**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 2044-64-6 |N,N-Dimethylacetoacetamide | 70 % | 218-059-8 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | Balance | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Light sensitive.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this
material have not been fully investigated.
Skin:
May cause skin irritation.
Ingestion:
Ingestion of large amounts may cause gastrointestinal irritation.
Low hazard for usual industrial handling.
Inhalation:
May cause respiratory tract irritation. Low hazard for usual
industrial handling.
Chronic:
None
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. If irritation
develops, get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid if irritation or symptoms occur.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Avoid
breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin,
and clothing. Keep container tightly closed. Avoid ingestion and
inhalation. Use with adequate ventilation. Store protected from
light.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep
refrigerated. (Store below 4C/39F.) Store protected from light.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 2044-64-6:
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: -55 deg C
Autoignition Temperature: 450 deg C ( 842.00 deg F)
Flash Point: 99 deg C ( 210.20 deg F)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: hydrolysis
Specific Gravity/Density: 1.0580g/cm3
Molecular Formula: C6H11NO2
Molecular Weight: 129.16
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light, ignition sources.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 2044-64-6: AK4035000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 2044-64-6: Draize test, rabbit, eye: 500 mg/24H Mild; Draize
test, rabbit, skin: 500 mg/24H Mild; Oral, rat: LD50 = 22600 uL/kg;
Skin, rabbit: LD50 = 14100 uL/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
N,N-Dimethylacetoacetamide -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 2044-64-6: No information available.
CAS# 7732-18-5: No information available.
Canada
CAS# 2044-64-6 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 2044-64-6 is not listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2044-64-6 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 10/15/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Poly(Ethylene Oxide) Approximate m.w.300.000
| 25322-68-3 |
|
Glutaric Dialdehyde, 25 wt.% Solution in Water
| 111-30-8 |
|
Palladium, Powder, 99.99%
| 7440-05-3 |
|
Palladium, Sponge, 99.9%
| 7440-05-3 |
|
Rhodium(II) Acetate, Dimer, Dihydrate (ca43% Rh)
| 29998-99-0 |
|
Rhodiumacetate, Brown, Water Soluble, ca 40% Rh
| 5503-41-3 |
|
N,N-Dimethylacetoacetamide, 70 Wt% Aqueous solution
| 2044-64-6 |
|
Sinigrin, Monohydrate, from Horseradish
| 3952-98-5 |
|
Lithium acetate, p.a.
| 546-89-4 |
|
d-2-Octanol, 99%
| 6169-06-8 |
|
Terephthaldehyde monodiethylacetal, 98+% stabilized with 0.1%
| 121-44-8 |
|
Tyramine hydrochloride, 98%
| 60-19-5 |
|
Methyl Vinyl Ether/Maleic Anhydride, Medium Molecular Weight
| 9011-16-9 |
|
Pyridine-D5, 99 Atom % D
| 7291-22-7 |
|
Pyridine-D5, 99 Atom % D, Contains 1 v/v% TMS
| 7291-22-7 |
|
Pyridine-D5, 99 Atom % D, Packaged in 1.00 ml Ampules
| 7291-22-7 |
|
Pyridine-D5, 100.0 Atom% D, Packaged in 0. 5 ml Ampules
| 7291-22-7 |
|
Plasmocorinth B
| 1058-92-0 |
|
Triethylenetetramine tetrahydrochloride, 97%
| 4961-40-4 |
|
Cyclooctene, 95%
| 931-88-4 |
|
N,N-Dimethylindoaniline, ca.92% Dye Content
| 2150-58-5 |
|
2,5-Dihydroxyphenylacetic Acid, 99%
| 451-13-8 |
|
Benzenesulfonyl Chloride, 96%
| 98-09-9 |
|
Wright stain solution in methanol buffered
| 67-56-1 |
|
Phenylhydrazine, 95%
| 100-63-0 |
|
Wright's stain (cert), 97% (uv-vis)
| 67-56-1 |
|
8-Hydroxyjulolidine, 98%
| 41175-50-2 |
|
2-Methyl-2,4-Pentanediol, 99%
| 107-41-5 |
|
Orcinol, 98% (uv-vis)
| 504-15-4 |
|
5-Bromovanillin, 98%
| 2973-76-4 |
|
2-Phenylbenzimidazole, 97%
| 716-79-0 |
|
Phenylhydrazine, 97%
| 100-63-0 |
|
2-Methylcyclohexanol (Mixture of Cis and Trans), 99%
| 583-59-5 |
|
1,1,3,3-Tetramethylurea, 99%
| 632-22-4 |
|
O-Toluoyl Chloride, 99% (Titr.)
| 933-88-0 |
|
Ethylxanthic Acid Potassium Salt
| 140-89-6 |
|
7-Diethylamino-3-Thenoylcoumarin
| 77820-11-2 |
|
Lithium, Wire, 99+%, Diameter 3.2mm
| 7439-93-2 |
|
Lithium (Granules, Coated with Mineral Oil)
| 7439-93-2 |
|
Thymine, 99%
| 65-71-4 |
|
Methyl stearate, 98%
| 112-61-8 |
|
Octacosane, 99+% (GC)
| 630-02-4 |
|
2,5-Dimethoxyaniline, 99+%
| 102-56-7 |
|
(R)-(-)-2-Amino-1-butanol
| 5856-63-3 |
|
Acetic-D3 Acid-D, 99.5 Atom % D
| 1186-52-3 |
|
Acetic-D3 Acid-D, 99.9 Atom % D (1pk=10x0.5ml)
| 1186-52-3 |
|
2-Mercaptobenzothiazole, 95% Contains 1-2% Oil
| 149-30-4 |
|
2-Mercaptobenzothiazole (Pract), 98% (Titr.)
| 149-30-4 |
|
4-Bromo-m-xylene, tech., 85%
| 583-70-0 |
|
3-(Dibutylamino)propionitrile, 97%
| 25726-99-2 |
|
|