**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 6258-66-8 |4-Chlorobenzyl Mercaptan | 98 | 228-395-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation and in contact with skin.Stench.
Potential Health Effects
Eye:
May cause eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
May cause irritation and dermatitis. May cause cyanosis of the
extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated. Mercaptans may cause nausea and headache.
Exposure to high concentrations of mercaptans can produce
unconsciousness with cyanosis (bluish discoloration of skin due to
deficient oxygenation of the blood), cold extremities and rapid
pulse.
Inhalation:
The toxicological properties of this substance have not been fully
investigated. Aspiration may lead to pulmonary edema. Exposure to
high concentrations of mercaptans can produce unconsciousness with
cyanosis (bluish discoloration of skin due to deficient oxygenation
of the blood), cold extremities and rapid pulse. Mercaptans may
cause nausea and headache. Inhalation at high concentrations may
cause CNS depression and asphixiation.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Contact with metals may evolve
flammable hydrogen gas. Containers may explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Do NOT get water
inside containers. For small fires, use dry chemical, carbon
dioxide, or water spray. For large fires, use dry chemical, carbon
dioxide, alcohol-resistant foam, or water spray.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 6258-66-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: stench
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 19.00 - 20.00 deg C
Autoignition Temperature: Not available.
Flash Point: 76 deg C ( 168.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.2020g/cm3
Molecular Formula: C7H7ClS
Molecular Weight: 158.65
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, oxides of sulfur, irritating and
toxic fumes and gases, carbon dioxide, hydrogen sulfide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 6258-66-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Chlorobenzyl Mercaptan -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: II
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: II
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21 Harmful by inhalation and in contact with
skin.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 6258-66-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 6258-66-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 6258-66-8 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3,5-Dichloro-2-hydroxybenzenesulfonic Acid, Sodium Salt, 99%
| 54970-72-8 |
|
1,1,3,3-Tetramethylguanidine, 99% (gc)
| 80-70-6 |
|
Carminic Acid 96%
| 1260-17-9 |
|
Azelaic Acid, 98% (Titr.)
| 123-99-9 |
|
4-Chlorobenzyl Mercaptan, 98%
| 6258-66-8 |
|
3-Methyl-2-buten-1-ol, 99%
| 556-82-1 |
|
2-Aminothiazole, 97%
| 96-50-4 |
|
4-Fluorobenzyl bromide, 97%
| 459-46-1 |
|
2-Bromophenol, 98%
| 95-56-7 |
|
(s)-3-Isopropyl-2,5-piperazinedione, 99% ( hplc)
| 16944-60-8 |
|
Hydrogen tetrachloroaurate(III) hydrate, p.a.
| 16903-35-8 |
|
Cholesteryl Linoleate
| 604-33-1 |
|
Ethyl dibromoacetate tech., 83%
| 617-33-4 |
|
2-Thiophenecarbonitrile, 97%
| 1003-31-2 |
|
Oxazine 1 perchlorate, laser grade, 99+% (uv-vis)
| 24796-94-9 |
|
6-Methoxy-2-tetralone, 98%
| 2472-22-2 |
|
Sodium phosphate dibasic, dodecahydrate, p.a.
| 7558-79-4 |
|
2,4,5,6-Tetraaminopyrimidine Sulfate, 98%
| 5392-28-9 |
|
Prostaglandin VII, 96%
| 0-01-1 |
|
4-Anisylchlorodiphenylmethane, 97%
| 14470-28-1 |
|
Glycyl-L-histidyl-L-lysine acetate, 99%
| 62024-09-3 |
|
Methyl p-fluorobenzoylacetate, 99%
| 63131-29-3 |
|
N-Carbobenzyloxy-DL-Serine, 98%
| 2768-56-1 |
|
2,4,6-Trifluoroaniline, 97+%
| 363-81-5 |
|
2,2,6,6-Tetrachlorocyclohexanol, 98%
| 56207-45-5 |
|
Trimethylsulfonium bromide, 99% (titr.)
| 3084-53-5 |
|
3,5-Diaminobenzoic Acid Dihydrochloride, 99%
| 618-56-4 |
|
Perfluorodecalin (mixture of cis and trans), 95%
| 306-94-5 |
|
1-(4'-Iodophenyl)butane, 98%
| 20651-57-4 |
|
2-tert-Butylanthraquinone, 95%
| 84-47-9 |
|
2-Dimethylaminopyridine, 97%
| 5683-33-0 |
|
1-Propanesulfonyl chloride, 99% (titr.)
| 10147-36-1 |
|
5-Phenyl-o-anisidine, 98+%
| 39811-17-1 |
|
Glycoluril, 98+%
| 496-46-8 |
|
Acrolein, stabilized, 97%
| 107-02-8 |
|
2-(4-Methoxybenzoyl)Thiophene, 99%
| 4160-63-8 |
|
Cyclohexylamine, p.a.
| 108-91-8 |
|
2-(Methylthio)ethanol, 99%
| 5271-38-5 |
|
Penicillic Acid
| 90-65-3 |
|
N-Methylcyclohexylamine, 98%
| 100-60-7 |
|
Ethyl 4-Nitrobenzoate, 99%
| 99-76-3 |
|
Tellurium Atomic Absorption Standard Solution, 1 mg/ml Te in 2% KOH
| 236-81-3 |
|
L(-)-Perillyl Alcohol, 85%
| 536-59-4 |
|
4-Epi-Anhydrotetracycline Hydrochloride, "Can be used as Secondary
| 4465-65-0 |
|
Helicin, 99%
| 618-65-5 |
|
Diethyl 2-Bromo-2-Methylmalonate, 98%
| 29263-94-3 |
|
Iminodibenzyl, 97%
| 494-19-9 |
|
N-Phthaloylglycine, 99%
| 4702-13-0 |
|
(+)-Alpha-Pinene, 98%
| 7785-70-8 |
|
3-Hydroxy-2-Naphthoic Acid, 98%
| 92-70-6 |
|
|