Search   
MSDS 
:
 Isopropylamine
CAS 
:
 75-31-0
SYNONYMS 
:
 2-Aminopropane; 2-Propylamine; 2-Propanamine; sec-Propylamine;     Monoisopropylamine.
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 75-31-0 |Isopropylamine | 99 | 200-860-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI F+
Risk Phrases: 12 36/37/38

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Extremely flammable. Irritating to eyes, respiratory system and
skin.

Potential Health Effects
Eye:
Low vapor concentrations may cause a temporary visual disturbance
known as 'blue haze' or 'halo vision'. Causes eye irritation and
burns. May cause tearing, conjunctivitis and corneal edema when
vapor is absorbed into the tissue of the eye. Direct contact with
liquid may cause blindness or permanent eye damage.
Skin:
Harmful if absorbed through the skin. Causes severe skin irritation
and burns.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns. May cause
central nervous system effects.
Inhalation:
Can produce delayed pulmonary edema. Causes respiratory tract
irritation with possible burns.
Chronic:
Prolonged or repeated skin contact may cause dermatitis.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
Evacuate area and fight fire from a safe distance. As in any fire,
wear a self-contained breathing apparatus in pressure-demand,
MSHA/NIOSH (approved or equivalent), and full protective gear. During
a fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Extremely flammable liquid and vapor.
Vapor may cause flash fire. Approach fire from upwind to avoid
hazardous vapors and toxic decomposition products. Vapors are heavier
than air and may travel to a source of ignition and flash back.
Vapors can spread along the ground and collect in low or confined
areas.
Extinguishing Media:
Use water spray, dry chemical, "alcohol resistant" foam, or carbon
dioxide. Water may be ineffective because it will not cool material
below its flash point.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. Use
water spray to cool and disperse vapors, protect personnel, and
dilute spills to form nonflammable mixtures.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Ground and bond containers when transferring
material. Use spark-proof tools and explosion proof equipment. Do not
get in eyes, on skin, or on clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames. Do
not breathe vapor. Use only with adequate ventilation. Keep away from
heat, sparks and flame.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits. Use explosion-proof ventilation equipment.
Facilities storing or utilizing this material should be equipped with
an eyewash facility and a safety shower.
Exposure Limits
CAS# 75-31-0:
United States OSHA: 5 ppm TWA; 12 mg/m3 TWA
Belgium - TWA: 5 ppm VLE; 12 mg/m3 VLE
Belgium - STEL: 10 ppm VLE; 24 mg/m3 VLE
France - VME: 5 ppm VME; 12 mg/m3 VME
Germany: 5 ppm TWA; 12 mg/m3 TWA
Malaysia: 5 ppm TWA; 12 mg/m3 TWA
Netherlands: 5 ppm MAC; 12 mg/m3 MAC
Russia: 1 mg/m3 TWA
Spain: 5 ppm VLA-ED; 12 mg/m3 VLA-ED
Spain: 10 ppm VLA-EC; 24 mg/m3 VLA-EC

Personal Protective Equipment

Eyes:
Wear chemical splash goggles and face shield.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Liquid
Color: clear, colorless
Odor: ammonia-like
pH: 11.8 (0.1M aq soln)
Vapor Pressure: 580 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 33-34 deg C
Freezing/Melting Point: -101 deg C
Autoignition Temperature: 402 deg C ( 755.60 deg F)
Flash Point: -37 deg C ( -34.60 deg F)
Explosion Limits, lower: 2.0 vol %
Explosion Limits, upper: 10.4 vol %
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: 0.69
Molecular Formula: C3H9N
Molecular Weight: 59.11

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, ignition sources, confined spaces.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 75-31-0: NT8400000
LD50/LC50:
CAS# 75-31-0: Draize test, rabbit, eye: 100 uL Severe; Inhalation,
rat: LC50 = 4000 ppm/4H; Oral, mouse: LD50 = 2200 mg/kg; Oral,
rabbit: LD50 = 3200 mg/kg; Oral, rat: LD50 = 111 mg/kg; Skin,
rabbit: LD50 = 380 mg/kg.
Carcinogenicity:
Isopropylamine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****

Ecotoxicity:
Water flea Daphnia: EC50 = 91.5-91.6 mg/L; 48 Hr; UnspecifiedBased on
the vapor pressure, isopropylamine should rapidly evaporate from dry
surfaces, especially when present in high concn such as in spill
situations. The miscibility of isopropylamine in water suggests that
adsorption and bioconcentration, in addition to volatilization, are
not important fate processes. This is supported by low estimates for
the bioconcentration factor (log BCF = 0.43) and soil adsorption
coefficient (Koc = 33).

**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Shipping Name: ISOPROPYLAMINE
Hazard Class: 3 (8)
UN Number: 1221
Packing Group: I
IMO
Shipping Name: ISOPROPYLAMINE
Hazard Class: 3.1 (8)
UN Number: 1221
Packing Group: I
RID/ADR
Shipping Name: ISOPROPYLAMINE
Hazard Class: 3
UN Number: 1221
Packing group: I

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI F+
Risk Phrases:
R 12 Extremely flammable.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 29 Do not empty into drains.
WGK (Water Danger/Protection)
CAS# 75-31-0: 2
Canada
CAS# 75-31-0 is listed on Canada's DSL List.
CAS# 75-31-0 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 75-31-0 is listed on the TSCA inventory.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 6/17/1999 Revision #4 Date: 2/09/2004

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
Search More   
ALL MSDS PAGES IN THIS GROUP
NAMECAS
Reagent Alcohol 64-17-5
Rubidium bromide, 99% 7789-39-1
Resorcinol 108-46-3
Chloropicrin, 98+% (GC) 76-06-2
exo-Norborneol, 97% 497-37-0
Dimethyl 1-Methyl-Trans-1,2-Cyclopropanedicarboxylate, 99+% 702-92-1
Rhodamine B, 97% (UV-Vis) 81-88-9
1,3,5-Benzenetricarboxylic acid chloride, 98% 4422-95-1
Betha-(1,4)-2-acetamido-2-deoxy-d-glucose 1398-61-4
trans-2-Benzylamino-1-cyclohexanol, 99+% 40571-86-6
2-Aminopurine, 98% 452-06-2
Ethyl 1-piperidineglyoxylate, 99% 53074-96-7
(S)-(-)-2-Amino-4-Pentenoic Acid, 98% e.e. 16338-48-0
Riboflavin 83-88-5
N-Methyldiethanolamine, 99+% 105-59-9
Disperse Red 19 2734-52-3
(-)-Eburnamonine, 98+% 4877-93-4
2-(2-Pyrazinyl)malondialdehyde
Isopropylamine 75-31-0
4-(Dicyanomethylene)-2-Methyl-6-(P-Dimethylaminostyryl)-4H-Pyran, 51325-91-8
Spironolactone, 99% (tlc) 52-01-7
Sodium Cyanoacetate, 50 wt% Aqueous Solution 1071-36-9
Isopropyl Salicylate, 99% (GC) 607-85-2
Rubidium Chloride 7791-11-9
D-Thyroxine, 97% 51-49-0
Cyclohexane Carboxamide, 97% 1122-56-1
(4-Aminobenzoyl)hydrazide, 95% 5351-17-7
1-Chloro-3-iodobenzene, 98% 625-99-0
2,6-Difluorobenzoylchloride 99% 18063-02-0
4-Bromothiophenol, 95% 106-53-6
o-Phenylene phosphorochloridite, 97% 1641-40-3
4-Hydroxybutyric Acid, Sodium Salt, 99% 502-85-2
n-Acetyl-l-tyrosinamide 1948-71-6
9-Benzhydrylidene-10-anthrone 667-91-4
Dimethyl 5-nitroisophthalate, 98% 13290-96-5
Isonipecotic Acid, 99% 498-94-2
Sodium Hydride, 80% Dispersion in Mineral Oil, Toluene Soluble Bags 7646-69-7
Salicylic acid 69-72-7
2,6-Dibromo-4-Methylaniline 99% 6968-24-7
S(-)-alpha-methylbenzyl isocyanate, 95% 14649-03-7
Mercury(II) cyanide, 99% 592-04-1
3-Hydroxy-1H-Indazole, 99% 7364-25-2
2,2-Pentamethylene-1,3-Dioxolane, 99% 177-10-6
3-Bromopropylamine Hydrobromide, 98% 5003-71-4
4-Chlorophenoxyacetic acid, 98% 122-88-3
L(+)-2-Aminobutyric Acid, 98% 1492-24-6
Neomycin B Sulfate 119-04-0
Trichlorosilane, 99% 10025-78-2
1-Bromo-3-Iodobenzene, 98+% 591-18-4
2,6-Dichloroanisole, 99% 1984-65-2

Free MSDS Search ( Providing 250,000+ Material Properties )
Chemcas.com| Ads link:todaystock.net