**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1663-39-4 |tert-Butyl acrylate | | 216-768-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN F
Risk Phrases: 11 20/22 36/37/38 52/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Harmful by inhalation and if swallowed. Irritating
to eyes, respiratory system and skin. Harmful to aquatic organisms,
may cause long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Flammable liquid and vapor.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin
and eyes.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 1663-39-4:
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: ester-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: 0.9 mPa.s @20 deg C
Boiling Point: 121 deg C @760mmHg
Freezing/Melting Point: -69 deg C
Autoignition Temperature: 400 deg C ( 752.00 deg F)
Flash Point: 11 deg C ( 51.80 deg F)
Explosion Limits, lower: 0.7 Vol % Vol %
Explosion Limits, upper: 7 Vol % Vol %
Decomposition Temperature:
Solubility in water: 2g/l
Specific Gravity/Density: 0.883
Molecular Formula: C7H12O2
Molecular Weight: 128.0828
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
High temperatures, incompatible materials, light, ignition sources.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1663-39-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
tert-Butyl acrylate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Daphnia: 14.0 mg/L; 48 h;Fish: Pseudomonas putida: 14.0 mg/L; 1/2
hFish: Leuciscus idus: 14.0 mg/L; 96 hlog Pow = 2.32
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: BUTYL ACRYLATES, STABILIZED
Hazard Class: 3
UN Number: 2348
Packing Group: III
IMO
Shipping Name: BUTYL ACRYLATES, STABILIZED
Hazard Class: 3
UN Number: 2348
Packing Group: III
RID/ADR
Shipping Name: BUTYL ACRYLATES, STABILIZED
Hazard Class: 3
UN Number: 2348
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 11 Highly flammable.
R 20/22 Harmful by inhalation and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 52/53 Harmful to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 1663-39-4: 1
Canada
CAS# 1663-39-4 is listed on Canada's DSL List.
CAS# 1663-39-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1663-39-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/10/2003 Revision #0 Date: Original.
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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| ALL MSDS PAGES IN THIS GROUP
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Zinc chloride, 0.5M solution in THF
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Ethyl (r)-(+)-4-chloro-3-hydroxybutyrate
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2,6-Difluorobenzophenone, 97%
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Platinum Atom. Absorpt. Standard Solution 1 mg/ml Pt in 10% HCl
| 7440-06-4 |
|
2,5-Dimethylpyrrolidine, mixture of cis an d trans, 93.5%
| 3378-71-0 |
|
Ethyl acetate
| 141-78-6 |
|
Methyl 5-bromo-2-pyridinecarboxylate
| 29682-15-3 |
|
3-Phenyl-2-propyn-1-ol, 98%
| 1504-58-1 |
|
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| 93110-05-5 |
|
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| 18595-18-1 |
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| 610-78-6 |
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| 15630-89-4 |
|
tert-Butyl acrylate, stabilized
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|
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|
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| 75-09-2 |
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| 141-97-9 |
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3-Azabicyclo??3.2.2??nonane, 99+% (gc)
| 283-24-9 |
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Zinc, 5% suspension in THF, highly active rieke?? metal
| 109-99-9 |
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Benzyl 3-pyrroline-1-carboxylate
| 31970-04-4 |
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| 7440-23-5 |
|
(2,5-Dimethoxyphenyl)acetyl chloride
| 52711-92-9 |
|
trans-2-Methyl-2-pentenoic acid
| 16957-70-3 |
|
4-Oxo-2,2,6,6-tetramethylpiperidinooxy, free radical 95%
| 2896-70-0 |
|
3-Fluorobenzyl bromide, 95%
| 456-41-7 |
|
2,3-Dichlorophenethylamine
| 34164-43-7 |
|
Brilliant Green (Cert)
| 633-03-4 |
|
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| 36082-50-5 |
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| 21320-91-2 |
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4-Bromo-2-chlorobenzenesulfonyl chloride
| 351003-52-6 |
|
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| 766-98-3 |
|
Ethyl Benzene
| 100-41-4 |
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| 42601-04-7 |
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| 94978-86-6 |
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| 1519-47-7 |
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| 2557-78-0 |
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| 41513-32-0 |
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