**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 75-36-5 |Acetyl chloride | >98 | 200-865-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F C
Risk Phrases: 11 14 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Reacts violently with water. Causes
burns.Corrosive.Water-Reactive.
Potential Health Effects
Eye:
Contact with liquid is corrosive to the eyes and causes severe
burns. May cause chemical conjunctivitis and corneal damage.
Skin:
Contact with liquid is corrosive and causes severe burns and
ulceration. May cause cyanosis of the extremities. May cause skin
rash (in milder cases), and cold and clammy skin with cyanosis or
pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. May
cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause perforation of the digestive tract. May cause
corrosion and permanent tissue destruction of the esophagus and
digestive tract. Ingestion of large amounts may cause CNS
depression. May cause systemic effects.
Inhalation:
Irritation may lead to chemical pneumonitis and pulmonary edema.
Causes severe irritation of upper respiratory tract with coughing,
burns, breathing difficulty, and possible coma. Causes chemical
burns to the respiratory tract. Aspiration may lead to pulmonary
edema. Vapors may cause dizziness or suffocation. May cause systemic
effects. May cause burning sensation in the chest.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Wear appropriate
protective clothing to prevent contact with skin and eyes. Wear a
self-contained breathing apparatus (SCBA) to prevent contact with
thermal decomposition products. Contact with moisture or water may
generate sufficient heat to ignite nearby combustible materials.
Containers may explode in the heat of a fire. Vapors mixed with air
can explode when ignited. Flammable liquid and vapor. Reacts
violently with water.
Extinguishing Media:
Do NOT use water directly on fire. Use water spray to cool
fire-exposed containers. Water may be ineffective. Do NOT use alcohol
foams. Use dry chemical to fight fire. Use carbon dioxide. DO NOT USE
WATER! Do NOT use straight streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. Do
not expose spill to water. A vapor suppressing foam may be used to
reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use only in a well-ventilated area. Ground and bond containers when
transferring material. Use spark-proof tools and explosion proof
equipment. Do not breathe dust, vapor, mist, or gas. Empty containers
retain product residue, (liquid and/or vapor), and can be dangerous.
Keep container tightly closed. Avoid contact with heat, sparks and
flame. Do not ingest or inhale. Do not allow contact with water.
Prevent build up of vapors to explosive concentration. Discard
contaminated shoes. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose empty containers to heat, sparks or open
flames.
Storage:
Keep container closed when not in use. Keep from contact with
oxidizing materials. Store in a cool, dry, well-ventilated area away
from incompatible substances. Keep away from water. Flammables-area.
Keep away from strong bases. Separate from alcohols.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Personal Protective Equipment
Eyes:
Wear chemical goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant a respirator's use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless to light yellow
Odor: pungent odor
pH: Not available.
Vapor Pressure: 249 mm Hg @68F
Viscosity: Not available.
Boiling Point: 126 deg F
Freezing/Melting Point: -170 deg F
Autoignition Temperature: 734 deg F ( 390.00 deg C)
Flash Point: 40 deg F ( 4.44 deg C)
Explosion Limits, lower: 5.0
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Reacts with water.
Specific Gravity/Density: 1.10
Molecular Formula: C2H3ClO
Molecular Weight: 78.50
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials, ignition sources, contact with water, excess
heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, alcohols, amines, water and
mixtures containing water (e.g. aqueous solutions, water).
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 75-36-5: AO6390000
LD50/LC50:
CAS# 75-36-5: Oral, rat: LD50 = 910 mg/kg.
Carcinogenicity:
Acetyl chloride -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 11 Highly flammable.
R 14 Reacts violently with water.
R 34 Causes burns.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 75-36-5: 1
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 75-36-5 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 75-36-5 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #7 Date: 3/04/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1,2-Dichloroethane, extra dry, water <50 ppm
| 107-06-2 |
|
1-Pyrrolidinecarbodithioic acid, ammonium salt
| 5108-96-3 |
|
Cyclohexane, Extra Dry, Water <50 ppm
| 110-82-7 |
|
1,2-Cyclohexanedione, 98%
| 765-87-7 |
|
Dichloromethane, Extra Dry, Water <30 ppm
| 75-09-2 |
|
Ether, extra dry, water <50 ppm
| 60-29-7 |
|
Dimethylformamide, extra dry, water <30 ppm
| 68-12-2 |
|
Methyl sulfoxide, extra dry, water <50 ppm
| 67-68-5 |
|
1,4-Dioxane, extra dry, water <50 ppm
| 123-91-1 |
|
4-Acetamidophenol, 98%
| 103-90-2 |
|
Acetyl chloride
| 75-36-5 |
|
Ethyl Acetate, Extra Dry, Water <50 ppm
| 141-78-6 |
|
Rhodium(III) Chloride Trihydrate 38% Rh
| 20765-98-4 |
|
Ammonium Sulfate, Reagent ACS (crystals)
| 7783-20-2 |
|
n-Heptane, extra dry, water <30 ppm
| 108-87-2 |
|
n-Hexane, extra dry, water <20 ppm
| 110-54-3 |
|
N-Methylpyrrolidinone, extra dry, water <50 ppm
| 872-50-4 |
|
Ammonium thiocyanate, reagent acs (crystals)
| 1762-95-4 |
|
2,2,4-Trimethylpentane, extra dry, water <30 ppm
| 540-84-1 |
|
Methyl alcohol, extra dry, water <50 ppm
| 67-56-1 |
|
Disperse Orange 1
| 2581-69-3 |
|
Isopropanol, Extra Dry, Water <50 ppm
| 67-63-0 |
|
Ammonium metavanadate, p.a.
| 7803-55-6 |
|
Tetrahydrofuran, Extra Dry, Water <50 ppm
| 109-99-9 |
|
Aniline, P.A.
| 62-53-3 |
|
Toluene, Extra Dry, Water <10 ppm
| 108-88-3 |
|
Antimony, p.a., powder, 0.15 mm
| 7440-36-0 |
|
Benzyltriphenylphosphonium Tetrafluoroborate, 97%
| 31240-52-5 |
|
n-Butyrophenone, 99%
| 495-40-9 |
|
Potassium antimonyl-tartrate hemihydrate 99+%
| 28300-74-5 |
|
2,3-Dimethylfuran, 99%
| 14920-89-9 |
|
Tween 85
| 9055-70-3 |
|
Antimony trichloride, reagent ACS, crystals, 99+%
| 10025-91-9 |
|
Tween 40
| 9005-66-7 |
|
Antimony(III) Oxide, 99+%
| 1309-64-4 |
|
2-Amino-3,5-Dibromobenzaldehyde, 97%
| 50910-55-9 |
|
Piperonyl Butoxide, Tech., 90%
| 51-03-6 |
|
Arsenic (III) Oxide, P.A.
| 1327-53-3 |
|
4'-Bromo-3-Chloropropiophenone, 99%
| 31736-73-9 |
|
l(+)-Aspartic acid, 98+%
| 56-84-8 |
|
Meldola's Blue
| 7057-57-0 |
|
d-(+)-Isoascorbic acid,sodium salt, 98%
| 6381-77-7 |
|
Auramine O (Cert)
| 2465-27-2 |
|
4-Bromomethyl-3-Nitrobenzoic Acid
| 55715-03-2 |
|
Barbituric Acid, 99+%
| 67-52-7 |
|
3-(Trifluoromethoxy)Cinnamic Acid
| 0-01-1 |
|
(S)-(+)-Nalpha-Benzyl-N??-BOC-L-Hydrazinovaline
| 0-01-1 |
|
1,2-Epoxy-9-Decene, 96%
| 85721-25-1 |
|
Barium Acetate, Reagent ACS (Granular)
| 543-80-6 |
|
trans-1,4-Dichloro-2-butene, 95%
| 110-57-6 |
|
|