**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 4422-95-1 |1,3,5-Benzenetricarboxylic acid chlori| 98 | 224-594-8 |
| |de | | |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears). May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract. The toxicological
properties of this substance have not been fully investigated.
Aspiration may lead to pulmonary edema. May cause systemic effects.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Do NOT use water directly on fire. Use foam, dry chemical, or carbon
dioxide. Use agent most appropriate to extinguish fire. Do NOT get
water inside containers. Use water spray, dry chemical, carbon
dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation. Do not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Do not get in eyes, on skin, or on
clothing. Keep container tightly closed. Do not ingest or inhale. Use
with adequate ventilation. Do not allow contact with water. Discard
contaminated shoes. Keep from contact with moist air and steam.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Corrosives area. Store protected from
moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 4422-95-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use. Wear a NIOSH/MSHA
or European Standard EN 149 approved full-facepiece
airline respirator in the positive pressure mode with
emergency escape provisions.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 180 deg C @ 16 mmHg
Freezing/Melting Point: 34.5-36 deg C
Autoignition Temperature: Not available.
Flash Point: > 112 deg C (> 233.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: decomposes
Specific Gravity/Density:
Molecular Formula: C9H3Cl3O3
Molecular Weight: 265.47
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Moisture.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, moisture.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 4422-95-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1,3,5-Benzenetricarboxylic acid chloride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S
Hazard Class: 8
UN Number: 3261
Packing Group: II
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S
Hazard Class: 8
UN Number: 3261
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S
Hazard Class: 8
UN Number: 3261
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 4422-95-1: No information available.
Canada
CAS# 4422-95-1 is listed on Canada's NDSL List.
CAS# 4422-95-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 4422-95-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #8 Date: 3/11/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Reagent Alcohol
| 64-17-5 |
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Rubidium bromide, 99%
| 7789-39-1 |
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Resorcinol
| 108-46-3 |
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Chloropicrin, 98+% (GC)
| 76-06-2 |
|
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| 497-37-0 |
|
Dimethyl 1-Methyl-Trans-1,2-Cyclopropanedicarboxylate, 99+%
| 702-92-1 |
|
Rhodamine B, 97% (UV-Vis)
| 81-88-9 |
|
1,3,5-Benzenetricarboxylic acid chloride, 98%
| 4422-95-1 |
|
Betha-(1,4)-2-acetamido-2-deoxy-d-glucose
| 1398-61-4 |
|
trans-2-Benzylamino-1-cyclohexanol, 99+%
| 40571-86-6 |
|
2-Aminopurine, 98%
| 452-06-2 |
|
Ethyl 1-piperidineglyoxylate, 99%
| 53074-96-7 |
|
(S)-(-)-2-Amino-4-Pentenoic Acid, 98% e.e.
| 16338-48-0 |
|
Riboflavin
| 83-88-5 |
|
N-Methyldiethanolamine, 99+%
| 105-59-9 |
|
Disperse Red 19
| 2734-52-3 |
|
(-)-Eburnamonine, 98+%
| 4877-93-4 |
|
2-(2-Pyrazinyl)malondialdehyde
| |
|
Isopropylamine
| 75-31-0 |
|
4-(Dicyanomethylene)-2-Methyl-6-(P-Dimethylaminostyryl)-4H-Pyran,
| 51325-91-8 |
|
Spironolactone, 99% (tlc)
| 52-01-7 |
|
Sodium Cyanoacetate, 50 wt% Aqueous Solution
| 1071-36-9 |
|
Isopropyl Salicylate, 99% (GC)
| 607-85-2 |
|
Rubidium Chloride
| 7791-11-9 |
|
D-Thyroxine, 97%
| 51-49-0 |
|
Cyclohexane Carboxamide, 97%
| 1122-56-1 |
|
(4-Aminobenzoyl)hydrazide, 95%
| 5351-17-7 |
|
1-Chloro-3-iodobenzene, 98%
| 625-99-0 |
|
2,6-Difluorobenzoylchloride 99%
| 18063-02-0 |
|
4-Bromothiophenol, 95%
| 106-53-6 |
|
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| 1641-40-3 |
|
4-Hydroxybutyric Acid, Sodium Salt, 99%
| 502-85-2 |
|
n-Acetyl-l-tyrosinamide
| 1948-71-6 |
|
9-Benzhydrylidene-10-anthrone
| 667-91-4 |
|
Dimethyl 5-nitroisophthalate, 98%
| 13290-96-5 |
|
Isonipecotic Acid, 99%
| 498-94-2 |
|
Sodium Hydride, 80% Dispersion in Mineral Oil, Toluene Soluble Bags
| 7646-69-7 |
|
Salicylic acid
| 69-72-7 |
|
2,6-Dibromo-4-Methylaniline 99%
| 6968-24-7 |
|
S(-)-alpha-methylbenzyl isocyanate, 95%
| 14649-03-7 |
|
Mercury(II) cyanide, 99%
| 592-04-1 |
|
3-Hydroxy-1H-Indazole, 99%
| 7364-25-2 |
|
2,2-Pentamethylene-1,3-Dioxolane, 99%
| 177-10-6 |
|
3-Bromopropylamine Hydrobromide, 98%
| 5003-71-4 |
|
4-Chlorophenoxyacetic acid, 98%
| 122-88-3 |
|
L(+)-2-Aminobutyric Acid, 98%
| 1492-24-6 |
|
Neomycin B Sulfate
| 119-04-0 |
|
Trichlorosilane, 99%
| 10025-78-2 |
|
1-Bromo-3-Iodobenzene, 98+%
| 591-18-4 |
|
2,6-Dichloroanisole, 99%
| 1984-65-2 |
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