**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 29998-99-0 |Rhodium(II) Acetate, Dimer, Dihydrate | ca. 57.0 | unlisted |
| |(ca43% Rh) | | |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes and skin.The toxicological properties of this
material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation and possible burns. May cause chemical
conjunctivitis.
Skin:
Causes skin irritation and possible burns.
Ingestion:
May cause cardiac disturbances. The toxicological properties of this
substance have not been fully investigated. May cause central nervous
system effects. May cause irritation of the digestive tract and
possible burns.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. Central nervous
system effects, which appear to predominate in acute cases are
characterized by abnormal fatigue, memory difficulties and
dizziness.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid. Do NOT allow victim to rub eyes or keep eyes
closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Contact
with metals may evolve flammable hydrogen gas. Containers may explode
when heated. Non-combustible, substance itself does not burn but may
decompose upon heating to produce irritating, corrosive and/or toxic
fumes. Runoff from fire control or dilution water may cause
pollution.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Do NOT get water
inside containers. For small fires, use dry chemical, carbon
dioxide, or water spray. For large fires, use dry chemical, carbon
dioxide, alcohol-resistant foam, or water spray.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid
contact with eyes, skin, and clothing. Keep container tightly
closed. Avoid ingestion and inhalation. Use only in a chemical fume
hood. Wash clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low. Use only under a
chemical fume hood.
Exposure Limits
CAS# 29998-99-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear a chemical apron. Wear appropriate protective
clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: green
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 88-90C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: .888
Molecular Formula: (CH3Co2)Rh2.nH2O
Molecular Weight: 338.6984
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, rhodium/rhodium oxides.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 29998-99-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Rhodium(II) Acetate, Dimer, Dihydrate (ca43% Rh) -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 15 Keep away from heat.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 29998-99-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 29998-99-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 29998-99-0 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/23/1999 Revision #4 Date: 8/30/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Poly(Ethylene Oxide) Approximate m.w.300.000
| 25322-68-3 |
|
Glutaric Dialdehyde, 25 wt.% Solution in Water
| 111-30-8 |
|
Palladium, Powder, 99.99%
| 7440-05-3 |
|
Palladium, Sponge, 99.9%
| 7440-05-3 |
|
Rhodium(II) Acetate, Dimer, Dihydrate (ca43% Rh)
| 29998-99-0 |
|
Rhodiumacetate, Brown, Water Soluble, ca 40% Rh
| 5503-41-3 |
|
N,N-Dimethylacetoacetamide, 70 Wt% Aqueous solution
| 2044-64-6 |
|
Sinigrin, Monohydrate, from Horseradish
| 3952-98-5 |
|
Lithium acetate, p.a.
| 546-89-4 |
|
d-2-Octanol, 99%
| 6169-06-8 |
|
Terephthaldehyde monodiethylacetal, 98+% stabilized with 0.1%
| 121-44-8 |
|
Tyramine hydrochloride, 98%
| 60-19-5 |
|
Methyl Vinyl Ether/Maleic Anhydride, Medium Molecular Weight
| 9011-16-9 |
|
Pyridine-D5, 99 Atom % D
| 7291-22-7 |
|
Pyridine-D5, 99 Atom % D, Contains 1 v/v% TMS
| 7291-22-7 |
|
Pyridine-D5, 99 Atom % D, Packaged in 1.00 ml Ampules
| 7291-22-7 |
|
Pyridine-D5, 100.0 Atom% D, Packaged in 0. 5 ml Ampules
| 7291-22-7 |
|
Plasmocorinth B
| 1058-92-0 |
|
Triethylenetetramine tetrahydrochloride, 97%
| 4961-40-4 |
|
Cyclooctene, 95%
| 931-88-4 |
|
N,N-Dimethylindoaniline, ca.92% Dye Content
| 2150-58-5 |
|
2,5-Dihydroxyphenylacetic Acid, 99%
| 451-13-8 |
|
Benzenesulfonyl Chloride, 96%
| 98-09-9 |
|
Wright stain solution in methanol buffered
| 67-56-1 |
|
Phenylhydrazine, 95%
| 100-63-0 |
|
Wright's stain (cert), 97% (uv-vis)
| 67-56-1 |
|
8-Hydroxyjulolidine, 98%
| 41175-50-2 |
|
2-Methyl-2,4-Pentanediol, 99%
| 107-41-5 |
|
Orcinol, 98% (uv-vis)
| 504-15-4 |
|
5-Bromovanillin, 98%
| 2973-76-4 |
|
2-Phenylbenzimidazole, 97%
| 716-79-0 |
|
Phenylhydrazine, 97%
| 100-63-0 |
|
2-Methylcyclohexanol (Mixture of Cis and Trans), 99%
| 583-59-5 |
|
1,1,3,3-Tetramethylurea, 99%
| 632-22-4 |
|
O-Toluoyl Chloride, 99% (Titr.)
| 933-88-0 |
|
Ethylxanthic Acid Potassium Salt
| 140-89-6 |
|
7-Diethylamino-3-Thenoylcoumarin
| 77820-11-2 |
|
Lithium, Wire, 99+%, Diameter 3.2mm
| 7439-93-2 |
|
Lithium (Granules, Coated with Mineral Oil)
| 7439-93-2 |
|
Thymine, 99%
| 65-71-4 |
|
Methyl stearate, 98%
| 112-61-8 |
|
Octacosane, 99+% (GC)
| 630-02-4 |
|
2,5-Dimethoxyaniline, 99+%
| 102-56-7 |
|
(R)-(-)-2-Amino-1-butanol
| 5856-63-3 |
|
Acetic-D3 Acid-D, 99.5 Atom % D
| 1186-52-3 |
|
Acetic-D3 Acid-D, 99.9 Atom % D (1pk=10x0.5ml)
| 1186-52-3 |
|
2-Mercaptobenzothiazole, 95% Contains 1-2% Oil
| 149-30-4 |
|
2-Mercaptobenzothiazole (Pract), 98% (Titr.)
| 149-30-4 |
|
4-Bromo-m-xylene, tech., 85%
| 583-70-0 |
|
3-(Dibutylamino)propionitrile, 97%
| 25726-99-2 |
|
|