**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 60-29-7 |Diethyl ether | 86 | 200-467-2 |
|----------------|--------------------------------------|----------|-----------|
| 7646-85-7 |Zinc chloride | 14 | 231-592-0 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: F+ C N
Risk Phrases: 12 19 22 34 51/53 66 67
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Extremely flammable. May form explosive peroxides. Harmful if
swallowed. Causes burns. Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment. Repeated
exposure may cause skin dryness or cracking. Vapours may cause
drowsiness and dizziness.Hygroscopic (absorbs moisture from the
air).Light sensitive.Air sensitive.
Potential Health Effects
Eye:
Causes eye burns. Causes redness and pain.
Skin:
Causes skin burns. Prolonged and/or repeated contact may cause
defatting of the skin and dermatitis. Causes redness and pain.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns. May cause
systemic toxicity with acidosis. May cause liver and kidney damage.
May cause central nervous system depression, characterized by
excitement, followed by headache, dizziness, drowsiness, and nausea.
Advanced stages may cause collapse, unconsciousness, coma and
possible death due to respiratory failure.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. Causes chemical burns to the respiratory tract. May cause
drowsiness, unconsciousness, and central nervous system depression.
Vapors may cause dizziness or suffocation. Causes irritation of the
mucous membrane.
Chronic:
Prolonged or repeated skin contact may cause defatting and
dermatitis. Prolonged or repeated exposure can cause psychic
abnormalities such as anxiety, depression and excitability.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Get medical aid immediately. Do NOT induce vomiting. If conscious
and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Containers can build up pressure if exposed to heat and/or fire. As
in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water runoff can cause environmental damage. Dike
and collect water used to fight fire. Vapors may form an explosive
mixture with air. Vapors can travel to a source of ignition and flash
back. Will burn if involved in a fire. Use water spray to keep
fire-exposed containers cool. Extremely flammable liquid and vapor.
Water may be ineffective. Material is lighter than water and a fire
may be spread by the use of water. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined
areas. Will be easily ignited by heat, sparks or flame. May
accumulate static electrical charges, and may cause ignition of its
own vapors. Containers may explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Water may be
ineffective. Use dry chemical, carbon dioxide, or alcohol-resistant
foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Remove all sources of ignition. Absorb spill using an absorbent,
non-combustible material such as earth, sand, or vermiculite. Do not
use combustible materials such as sawdust. Use a spark-proof tool.
Provide ventilation. A vapor suppressing foam may be used to reduce
vapors. Water spray may reduce vapor but may not prevent ignition in
closed spaces. Stop leak only if you can do so without risk.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use only in a well-ventilated area. Ground and bond containers when
transferring material. Use spark-proof tools and explosion proof
equipment. Do not breathe dust, vapor, mist, or gas. Do not get in
eyes, on skin, or on clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Take
precautionary measures against static discharges. Keep away from
heat, sparks and flame. Use only in a chemical fume hood. If peroxide
formation is suspected, do not open or move container. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Do not store in direct sunlight. Store in a tightly closed
container. Keep from contact with oxidizing materials. Store in a
cool, dry, well-ventilated area away from incompatible substances.
Flammables-area. Regularly check inhibitor levels to maintain
peroxide levels below 1%. After opening, purge container with
nitrogen before reclosing. Periodically test for peroxide formation
on long-term storage. Addition of water or appropriate reducing
materials will lessen peroxide formation.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 60-29-7:
United Kingdom, WEL - TWA: 100 ppm TWA; 310 mg/m3 TWA
United Kingdom, WEL - STEL: 200 ppm STEL; 620 mg/m3 STEL
United States OSHA: 400 ppm TWA; 1200 mg/m3 TWA
Belgium - TWA: 100 ppm VLE; 308 mg/m3 VLE
Belgium - STEL: 200 ppm VLE; 616 mg/m3 VLE
France - VME: 400 ppm VME; 1200 mg/m3 VME
France - VLE: 500 ppm VLE; 1500 mg/m3 VLE
Germany: 400 ppm TWA; 1200 mg/m3 TWA
Japan: 400 ppm OEL; 1200 mg/m3 OEL
Malaysia: 400 ppm TWA; 1210 mg/m3 TWA
Netherlands: 200 ppm STEL; 616 mg/m3 STEL
Netherlands: 100 ppm MAC; 308 mg/m3 MAC
Russia: 300 mg/m3 TWA
Spain: 100 ppm VLA-ED; 308 mg/m3 VLA-ED
Spain: 200 ppm VLA-EC; 616 mg/m3 VLA-EC
CAS# 7646-85-7:
United Kingdom, WEL - TWA: 1 mg/m3 TWA (fume)
United Kingdom, WEL - STEL: 2 mg/m3 STEL (fume)
United States OSHA: 1 mg/m3 TWA (fume)
Belgium - TWA: 1 mg/m3 VLE (fumes)
Belgium - STEL: 2 mg/m3 VLE (fumes)
France - VME: 1 mg/m3 VME (fume)
Malaysia: 1 mg/m3 TWA (fume)
Netherlands: 1 mg/m3 MAC (smoke)
Spain: 1 mg/m3 VLA-ED (fume)
Spain: 2 mg/m3 VLA-EC (fume)
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: colorless
Odor: ether-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: 665 deg C ( 1,229.00 deg F)
Flash Point: -21 deg C ( -5.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: 1.120
Molecular Formula: Cl2Zn
Molecular Weight: 136.29
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Prolonged exposure to air and sunlight may form unstable peroxides.
Distillation may lead to the formation of peroxides.
Conditions to Avoid:
Incompatible materials, light, ignition sources, temperatures above
150C, exposure to moist air or water.
Incompatibilities with Other Materials:
Nitrates, oxidizing agents, strong acids, chlorine trifluoride,
liquid chlorine, nitric acid, sodium peroxide, ozone, peroxides and
hydroperoxides (organic, e.g. acetyl peroxide, benzoyl peroxide,
butyl peroxide, methyl ethyl ketone peroxide), chromyl chloride,
nitrosyl perchlorate, perchloric acid, chromic anhydride, zinc,
azides, chlorine, sulfuric acid, permanganates, liquid oxygen.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide, peroxides, toxic
fumes of zinc oxide, zinc, zinc oxides.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 60-29-7: KI5775000
CAS# 7646-85-7: ZH1400000
LD50/LC50:
CAS# 60-29-7: Draize test, rabbit, eye: 100 mg Moderate; Inhalation,
mouse: LC50 = 31000 ppm/30M; Oral, mouse: LD50 = 1760 mg/kg; Oral,
rat: LD50 = 1215 mg/kg; Skin, rabbit: LD50 = >20 mL/kg.
CAS# 7646-85-7: Oral, mouse: LD50 = 329 mg/kg; Oral, rat: LD50 = 350
mg/kg.
Carcinogenicity:
Diethyl ether -
Not listed by ACGIH, IARC, or NTP.
Zinc chloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.*
Hazard Class: 3 (8)
UN Number: 2924
Packing Group: I
IMO
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.
Hazard Class: 3 (8)
UN Number: 2924
Packing Group: I
RID/ADR
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.
Hazard Class: 3
UN Number: 2924
Packing group: I
USA RQ: CAS# 60-29-7: 100 lb final RQ; 45.4 kg final RQ
USA RQ: CAS# 7646-85-7: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F+ C N
Risk Phrases:
R 12 Extremely flammable.
R 19 May form explosive peroxides.
R 22 Harmful if swallowed.
R 34 Causes burns.
R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
R 66 Repeated exposure may cause skin dryness or
cracking.
R 67 Vapours may cause drowsiness and dizziness.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 28A After contact with skin, wash immediately with
plenty of water.
S 29 Do not empty into drains.
S 33 Take precautionary measures against static
discharges.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 60-29-7: 1
CAS# 7646-85-7: 1
Canada
CAS# 60-29-7 is listed on Canada's DSL List.
CAS# 7646-85-7 is listed on Canada's DSL List.
CAS# 60-29-7 is listed on Canada's Ingredient Disclosure List.
CAS# 7646-85-7 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 60-29-7 is listed on the TSCA inventory.
CAS# 7646-85-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 6/10/2003 Revision #0 Date: Original.
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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