**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 55715-03-2 |4-Bromomethyl-3-Nitrobenzoic Acid | ca. 100 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears). May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause systemic effects. May cause cardiac effects such as
tachyardia and shock.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be
fatal as a result of spasm, inflammation, edema of the larynx and
bronchi, chemical pneumonitis and pulmonary edema. Aspiration may
lead to pulmonary edema. May cause systemic effects. May cause
Central Nervous System Effects characterized by apathy, mental
confusion, blurred vision, and tremors.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Containers
may explode in the heat of a fire. Contact with metals may evolve
flammable hydrogen gas.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Substance is
noncombustible; use agent most appropriate to extinguish surrounding
fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Minimize dust generation and accumulation. Do not breathe dust,
vapor, mist, or gas. Do not get in eyes, on skin, or on clothing.
Keep container tightly closed. Do not ingest or inhale. Use only in
a chemical fume hood. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 55715-03-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 127 - 130 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C8H6BrNO4
Molecular Weight: 259.9503
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 55715-03-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Bromomethyl-3-Nitrobenzoic Acid -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Pseudomonas putida:
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8,39C
UN Number: 3261
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 55715-03-2: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 55715-03-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 55715-03-2 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 10/26/1998 Revision #3 Date: 3/04/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1,2-Dichloroethane, extra dry, water <50 ppm
| 107-06-2 |
|
1-Pyrrolidinecarbodithioic acid, ammonium salt
| 5108-96-3 |
|
Cyclohexane, Extra Dry, Water <50 ppm
| 110-82-7 |
|
1,2-Cyclohexanedione, 98%
| 765-87-7 |
|
Dichloromethane, Extra Dry, Water <30 ppm
| 75-09-2 |
|
Ether, extra dry, water <50 ppm
| 60-29-7 |
|
Dimethylformamide, extra dry, water <30 ppm
| 68-12-2 |
|
Methyl sulfoxide, extra dry, water <50 ppm
| 67-68-5 |
|
1,4-Dioxane, extra dry, water <50 ppm
| 123-91-1 |
|
4-Acetamidophenol, 98%
| 103-90-2 |
|
Acetyl chloride
| 75-36-5 |
|
Ethyl Acetate, Extra Dry, Water <50 ppm
| 141-78-6 |
|
Rhodium(III) Chloride Trihydrate 38% Rh
| 20765-98-4 |
|
Ammonium Sulfate, Reagent ACS (crystals)
| 7783-20-2 |
|
n-Heptane, extra dry, water <30 ppm
| 108-87-2 |
|
n-Hexane, extra dry, water <20 ppm
| 110-54-3 |
|
N-Methylpyrrolidinone, extra dry, water <50 ppm
| 872-50-4 |
|
Ammonium thiocyanate, reagent acs (crystals)
| 1762-95-4 |
|
2,2,4-Trimethylpentane, extra dry, water <30 ppm
| 540-84-1 |
|
Methyl alcohol, extra dry, water <50 ppm
| 67-56-1 |
|
Disperse Orange 1
| 2581-69-3 |
|
Isopropanol, Extra Dry, Water <50 ppm
| 67-63-0 |
|
Ammonium metavanadate, p.a.
| 7803-55-6 |
|
Tetrahydrofuran, Extra Dry, Water <50 ppm
| 109-99-9 |
|
Aniline, P.A.
| 62-53-3 |
|
Toluene, Extra Dry, Water <10 ppm
| 108-88-3 |
|
Antimony, p.a., powder, 0.15 mm
| 7440-36-0 |
|
Benzyltriphenylphosphonium Tetrafluoroborate, 97%
| 31240-52-5 |
|
n-Butyrophenone, 99%
| 495-40-9 |
|
Potassium antimonyl-tartrate hemihydrate 99+%
| 28300-74-5 |
|
2,3-Dimethylfuran, 99%
| 14920-89-9 |
|
Tween 85
| 9055-70-3 |
|
Antimony trichloride, reagent ACS, crystals, 99+%
| 10025-91-9 |
|
Tween 40
| 9005-66-7 |
|
Antimony(III) Oxide, 99+%
| 1309-64-4 |
|
2-Amino-3,5-Dibromobenzaldehyde, 97%
| 50910-55-9 |
|
Piperonyl Butoxide, Tech., 90%
| 51-03-6 |
|
Arsenic (III) Oxide, P.A.
| 1327-53-3 |
|
4'-Bromo-3-Chloropropiophenone, 99%
| 31736-73-9 |
|
l(+)-Aspartic acid, 98+%
| 56-84-8 |
|
Meldola's Blue
| 7057-57-0 |
|
d-(+)-Isoascorbic acid,sodium salt, 98%
| 6381-77-7 |
|
Auramine O (Cert)
| 2465-27-2 |
|
4-Bromomethyl-3-Nitrobenzoic Acid
| 55715-03-2 |
|
Barbituric Acid, 99+%
| 67-52-7 |
|
3-(Trifluoromethoxy)Cinnamic Acid
| 0-01-1 |
|
(S)-(+)-Nalpha-Benzyl-N??-BOC-L-Hydrazinovaline
| 0-01-1 |
|
1,2-Epoxy-9-Decene, 96%
| 85721-25-1 |
|
Barium Acetate, Reagent ACS (Granular)
| 543-80-6 |
|
trans-1,4-Dichloro-2-butene, 95%
| 110-57-6 |
|
|