**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| Not available |Tellurium | <1.0% | unlisted |
|----------------|--------------------------------------|----------|-----------|
| 1310-58-3 |Potassium Hydroxide | 2.0% | 215-181-3 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | Balance | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XI C
Risk Phrases: 35 36/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes severe burns. Irritating to eyes and
skin.Corrosive.Water-reactive.
Potential Health Effects
Eye:
Causes severe eye burns. May cause irreversible eye injury.
Contact may cause ulceration of the conjunctiva and cornea. Eye
damage may be delayed.
Skin:
Causes skin burns. May cause deep, penetrating ulcers of the skin.
Ingestion:
Harmful if swallowed. May cause circulatory system failure. May
cause perforation of the digestive tract. May cause cardiac
disturbances. Causes severe digestive tract burns with abdominal
pain, vomiting, and possible death. May cause central nervous system
effects.
Inhalation:
Harmful if inhaled. Irritation may lead to chemical pneumonitis and
pulmonary edema. May cause severe irritation of the respiratory
tract with sore throat, coughing, shortness of breath and delayed
lung edema. Causes chemical burns to the respiratory tract. May
cause cardiac abnormalities.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Prolonged
or repeated eye contact may cause conjunctivitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Discard contaminated clothing in a manner which limits
further exposure.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Use water with caution and in flooding amounts.
Contact with moisture or water may generate sufficient heat to ignite
nearby combustible materials.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Vacuum or sweep up material and
place into a suitable disposal container. Avoid generating dusty
conditions.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Do
not allow water to get into the container because of violent
reaction. Do not get in eyes, on skin, or on clothing. Do not ingest
or inhale.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep away
from strong acids. Keep away from water. Keep away from metals. Keep
away from flammable liquids. Keep away from organic halogens.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 236-81-3:
CAS# 1310-58-3:
United Kingdom, WEL - STEL: 2 mg/m3 STEL
Belgium - STEL: 2 mg/m3 VLE
France - VLE: 2 mg/m3 VLE
Japan: 2 mg/m3 Ceiling
Malaysia: 2 mg/m3 Ceiling
Spain: 2 mg/m3 VLA-EC
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: not available
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: miscible
Specific Gravity/Density:
Molecular Formula: Solution
Molecular Weight: 0
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable. Stable under normal temperatures and pressures. Readily
absorbs carbon dioxide and moisture from the air and deliquesces (to
absorb atmospheric water vapor and become liquid).
Conditions to Avoid:
Incompatible materials, moisture, contact with water, acids, metals.
Incompatibilities with Other Materials:
Generates large amounts of heat when in contact with water and may
steam and splatter. Reacts with chlorine dioxide, nitrobenzene,
nitromethane, nitrogen trichloride, peroxidized tetrahydrofuran,
2,4,6-trinitrotoluene, bromoform+ crown ethers, acids alcohols,
sugars, germanium cyclopentadiene, maleic dicarbide. Corrosive to
metals such as aluminum, tin, and zinc to cause formation of
flammable hydrogen gas.
Hazardous Decomposition Products:
Oxides of potassium.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 236-81-3 unlisted.
CAS# 1310-58-3: TT2100000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
Not available.
CAS# 1310-58-3: Draize test, rabbit, skin: 50 mg/24H Severe; Oral,
rat: LD50 = 273 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Tellurium -
Not listed by ACGIH, IARC, or NTP.
Potassium Hydroxide -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Mosquito Fish: LC50 = 80.0 mg/L; 24 Hr.; Unspecified
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: POTASSIUM HYDROXIDE SOLUTION
Hazard Class: 8
UN Number: 1814
Packing Group: II
IMO
Shipping Name: POTASSIUM HYDROXIDE SOLUTION
Hazard Class: 8
UN Number: 1814
Packing Group: II
RID/ADR
Shipping Name: POTASSIUM HYDROXIDE SOLUTION
Hazard Class: 8
UN Number: 1814
Packing group: II
USA RQ: CAS# 1310-58-3: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI C
Risk Phrases:
R 35 Causes severe burns.
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 2 Keep out of reach of children.
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 27 Take off immediately all contaminated clothing.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 236-81-3: No information available.
CAS# 1310-58-3: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 1310-58-3 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 236-81-3 is not listed on Canada's Ingredient Disclosure List.
CAS# 1310-58-3 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 236-81-3 is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 1310-58-3 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/02/1997 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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3,5-Dichloro-2-hydroxybenzenesulfonic Acid, Sodium Salt, 99%
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1,1,3,3-Tetramethylguanidine, 99% (gc)
| 80-70-6 |
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Carminic Acid 96%
| 1260-17-9 |
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Azelaic Acid, 98% (Titr.)
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4-Chlorobenzyl Mercaptan, 98%
| 6258-66-8 |
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3-Methyl-2-buten-1-ol, 99%
| 556-82-1 |
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2-Aminothiazole, 97%
| 96-50-4 |
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4-Fluorobenzyl bromide, 97%
| 459-46-1 |
|
2-Bromophenol, 98%
| 95-56-7 |
|
(s)-3-Isopropyl-2,5-piperazinedione, 99% ( hplc)
| 16944-60-8 |
|
Hydrogen tetrachloroaurate(III) hydrate, p.a.
| 16903-35-8 |
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Cholesteryl Linoleate
| 604-33-1 |
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Ethyl dibromoacetate tech., 83%
| 617-33-4 |
|
2-Thiophenecarbonitrile, 97%
| 1003-31-2 |
|
Oxazine 1 perchlorate, laser grade, 99+% (uv-vis)
| 24796-94-9 |
|
6-Methoxy-2-tetralone, 98%
| 2472-22-2 |
|
Sodium phosphate dibasic, dodecahydrate, p.a.
| 7558-79-4 |
|
2,4,5,6-Tetraaminopyrimidine Sulfate, 98%
| 5392-28-9 |
|
Prostaglandin VII, 96%
| 0-01-1 |
|
4-Anisylchlorodiphenylmethane, 97%
| 14470-28-1 |
|
Glycyl-L-histidyl-L-lysine acetate, 99%
| 62024-09-3 |
|
Methyl p-fluorobenzoylacetate, 99%
| 63131-29-3 |
|
N-Carbobenzyloxy-DL-Serine, 98%
| 2768-56-1 |
|
2,4,6-Trifluoroaniline, 97+%
| 363-81-5 |
|
2,2,6,6-Tetrachlorocyclohexanol, 98%
| 56207-45-5 |
|
Trimethylsulfonium bromide, 99% (titr.)
| 3084-53-5 |
|
3,5-Diaminobenzoic Acid Dihydrochloride, 99%
| 618-56-4 |
|
Perfluorodecalin (mixture of cis and trans), 95%
| 306-94-5 |
|
1-(4'-Iodophenyl)butane, 98%
| 20651-57-4 |
|
2-tert-Butylanthraquinone, 95%
| 84-47-9 |
|
2-Dimethylaminopyridine, 97%
| 5683-33-0 |
|
1-Propanesulfonyl chloride, 99% (titr.)
| 10147-36-1 |
|
5-Phenyl-o-anisidine, 98+%
| 39811-17-1 |
|
Glycoluril, 98+%
| 496-46-8 |
|
Acrolein, stabilized, 97%
| 107-02-8 |
|
2-(4-Methoxybenzoyl)Thiophene, 99%
| 4160-63-8 |
|
Cyclohexylamine, p.a.
| 108-91-8 |
|
2-(Methylthio)ethanol, 99%
| 5271-38-5 |
|
Penicillic Acid
| 90-65-3 |
|
N-Methylcyclohexylamine, 98%
| 100-60-7 |
|
Ethyl 4-Nitrobenzoate, 99%
| 99-76-3 |
|
Tellurium Atomic Absorption Standard Solution, 1 mg/ml Te in 2% KOH
| 236-81-3 |
|
L(-)-Perillyl Alcohol, 85%
| 536-59-4 |
|
4-Epi-Anhydrotetracycline Hydrochloride, "Can be used as Secondary
| 4465-65-0 |
|
Helicin, 99%
| 618-65-5 |
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Diethyl 2-Bromo-2-Methylmalonate, 98%
| 29263-94-3 |
|
Iminodibenzyl, 97%
| 494-19-9 |
|
N-Phthaloylglycine, 99%
| 4702-13-0 |
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(+)-Alpha-Pinene, 98%
| 7785-70-8 |
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3-Hydroxy-2-Naphthoic Acid, 98%
| 92-70-6 |
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|