**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 69-72-7 |Salicylic acid | >99 | 200-712-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 37/38 41
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to respiratory system and skin.
Risk of serious damage to eyes.Light sensitive.
Potential Health Effects
Eye:
Causes severe eye irritation. May result in corneal injury.
Skin:
Contact with skin causes irritation and possible burns, especially
if the skin is wet or moist. If absorbed, may cause symptoms similar
to those for ingestion. May cause skin rash and eruptions.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause "salicylism"; characterized by headache,
dizziness, ringing in the ears, hearing difficulty, visual
disturbances, mental confusion, drowsiness, sweating thirst,
hyperventilation, nausea, vomiting and diarrhea. May be harmful if
swallowed. Severe salicylate intoxication may cause central nervous
system disturbances such as convulsions and coma, skin eruptions, and
alteration in the acid-base balance.
Inhalation:
Causes irritation of the mucous membrane and upper respiratory
tract.
Chronic:
May cause reproductive and fetal effects. Laboratory experiments
have resulted in mutagenic effects. May cause salicylism with effects
similar to those of skin absorption. May cause damage to the kidneys
and pancrease.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting
unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Follow with gastric lavage with activated charcoal. If available,
administer ferric hexacyanoferrate as a gastrointestinal trapping
agent. Persons with pre-existing skin disorders, eye problems, or
impaired kidney function may be more susceptible to the effects of
this substance.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Dusts at sufficient concentrations can form
explosive mixtures with air. During a fire, irritating and highly
toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. Water or foam may cause frothing. Use agent
most appropriate to extinguish fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid generating dusty conditions. Remove all sources of
ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Avoid ingestion and inhalation.
Storage:
Keep away from sources of ignition. Do not store in direct sunlight.
Store in a cool, dry, well-ventilated area away from incompatible
substances. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 69-72-7:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: white
Odor: odorless - slight phenolic odor
pH: 2.4
Vapor Pressure: 0.000082 mm Hg
Viscosity: Not available.
Boiling Point: 211 deg C @ 20.00mm Hg
Freezing/Melting Point: 158 - 160 deg C
Autoignition Temperature: 535 deg C ( 995.00 deg F)
Flash Point: 157 deg C ( 314.60 deg F)
Explosion Limits, lower: 1.1 % @ 392F
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: 1.4400g/cm3
Molecular Formula: C7H6O3
Molecular Weight: 138.12
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Moisture sensitive.
Light sensitive. Darkens on exposure to light.
Conditions to Avoid:
High temperatures, incompatible materials, light, moisture, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents, lead acetate, iron salts, alkalis, iodine, spirit
nitrous ether.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 69-72-7: VO0525000
LD50/LC50:
CAS# 69-72-7: Draize test, rabbit, eye: 100 mg Severe; Draize test,
rabbit, skin: 500 mg/24H Mild; Inhalation, rat: LC50 = >900
mg/m3/1H; Oral, mouse: LD50 = 480 mg/kg; Oral, rabbit: LD50 = 1300
mg/kg; Oral, rat: LD50 = 891 mg/kg; Skin, rabbit: LD50 = >10 gm/kg;
Skin, rat: LD50 = >2 gm/kg.
Carcinogenicity:
Salicylic acid -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Bacteria: Phytobacterium phosphoreum: EC50 = 214 mg/L; 5 min;
Microtox testAdsorption, volatilization and bioconcentration are not
expected to be
important environmental fate processes.
Biodegradation is expected to be the dominant removal mechanism from
soil and water. It may also undergo
photochemical degradation in
sunlit environmental media.
Other
Dangerous to aquatic life in high concentrations.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 37/38 Irritating to respiratory system and skin.
R 41 Risk of serious damage to eyes.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 69-72-7: 1
Canada
CAS# 69-72-7 is listed on Canada's DSL List.
CAS# 69-72-7 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 69-72-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/10/1999 Revision #3 Date: 10/26/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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