**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 591-18-4 |1-Bromo-3-Iodobenzene | 98+ | 209-703-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Light sensitive.The
toxicological properties of this material have not been fully
investigated.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this
material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this
material have not been fully investigated.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. If irritation
develops, get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Wash clothing before
reuse. Get medical aid if symptoms occur.
Ingestion:
Never give anything by mouth to an unconscious person. Do NOT induce
vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls
of milk or water. Get medical aid if irritation or symptoms occur.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Containers may explode in
the heat of a fire.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Cool containers with flooding quantities of
water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Avoid contact
with eyes, skin, and clothing. Avoid ingestion and inhalation. Store
protected from light.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
Store protected from light.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits. Use process
enclosure, local exhaust ventilation, or other engineering controls
to control airborne levels.
Exposure Limits
CAS# 591-18-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149
approved full-facepiece airline respirator in the
positive pressure mode with emergency escape
provisions.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear very light yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 120 deg C @ 18.00mmHg
Freezing/Melting Point: 9.3 deg C
Autoignition Temperature: Not available.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density: 2.2190g/cm3
Molecular Formula: C6H4BrI
Molecular Weight: 282.89
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, hydrogen bromide, hydrogen iodide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 591-18-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-Bromo-3-Iodobenzene -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 591-18-4: No information available.
Canada
CAS# 591-18-4 is listed on Canada's NDSL List.
CAS# 591-18-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 591-18-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/16/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
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Chloropicrin, 98+% (GC)
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| 497-37-0 |
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| 702-92-1 |
|
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| 81-88-9 |
|
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| 4422-95-1 |
|
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| 1398-61-4 |
|
trans-2-Benzylamino-1-cyclohexanol, 99+%
| 40571-86-6 |
|
2-Aminopurine, 98%
| 452-06-2 |
|
Ethyl 1-piperidineglyoxylate, 99%
| 53074-96-7 |
|
(S)-(-)-2-Amino-4-Pentenoic Acid, 98% e.e.
| 16338-48-0 |
|
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| 83-88-5 |
|
N-Methyldiethanolamine, 99+%
| 105-59-9 |
|
Disperse Red 19
| 2734-52-3 |
|
(-)-Eburnamonine, 98+%
| 4877-93-4 |
|
2-(2-Pyrazinyl)malondialdehyde
| |
|
Isopropylamine
| 75-31-0 |
|
4-(Dicyanomethylene)-2-Methyl-6-(P-Dimethylaminostyryl)-4H-Pyran,
| 51325-91-8 |
|
Spironolactone, 99% (tlc)
| 52-01-7 |
|
Sodium Cyanoacetate, 50 wt% Aqueous Solution
| 1071-36-9 |
|
Isopropyl Salicylate, 99% (GC)
| 607-85-2 |
|
Rubidium Chloride
| 7791-11-9 |
|
D-Thyroxine, 97%
| 51-49-0 |
|
Cyclohexane Carboxamide, 97%
| 1122-56-1 |
|
(4-Aminobenzoyl)hydrazide, 95%
| 5351-17-7 |
|
1-Chloro-3-iodobenzene, 98%
| 625-99-0 |
|
2,6-Difluorobenzoylchloride 99%
| 18063-02-0 |
|
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| 106-53-6 |
|
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| 1641-40-3 |
|
4-Hydroxybutyric Acid, Sodium Salt, 99%
| 502-85-2 |
|
n-Acetyl-l-tyrosinamide
| 1948-71-6 |
|
9-Benzhydrylidene-10-anthrone
| 667-91-4 |
|
Dimethyl 5-nitroisophthalate, 98%
| 13290-96-5 |
|
Isonipecotic Acid, 99%
| 498-94-2 |
|
Sodium Hydride, 80% Dispersion in Mineral Oil, Toluene Soluble Bags
| 7646-69-7 |
|
Salicylic acid
| 69-72-7 |
|
2,6-Dibromo-4-Methylaniline 99%
| 6968-24-7 |
|
S(-)-alpha-methylbenzyl isocyanate, 95%
| 14649-03-7 |
|
Mercury(II) cyanide, 99%
| 592-04-1 |
|
3-Hydroxy-1H-Indazole, 99%
| 7364-25-2 |
|
2,2-Pentamethylene-1,3-Dioxolane, 99%
| 177-10-6 |
|
3-Bromopropylamine Hydrobromide, 98%
| 5003-71-4 |
|
4-Chlorophenoxyacetic acid, 98%
| 122-88-3 |
|
L(+)-2-Aminobutyric Acid, 98%
| 1492-24-6 |
|
Neomycin B Sulfate
| 119-04-0 |
|
Trichlorosilane, 99%
| 10025-78-2 |
|
1-Bromo-3-Iodobenzene, 98+%
| 591-18-4 |
|
2,6-Dichloroanisole, 99%
| 1984-65-2 |
|
|