**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 98-09-9 |Benzenesulfonyl Chloride | 96 | 202-636-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN C
Risk Phrases: 22 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Causes burns.Corrosive.Water-Reactive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns. May cause perforation of the
digestive tract. May be harmful if swallowed.
Inhalation:
Causes chemical burns to the respiratory tract. May cause pulmonary
edema and severe respiratory disturbances.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Extensive irrigation with water is
required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
soap and water for at least 15 minutes while removing contaminated
clothing and shoes. Wash clothing before reuse. Destroy contaminated
shoes.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air
immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Containers
may explode in the heat of a fire. May react exothermically with
water, causing liberation of heat and possible spattering of
material. Vapors may be heavier than air. They can spread along the
ground and collect in low or confined areas. Contact with metals may
evolve flammable hydrogen gas. Combustible material; may burn but
does not ignite readily.
Extinguishing Media:
Do NOT get water inside containers. For large fires, use water
spray, fog or alcohol-resistant foam. Do NOT use straight streams of
water. Most foams will react with the material and release
corrosive/toxic gases. Cool containers with flooding quantities of
water until well after fire is out. For small fires, use dry
chemical, dry sand, alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Large spills may be neutralized with dilute alkaline solutions of
soda ash, or lime. Absorb the liquid and scrub the area with
detergent and water. Clean up spills immediately, observing
precautions in the Protective Equipment section. Remove all sources
of ignition. Use a spark-proof tool. Provide ventilation. Do not get
water inside containers. A vapor suppressing foam may be used to
reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove
contaminated clothing and wash before reuse. Use only in a
well-ventilated area. Do not get in eyes, on skin, or on clothing.
Empty containers retain product residue, (liquid and/or vapor), and
can be dangerous. Avoid contact with heat, sparks and flame. Do not
ingest or inhale. Use caution when opening. Can explode without
warning when caps of old containers are unscrewed. Do not pressurize,
cut, weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a cool, dry place. Do not store in direct
sunlight. Store in a tightly closed container. Keep from contact with
oxidizing materials. Corrosives area. Water free area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits. Facilities storing or utilizing this material should
be equipped with an eyewash facility and a safety shower.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure. Wear an impervious apron.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure. Wear an impervious apron.
Respirators:
Follow the OSHA respirator regulations found in 29CFR
1910.134 or European Standard EN 149. Always use a
NIOSH or European Standard EN 149 approved respirator
when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Appearance: clear slightly yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: 6 mm Hg @ 20 C
Viscosity: Not available.
Boiling Point: 252 deg C
Freezing/Melting Point: 15 deg C
Autoignition Temperature: 450 deg C ( 842.00 deg F)
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: > 252 deg C
Solubility in water: Reacts with water.
Specific Gravity/Density: 1.38
Molecular Formula: C6H5SO2Cl
Molecular Weight: 176.5468
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
High temperatures, mechanical shock, incompatible materials, ignition
sources, contact with water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, dimethyl sulfoxide, methyl
formamide, and water or moisture.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, carbon monoxide, oxides of sulfur,
carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 98-09-9: DB8750000
LD50/LC50:
CAS# 98-09-9: Oral, mouse: LD50 = 828 mg/kg; Oral, rabbit: LD50 =
828 mg/kg; Oral, rat: LD50 = 1960 mg/kg.
Carcinogenicity:
Benzenesulfonyl Chloride -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: BENZENESULPHONYL CHLORIDE
Hazard Class: 8
UN Number: 2225
Packing Group: III
IMO
Shipping Name: BENZENESULPHONYL CHLORIDE
Hazard Class: 8
UN Number: 2225
Packing Group: III
RID/ADR
Shipping Name: BENZENE SULPHONYL CHLORIDE
Dangerous Goods Code: 8(35C)
UN Number: 2225
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN C
Risk Phrases:
R 22 Harmful if swallowed.
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28 After contact with skin, wash immediately
with...
S 36/39 Wear suitable protective clothing and
eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 98-09-9: 1
United Kingdom Occupational Exposure Limits
Canada
CAS# 98-09-9 is listed on Canada's DSL List.
CAS# 98-09-9 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 98-09-9: OEL-RUSSIA:STEL 1 mg/m3;Skin
US FEDERAL
TSCA
CAS# 98-09-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/20/1998 Revision #2 Date: 8/02/2000
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Poly(Ethylene Oxide) Approximate m.w.300.000
| 25322-68-3 |
|
Glutaric Dialdehyde, 25 wt.% Solution in Water
| 111-30-8 |
|
Palladium, Powder, 99.99%
| 7440-05-3 |
|
Palladium, Sponge, 99.9%
| 7440-05-3 |
|
Rhodium(II) Acetate, Dimer, Dihydrate (ca43% Rh)
| 29998-99-0 |
|
Rhodiumacetate, Brown, Water Soluble, ca 40% Rh
| 5503-41-3 |
|
N,N-Dimethylacetoacetamide, 70 Wt% Aqueous solution
| 2044-64-6 |
|
Sinigrin, Monohydrate, from Horseradish
| 3952-98-5 |
|
Lithium acetate, p.a.
| 546-89-4 |
|
d-2-Octanol, 99%
| 6169-06-8 |
|
Terephthaldehyde monodiethylacetal, 98+% stabilized with 0.1%
| 121-44-8 |
|
Tyramine hydrochloride, 98%
| 60-19-5 |
|
Methyl Vinyl Ether/Maleic Anhydride, Medium Molecular Weight
| 9011-16-9 |
|
Pyridine-D5, 99 Atom % D
| 7291-22-7 |
|
Pyridine-D5, 99 Atom % D, Contains 1 v/v% TMS
| 7291-22-7 |
|
Pyridine-D5, 99 Atom % D, Packaged in 1.00 ml Ampules
| 7291-22-7 |
|
Pyridine-D5, 100.0 Atom% D, Packaged in 0. 5 ml Ampules
| 7291-22-7 |
|
Plasmocorinth B
| 1058-92-0 |
|
Triethylenetetramine tetrahydrochloride, 97%
| 4961-40-4 |
|
Cyclooctene, 95%
| 931-88-4 |
|
N,N-Dimethylindoaniline, ca.92% Dye Content
| 2150-58-5 |
|
2,5-Dihydroxyphenylacetic Acid, 99%
| 451-13-8 |
|
Benzenesulfonyl Chloride, 96%
| 98-09-9 |
|
Wright stain solution in methanol buffered
| 67-56-1 |
|
Phenylhydrazine, 95%
| 100-63-0 |
|
Wright's stain (cert), 97% (uv-vis)
| 67-56-1 |
|
8-Hydroxyjulolidine, 98%
| 41175-50-2 |
|
2-Methyl-2,4-Pentanediol, 99%
| 107-41-5 |
|
Orcinol, 98% (uv-vis)
| 504-15-4 |
|
5-Bromovanillin, 98%
| 2973-76-4 |
|
2-Phenylbenzimidazole, 97%
| 716-79-0 |
|
Phenylhydrazine, 97%
| 100-63-0 |
|
2-Methylcyclohexanol (Mixture of Cis and Trans), 99%
| 583-59-5 |
|
1,1,3,3-Tetramethylurea, 99%
| 632-22-4 |
|
O-Toluoyl Chloride, 99% (Titr.)
| 933-88-0 |
|
Ethylxanthic Acid Potassium Salt
| 140-89-6 |
|
7-Diethylamino-3-Thenoylcoumarin
| 77820-11-2 |
|
Lithium, Wire, 99+%, Diameter 3.2mm
| 7439-93-2 |
|
Lithium (Granules, Coated with Mineral Oil)
| 7439-93-2 |
|
Thymine, 99%
| 65-71-4 |
|
Methyl stearate, 98%
| 112-61-8 |
|
Octacosane, 99+% (GC)
| 630-02-4 |
|
2,5-Dimethoxyaniline, 99+%
| 102-56-7 |
|
(R)-(-)-2-Amino-1-butanol
| 5856-63-3 |
|
Acetic-D3 Acid-D, 99.5 Atom % D
| 1186-52-3 |
|
Acetic-D3 Acid-D, 99.9 Atom % D (1pk=10x0.5ml)
| 1186-52-3 |
|
2-Mercaptobenzothiazole, 95% Contains 1-2% Oil
| 149-30-4 |
|
2-Mercaptobenzothiazole (Pract), 98% (Titr.)
| 149-30-4 |
|
4-Bromo-m-xylene, tech., 85%
| 583-70-0 |
|
3-(Dibutylamino)propionitrile, 97%
| 25726-99-2 |
|
|