**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 95-56-7 |2-Bromophenol | 98 | 202-432-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 10 22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful if swallowed. Irritating to eyes, respiratory
system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation. Vapors may cause dizziness or
suffocation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable liquid and vapor.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Remove contaminated clothing and wash before reuse. Ground and bond
containers when transferring material. Use spark-proof tools and
explosion proof equipment. Avoid breathing dust, vapor, mist, or gas.
Avoid contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Use with adequate ventilation. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 95-56-7:
Russia: 0.3 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 195 deg C @ 760.00mmHg
Freezing/Melting Point: 5 deg C
Autoignition Temperature: Not applicable.
Flash Point: 42 deg C ( 107.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble
Specific Gravity/Density: 1.4920g/cm3
Molecular Formula: C6H5BrO
Molecular Weight: 173.01
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Acid chlorides, acid anhydrides, oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 95-56-7: SJ7875000
LD50/LC50:
CAS# 95-56-7: Oral, mouse: LD50 = 652 mg/kg.
Carcinogenicity:
2-Bromophenol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Bacteria: Phytobacterium phosphoreum: EC50 = 20.6-21.2 mg/L; 5,30
min; Microtox test at 15 C
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 10 Flammable.
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 28A After contact with skin, wash immediately with
plenty of water.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 95-56-7: No information available.
Canada
CAS# 95-56-7 is listed on Canada's NDSL List.
CAS# 95-56-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 95-56-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/18/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Carminic Acid 96%
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|
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| 459-46-1 |
|
2-Bromophenol, 98%
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|
(s)-3-Isopropyl-2,5-piperazinedione, 99% ( hplc)
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| 617-33-4 |
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| 1003-31-2 |
|
Oxazine 1 perchlorate, laser grade, 99+% (uv-vis)
| 24796-94-9 |
|
6-Methoxy-2-tetralone, 98%
| 2472-22-2 |
|
Sodium phosphate dibasic, dodecahydrate, p.a.
| 7558-79-4 |
|
2,4,5,6-Tetraaminopyrimidine Sulfate, 98%
| 5392-28-9 |
|
Prostaglandin VII, 96%
| 0-01-1 |
|
4-Anisylchlorodiphenylmethane, 97%
| 14470-28-1 |
|
Glycyl-L-histidyl-L-lysine acetate, 99%
| 62024-09-3 |
|
Methyl p-fluorobenzoylacetate, 99%
| 63131-29-3 |
|
N-Carbobenzyloxy-DL-Serine, 98%
| 2768-56-1 |
|
2,4,6-Trifluoroaniline, 97+%
| 363-81-5 |
|
2,2,6,6-Tetrachlorocyclohexanol, 98%
| 56207-45-5 |
|
Trimethylsulfonium bromide, 99% (titr.)
| 3084-53-5 |
|
3,5-Diaminobenzoic Acid Dihydrochloride, 99%
| 618-56-4 |
|
Perfluorodecalin (mixture of cis and trans), 95%
| 306-94-5 |
|
1-(4'-Iodophenyl)butane, 98%
| 20651-57-4 |
|
2-tert-Butylanthraquinone, 95%
| 84-47-9 |
|
2-Dimethylaminopyridine, 97%
| 5683-33-0 |
|
1-Propanesulfonyl chloride, 99% (titr.)
| 10147-36-1 |
|
5-Phenyl-o-anisidine, 98+%
| 39811-17-1 |
|
Glycoluril, 98+%
| 496-46-8 |
|
Acrolein, stabilized, 97%
| 107-02-8 |
|
2-(4-Methoxybenzoyl)Thiophene, 99%
| 4160-63-8 |
|
Cyclohexylamine, p.a.
| 108-91-8 |
|
2-(Methylthio)ethanol, 99%
| 5271-38-5 |
|
Penicillic Acid
| 90-65-3 |
|
N-Methylcyclohexylamine, 98%
| 100-60-7 |
|
Ethyl 4-Nitrobenzoate, 99%
| 99-76-3 |
|
Tellurium Atomic Absorption Standard Solution, 1 mg/ml Te in 2% KOH
| 236-81-3 |
|
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| 536-59-4 |
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| 4465-65-0 |
|
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| 618-65-5 |
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| 29263-94-3 |
|
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| 494-19-9 |
|
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| 4702-13-0 |
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| 7785-70-8 |
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| 92-70-6 |
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