**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 15128-65-1 |cis-syn-cis-Dicyclohexano-18-crown-6 | >98 | unlisted |
|----------------|--------------------------------------|----------|-----------|
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: T
Risk Phrases: 23/24/25 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.Hygroscopic (absorbs
moisture from the air).
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store
protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 15128-65-1:
CAS# 16069-36-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: very slightly yellow
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 60-63 deg C
Autoignition Temperature: Not applicable.
Flash Point: > 109 deg C (> 228.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C20H36O6
Molecular Weight: 372.50
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Dust generation, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong acids, strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 15128-65-1 unlisted.
CAS# 16069-36-6: HP5385000
LD50/LC50:
Not available.
CAS# 16069-36-6: Draize test, rabbit, eye: 50 mg Moderate; Draize
test, rabbit, skin: 100 mg/24H Mild; Oral, mouse: LD50 = 192 mg/kg;
Oral, mouse: LD50 = 192 mg/kg; Oral, rat: LD50 = 176 mg/kg; Oral,
rat: LD50 = 383 mg/kg.
Carcinogenicity:
cis-syn-cis-Dicyclohexano-18-crown-6 -
Not listed by ACGIH, IARC, or NTP.
Dicyclohexano-18-crown-6 (unspecified isomer) -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 38 In case of insufficient ventilation, wear
suitable respiratory equipment.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 15128-65-1: No information available.
CAS# 16069-36-6: No information available.
Canada
CAS# 16069-36-6 is listed on Canada's NDSL List.
CAS# 15128-65-1 is not listed on Canada's Ingredient Disclosure List.
CAS# 16069-36-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 15128-65-1 is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 16069-36-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/02/1997 Revision #6 Date: 3/24/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-Naphthyl isothiocyanate, 98%
| 551-06-4 |
|
2-Iodoaniline, 98%
| 615-43-0 |
|
DL-Alpha-Methyltyrosine, 98%
| 658-48-0 |
|
6-Chloropurine Riboside, 99+%
| 2004-06-0 |
|
2-Amino-4,4,4-trifluorobutyric acid
| 15960-05-1 |
|
4-Fluorophenol, 99%
| 371-41-5 |
|
4-Methyl-1-tetralone, 97%
| 19832-98-5 |
|
3,3'-Thiodipropionic Acid, 99%
| 111-17-1 |
|
Diaminomaleonitrile, 98%
| 1187-42-4 |
|
2-Butoxyethyl acetate, 98%
| 112-07-2 |
|
Chromocene
| 1271-24-5 |
|
Arsenazo III, 95% (HPLC)
| 1668-00-4 |
|
3-Dimethylaminophenol, 97+% (TLC)
| 99-07-0 |
|
2-Amino-4-Fluorobenzoic Acid, 96% (GC)
| 446-32-2 |
|
Dimethyl Phenylphosphonite, 98%
| 2946-61-4 |
|
Pinacolone, 97% (gc)
| 75-97-8 |
|
1-Phenylhexane, 97%
| 1077-16-3 |
|
Ethyl chrysanthemumate, 95%, mixture of cis/trans
| 97-41-6 |
|
Triethylamine Hydrochloride, 99+%
| 554-68-7 |
|
cis-Dicyclohexano-18-crown-6, cis-syn-cis isomer, 98+%
| 15128-65-1 |
|
2-Hydrazino-2-Imidazoline Hydrobromide, 98 %
| 55959-84-7 |
|
N-Methyl-m-toluidine
| 696-44-6 |
|
4-Ethoxyphenol
| 622-62-8 |
|
Tris(4-Chlorophenyl)Phosphine
| 1159-54-2 |
|
4-Bromo-2-fluorotoluene 98%
| 51436-99-8 |
|
7-Azaindole, 98%
| 271-63-6 |
|
1-Nitroso-2-naphtol-3,6-disulfonic acid disodium salt (pract), 95%
| 525-05-3 |
|
(S)-3-Hydroxy-3-Phenylpropanoic Acid
| 36567-72-3 |
|
Anthranilic acid, 98+%
| 118-92-3 |
|
Malonic Acid Disodium Salt Monohydrate, 99% (Titr.)
| 141-95-7 |
|
4-Chlorophenyl 2-Chloro-1,1,2-Trifluoro-Ethyl Sulfone, 98%
| 26574-59-4 |
|
2-Hexanone, 98%
| 591-78-6 |
|
2,2-Dimethylsuccinic Acid, 99%
| 597-43-3 |
|
O-Methoxybiphenyl, 98+%
| 86-26-0 |
|
2-Naphthol, 99+%
| 135-19-3 |
|
Ethylidenecyclohexane, 99%
| 1003-64-1 |
|
2,4,6-Trichlorophenol, 98%
| 88-06-2 |
|
Brilliant Cresyl Blue , High Purity Biological Stain
| 81029-05-2 |
|
Hydrocinnamoylchloride, 98%
| 645-45-4 |
|
Methacrylic acid, 99.5% (stabilized with ca 250 ppm MEHQ)
| 79-41-4 |
|
4-Aminosalicylic acid, 99%
| 65-49-6 |
|
3-Bromopropionic Acid, 99% (Titr.)
| 590-92-1 |
|
2-Ethylbutyraldehyde, 98%
| 97-96-1 |
|
2-Fluoro-5-Nitroaniline, 98%
| 369-36-8 |
|
Heptafluoro-n-propyliodide, 99%, stabilized with copper
| 754-34-7 |
|
3-Formyl-2-Methyl-5-Nitroindole, 95+%
| 3558-17-6 |
|
Crotononitrile (pract), 98% (gc)
| 4786-20-3 |
|
Praseodymium(iii,iv) oxide, 99.9%
| 12037-29-5 |
|
N-(4-Hydroxyphenyl)-Glycine, 99%
| 122-87-2 |
|
Cresol Red, indicator grade
| 1733-12-6 |
|
|