**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7803-55-6 |Ammonium metavanadate | ca.100 | 232-261-3
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 25 33 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic if swallowed. Danger of cumulative effects. Irritating to
eyes, respiratory system and skin.Hygroscopic.
Potential Health Effects
Eye:
Contact produces irritation, tearing, and burning pain. May cause
conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
Harmful if swallowed. Causes gastrointestinal irritation with
nausea, vomiting and diarrhea. Vanadium compounds can cause
polycythemia, followed by red blood cell destruction, anemia, loss
of appetite, pallor, and emaciation. May cause greenish-black tongue
discoloration due to deposition of vanadium salts.
Inhalation:
May be fatal if inhaled. Causes upper respiratory tract irritation.
Causes irritation of the mucous membrane. Inhalation may cause sore
throat, shortness of breath, labored breathing, coughing, and
pulmonary edema.
Chronic:
Repeated exposure may cause sensitization dermatitis. Chronic
exposure may cause a greenish tongue, metallic taste, cough, chronic
bronchitis, and emphysema. Material is a potent enzyme inhibitor.
Effects may be delayed. Laboratory experiments have resulted in
mutagenic effects. May cause adverse reproductive effects. May
produce scattered allergy-like eczematous skin lesions symptomatic of
vanadium toxicity.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of soap and
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting
unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air
immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Green coloration of the tongue, resulting from the deposition of
vanadium salts is an indicator of exposure; however, may be absent
even in prolonged exposure.. Treat symptomatically and supportively.
Effects may be delayed.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. This
material in sufficient quantity and reduced particle size is capable
of creating a dust explosion.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid runoff into storm sewers and ditches which lead to
waterways. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions. Use
water spray to disperse the gas/vapor. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Do not
breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or
on clothing. Keep container tightly closed. Do not ingest or inhale.
Use only in a chemical fume hood.
Storage:
Keep away from heat, sparks, and flame. Do not store near
combustible materials. Keep container closed when not in use. Store
in a tightly closed container. Store in a cool, dry, well-ventilated
area away from incompatible substances. Store protected from
moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use only under a
chemical fume hood.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant a respirator's use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: white - slightly yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 200 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 200 deg C
Solubility in water: 6.2 g/l (15 c)
Specific Gravity/Density: 2.3260g/cm3
Molecular Formula: H4NO3V
Molecular Weight: 116.98
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, exposure to moist air or
water, excess light.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, moisture.
Hazardous Decomposition Products:
Oxides of nitrogen, irritating and toxic fumes and gases, vanadium
oxide (VOx) gases, ammonia.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7803-55-6: YW0875000
LD50/LC50:
Not available.
Carcinogenicity:
Ammonium metavanadate -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Goldfish: LC50 = 1.5 - 3.8; 144 Hr; UnspecifiedFish: Goldfish:
LC50 = 1.5 - 3.8 mg/L; 144 Hr; unspecified
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: AMMONIUM METAVANADATE
Hazard Class: 6.1
UN Number: 2859
Packing Group: II
IMO
Shipping Name: AMMONIUM METAVANADATE
Hazard Class: 6.1
UN Number: 2859
Packing Group: II
RID/ADR
Shipping Name: AMMONIUM METAVANADATE
Hazard Class: 6.1
UN Number: 2859
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 25 Toxic if swallowed.
R 33 Danger of cumulative effects.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 22 Do not breathe dust.
S 24/25 Avoid contact with skin and eyes.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7803-55-6: No information available.
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 7803-55-6 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 7803-55-6: OEL-AUSTRALIA:TWA 0.05 mg(V2O5)/m3 JANUARY 1993
OEL-BELGIUM:TWA 0.05 mg(V2O5)/m3 JANUARY 1993
OEL-DENMARK:TWA 0.03 mg(V2O5)/m3 JANUARY 1993
OEL-FINLAND:TWA 0.5 mg(V2O5)/m3 JANUARY 1993
OEL-FRANCE:TWA 0.05 mg(V2O5)/m3 JANUARY 1993
OEL-GERMANY:TWA 0.05 mg(V2O5)/m3 JANUARY 1993
OEL-HUNGARY:TWA 0.05 mg(V2O5)/m3;STEL 0.1 mg(V205)/m3 JANUARY 1993
OEL-JAPAN:TWA 0.5 mg(V2O5)/m3 JANUARY 1993
OEL-THE NETHERLANDS:TWA 0.5 mg(V2O5)/m3 JANUARY 1993
OEL-THE PHILIPPINES:TWA 0.25 mg(V205)/m3 JANUARY 1993
OEL-POLAND:TWA 0.5 mg(V2O5)/m3 JANUARY 1993
OEL-SWEDEN:STEL 0.05 mg(V2O5)/m3 JANUARY 1993
OEL-SWEDEN:TWA 0.2 mg(V2O5)/m3 (dust)
OEL-SWITZERLAND:TWA 0.05 mg(V2O5)/m3;STEL 0.25 mg(V2O5)/m3
OEL-TURKEY:TWA 0.5 mg(V2O5)/m3 JANUARY 1993
OEL-UNITED KINGDOM:TWA 0.05 mg(V2O5)/m3 (dust)
OEL-UNITED KINGDOM:TWA 0.5 mg(V2O5)/m3 JANUARY 1993
US FEDERAL
TSCA
CAS# 7803-55-6 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/04/1999 Revision #2 Date: 12/03/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1,2-Dichloroethane, extra dry, water <50 ppm
| 107-06-2 |
|
1-Pyrrolidinecarbodithioic acid, ammonium salt
| 5108-96-3 |
|
Cyclohexane, Extra Dry, Water <50 ppm
| 110-82-7 |
|
1,2-Cyclohexanedione, 98%
| 765-87-7 |
|
Dichloromethane, Extra Dry, Water <30 ppm
| 75-09-2 |
|
Ether, extra dry, water <50 ppm
| 60-29-7 |
|
Dimethylformamide, extra dry, water <30 ppm
| 68-12-2 |
|
Methyl sulfoxide, extra dry, water <50 ppm
| 67-68-5 |
|
1,4-Dioxane, extra dry, water <50 ppm
| 123-91-1 |
|
4-Acetamidophenol, 98%
| 103-90-2 |
|
Acetyl chloride
| 75-36-5 |
|
Ethyl Acetate, Extra Dry, Water <50 ppm
| 141-78-6 |
|
Rhodium(III) Chloride Trihydrate 38% Rh
| 20765-98-4 |
|
Ammonium Sulfate, Reagent ACS (crystals)
| 7783-20-2 |
|
n-Heptane, extra dry, water <30 ppm
| 108-87-2 |
|
n-Hexane, extra dry, water <20 ppm
| 110-54-3 |
|
N-Methylpyrrolidinone, extra dry, water <50 ppm
| 872-50-4 |
|
Ammonium thiocyanate, reagent acs (crystals)
| 1762-95-4 |
|
2,2,4-Trimethylpentane, extra dry, water <30 ppm
| 540-84-1 |
|
Methyl alcohol, extra dry, water <50 ppm
| 67-56-1 |
|
Disperse Orange 1
| 2581-69-3 |
|
Isopropanol, Extra Dry, Water <50 ppm
| 67-63-0 |
|
Ammonium metavanadate, p.a.
| 7803-55-6 |
|
Tetrahydrofuran, Extra Dry, Water <50 ppm
| 109-99-9 |
|
Aniline, P.A.
| 62-53-3 |
|
Toluene, Extra Dry, Water <10 ppm
| 108-88-3 |
|
Antimony, p.a., powder, 0.15 mm
| 7440-36-0 |
|
Benzyltriphenylphosphonium Tetrafluoroborate, 97%
| 31240-52-5 |
|
n-Butyrophenone, 99%
| 495-40-9 |
|
Potassium antimonyl-tartrate hemihydrate 99+%
| 28300-74-5 |
|
2,3-Dimethylfuran, 99%
| 14920-89-9 |
|
Tween 85
| 9055-70-3 |
|
Antimony trichloride, reagent ACS, crystals, 99+%
| 10025-91-9 |
|
Tween 40
| 9005-66-7 |
|
Antimony(III) Oxide, 99+%
| 1309-64-4 |
|
2-Amino-3,5-Dibromobenzaldehyde, 97%
| 50910-55-9 |
|
Piperonyl Butoxide, Tech., 90%
| 51-03-6 |
|
Arsenic (III) Oxide, P.A.
| 1327-53-3 |
|
4'-Bromo-3-Chloropropiophenone, 99%
| 31736-73-9 |
|
l(+)-Aspartic acid, 98+%
| 56-84-8 |
|
Meldola's Blue
| 7057-57-0 |
|
d-(+)-Isoascorbic acid,sodium salt, 98%
| 6381-77-7 |
|
Auramine O (Cert)
| 2465-27-2 |
|
4-Bromomethyl-3-Nitrobenzoic Acid
| 55715-03-2 |
|
Barbituric Acid, 99+%
| 67-52-7 |
|
3-(Trifluoromethoxy)Cinnamic Acid
| 0-01-1 |
|
(S)-(+)-Nalpha-Benzyl-N??-BOC-L-Hydrazinovaline
| 0-01-1 |
|
1,2-Epoxy-9-Decene, 96%
| 85721-25-1 |
|
Barium Acetate, Reagent ACS (Granular)
| 543-80-6 |
|
trans-1,4-Dichloro-2-butene, 95%
| 110-57-6 |
|
|