**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 20765-98-4 |Rhodium(III) Chloride Trihydrate | | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN C
Risk Phrases: 22 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Causes burns.Hygroscopic (absorbs moisture
from the air).Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
Causes gastrointestinal tract burns. May cause perforation of the
digestive tract. May cause cardiac disturbances. May cause central
nervous system effects. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead
to pulmonary edema. May cause cardiac abnormalities. May cause
systemic effects. Central nervous system effects, which appear to
predominate in acute cases are characterized by abnormal fatigue,
memory difficulties and dizziness.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Contact
with metals may evolve flammable hydrogen gas. Containers may explode
when heated. Non-combustible, substance itself does not burn but may
decompose upon heating to produce irritating, corrosive and/or toxic
fumes. Runoff from fire control or dilution water may cause
pollution.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Do NOT get water
inside containers. For small fires, use dry chemical, carbon
dioxide, or water spray. For large fires, use dry chemical, carbon
dioxide, alcohol-resistant foam, or water spray.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use only in a well-ventilated area. Minimize dust generation and
accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in
eyes, on skin, or on clothing. Keep container tightly closed. Do not
ingest or inhale. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 20765-98-4:
United Kingdom, WEL - TWA: (listed as rhodium): 0.1 mg/m3 TWA (du
and fume)
United Kingdom, WEL - STEL: (listed as rhodium): 0.3 mg/m3 STEL (
and fume)
United States OSHA: 0.1 mg/m3 TWA (listed under Rhodium).0.001 m
TWA (as Rh) (listed under Rhodium soluble compounds).
Belgium - TWA: (listed as rhodium soluble compounds): 0.01 mg/m3
(as Rh)
France - VME: (listed as rhodium): 1 mg/m3 VME
Germany: (listed as rhodium): 1 mg/m3 VME
Malaysia: (listed as rhodium soluble compounds): 0.01 mg/m3 TWA (
Rh)
Netherlands: (listed as rhodium soluble compounds): 0.001 mg/m3 M
(as Rh)
Spain: (listed as rhodium soluble compounds): 0.01 mg/m3 VLA-ED (
Rh)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: dark brown
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 100 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: slightly soluble
Specific Gravity/Density:
Molecular Formula: Cl3Rh.3H2O
Molecular Weight: 263.30
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong
oxidants, exposure to moist air or water.
Incompatibilities with Other Materials:
Moisture.
Hazardous Decomposition Products:
Hydrogen chloride, irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 20765-98-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Rhodium(III) Chloride Trihydrate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN C
Risk Phrases:
R 22 Harmful if swallowed.
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 20765-98-4: 1
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 20765-98-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 20765-98-4 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1,2-Dichloroethane, extra dry, water <50 ppm
| 107-06-2 |
|
1-Pyrrolidinecarbodithioic acid, ammonium salt
| 5108-96-3 |
|
Cyclohexane, Extra Dry, Water <50 ppm
| 110-82-7 |
|
1,2-Cyclohexanedione, 98%
| 765-87-7 |
|
Dichloromethane, Extra Dry, Water <30 ppm
| 75-09-2 |
|
Ether, extra dry, water <50 ppm
| 60-29-7 |
|
Dimethylformamide, extra dry, water <30 ppm
| 68-12-2 |
|
Methyl sulfoxide, extra dry, water <50 ppm
| 67-68-5 |
|
1,4-Dioxane, extra dry, water <50 ppm
| 123-91-1 |
|
4-Acetamidophenol, 98%
| 103-90-2 |
|
Acetyl chloride
| 75-36-5 |
|
Ethyl Acetate, Extra Dry, Water <50 ppm
| 141-78-6 |
|
Rhodium(III) Chloride Trihydrate 38% Rh
| 20765-98-4 |
|
Ammonium Sulfate, Reagent ACS (crystals)
| 7783-20-2 |
|
n-Heptane, extra dry, water <30 ppm
| 108-87-2 |
|
n-Hexane, extra dry, water <20 ppm
| 110-54-3 |
|
N-Methylpyrrolidinone, extra dry, water <50 ppm
| 872-50-4 |
|
Ammonium thiocyanate, reagent acs (crystals)
| 1762-95-4 |
|
2,2,4-Trimethylpentane, extra dry, water <30 ppm
| 540-84-1 |
|
Methyl alcohol, extra dry, water <50 ppm
| 67-56-1 |
|
Disperse Orange 1
| 2581-69-3 |
|
Isopropanol, Extra Dry, Water <50 ppm
| 67-63-0 |
|
Ammonium metavanadate, p.a.
| 7803-55-6 |
|
Tetrahydrofuran, Extra Dry, Water <50 ppm
| 109-99-9 |
|
Aniline, P.A.
| 62-53-3 |
|
Toluene, Extra Dry, Water <10 ppm
| 108-88-3 |
|
Antimony, p.a., powder, 0.15 mm
| 7440-36-0 |
|
Benzyltriphenylphosphonium Tetrafluoroborate, 97%
| 31240-52-5 |
|
n-Butyrophenone, 99%
| 495-40-9 |
|
Potassium antimonyl-tartrate hemihydrate 99+%
| 28300-74-5 |
|
2,3-Dimethylfuran, 99%
| 14920-89-9 |
|
Tween 85
| 9055-70-3 |
|
Antimony trichloride, reagent ACS, crystals, 99+%
| 10025-91-9 |
|
Tween 40
| 9005-66-7 |
|
Antimony(III) Oxide, 99+%
| 1309-64-4 |
|
2-Amino-3,5-Dibromobenzaldehyde, 97%
| 50910-55-9 |
|
Piperonyl Butoxide, Tech., 90%
| 51-03-6 |
|
Arsenic (III) Oxide, P.A.
| 1327-53-3 |
|
4'-Bromo-3-Chloropropiophenone, 99%
| 31736-73-9 |
|
l(+)-Aspartic acid, 98+%
| 56-84-8 |
|
Meldola's Blue
| 7057-57-0 |
|
d-(+)-Isoascorbic acid,sodium salt, 98%
| 6381-77-7 |
|
Auramine O (Cert)
| 2465-27-2 |
|
4-Bromomethyl-3-Nitrobenzoic Acid
| 55715-03-2 |
|
Barbituric Acid, 99+%
| 67-52-7 |
|
3-(Trifluoromethoxy)Cinnamic Acid
| 0-01-1 |
|
(S)-(+)-Nalpha-Benzyl-N??-BOC-L-Hydrazinovaline
| 0-01-1 |
|
1,2-Epoxy-9-Decene, 96%
| 85721-25-1 |
|
Barium Acetate, Reagent ACS (Granular)
| 543-80-6 |
|
trans-1,4-Dichloro-2-butene, 95%
| 110-57-6 |
|
|