P.A.
| 1317-38-0 |
|
Copper (II) Oxide, Black, Reagent ACS (Powder)
| 1317-38-0 |
|
Copper(II) sulfate, anhydrous, p.a.
| 7758-98-7 |
|
Beta-Apo-Oxytetracycline,"Can be Used as Secondary Standard"
| 18751-99-0 |
|
Tolylene-2,4-Diisocyanate, Tech., 80%
| 584-84-9 |
|
Copper(II) sulfate pentahydrate, p.a.
| 7758-98-7 |
|
Copper(II) sulfate pentahydrate, reagent ACS
| 7758-98-7 |
|
N,N'-Di-N-Butylthiourea, 99%
| 109-46-6 |
|
5-Aminosalicylic Acid, 95%
| 89-57-6 |
|
Butyl Benzoate, 98%
| 136-60-7 |
|
Dl-sec-phenethyl alcohol, 99+%
| 98-85-1 |
|
D-(-)-Fructose, 98%
| 57-48-7 |
|
D-Sorbitol, 97%
| 50-70-4 |
|
Decahydronaphthalene, mixture of cis and trans, 98%
| 91-17-8 |
|
2,6-Di-tert-butyl-4-methylphenol, 99%
| 128-37-0 |
|
2-Aminothiophenol, 98% (GC)
| 137-07-5 |
|
2-Methyl-beta-naphthothiazole, 98%
| 2682-45-3 |
|
Di-n-butylamine 99%
| 111-92-2 |
|
tert-Butyl bromoacetate, 99%
| 5292-43-3 |
|
1,4-Dimethoxybenzene, 99+%
| 150-78-7 |
|
5-Chloro-2-Methylbenzoxazole, 99+% (GC)
| 19219-99-9 |
|
Ammonium oxalate, monohydrate, p.a.
| 1113-38-8 |
|
L-Lactic Acid, 20 Wt. % Solution in Water
| 79-33-4 |
|
Benzenesulfonic acid, tech., 90%
| 98-11-3 |
|
Molybdic acid p.a.
| 7782-91-4 |
|
Poly(phenylene sulfide) nominal m.w. 10000 ,powder
| 9016-75-5 |
|
2-Pyrrolidinone, 98%
| 616-45-5 |
|
Ethyl Caprate, 99+%
| 110-38-3 |
|
2,4-Dihydroxybenzoic acid, 97%
| 89-86-1 |
|
|