**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 56-18-8 |3,3'-Iminobispropylamine | 98 | 200-261-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T+ C
Risk Phrases: 22 24 26 35 43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Toxic in contact with skin. Very toxic by
inhalation. Causes severe burns. May cause sensitization by skin
contact.Corrosive.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns.
Skin:
May be fatal if absorbed through the skin. May cause severe
irritation and possible burns.
Ingestion:
May cause severe gastrointestinal tract irritation with nausea,
vomiting and possible burns. May be harmful if swallowed.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. Causes
chemical burns to the respiratory tract.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Discard contaminated clothing in a manner which limits
further exposure. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use agent most appropriate to extinguish
fire. Do NOT get water inside containers. Contact with water or steam
may produce toxic and flammable vapors.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Do not get in
eyes, on skin, or on clothing. Do not ingest or inhale.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Corrosives area. Keep containers tightly closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 56-18-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: 0.05 mbar @ 20
Viscosity: Not available.
Boiling Point: 235 deg C @ 760.00mm Hg
Freezing/Melting Point: -14 deg C
Autoignition Temperature: 280 deg C ( 536.00 deg F)
Flash Point: 118 deg C ( 244.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Not available.
Specific Gravity/Density: .9380g/cm3
Molecular Formula: C6H17N3
Molecular Weight: 131.22
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents, strong acids, acid chlorides, acid anhydrides,
chloroformates.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 56-18-8: JL9450000
LD50/LC50:
CAS# 56-18-8: Draize test, rabbit, eye: 47 mg Severe; Inhalation,
rat: LC50 = 30 mg/m3/4H; Oral, mouse: LD50 = 435 mg/kg; Oral,
rabbit: LD50 = 210 mg/kg; Oral, rat: LD50 = 738 mg/kg; Skin, rabbit:
LD50 = 110 uL/kg.
Carcinogenicity:
3,3'-Iminobispropylamine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: 3,3'-IMINODIPROPYLAMINE
Hazard Class: 8
UN Number: 2269
Packing Group: III
IMO
Shipping Name: 3,3'-IMINODIPROPYLAMINE
Hazard Class: 8
UN Number: 2269
Packing Group: III
RID/ADR
Shipping Name: 3,3'-IMINODIPROPYLAMINE
Hazard Class: 8
UN Number: 2269
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+ C
Risk Phrases:
R 22 Harmful if swallowed.
R 24 Toxic in contact with skin.
R 26 Very toxic by inhalation.
R 35 Causes severe burns.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 56-18-8: 2
Canada
CAS# 56-18-8 is listed on Canada's DSL List.
CAS# 56-18-8 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 56-18-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/25/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
(-)-N,N,N',N'-TETRAMETHYL-D-TARTARAMIDE
| 63126-52-3 |
|
Acryloyl Chloride, Stabilized with 0.1% Phenothiazine, 98%
| 92-84-2 |
|
Calcium Nitrate Tetrahydrate, P.A.
| 13477-34-4 |
|
4-Nitrophthalic acid, 99% (titr.)
| 610-27-5 |
|
Anthracene, 99%
| 120-12-7 |
|
Anthracene, p.a.
| 120-12-7 |
|
Anthracene, scintillation grade
| 120-12-7 |
|
2-Thiouracil, 99% (Titr.)
| 141-90-2 |
|
Pyrene, ca 96%
| 129-00-0 |
|
Dowex 1x2-100 ion-exchange resin
| 9085-42-1 |
|
Dowex 1x2-400 ion-exchange resin
| 9085-42-1 |
|
Ethyl Methacrylate, 99%, Inhibited with 15 ppm Hydroquinone
| 97-63-2 |
|
Gadolinium(iii) nitrate pentahydrate, 99.9%
| 52788-53-1 |
|
Bromothymol Blue, Indicator
| 76-59-5 |
|
3-Nitrobenzenesulfonic Acid, Sodium Salt, 99%
| 127-68-4 |
|
2-(2-Aminoethylamino)-Ethanol, 97%
| 111-41-1 |
|
2,2,4-Trimethylpentane, spectrophotometric grade, 99%
| 540-84-1 |
|
2,2,4-Trimethylpentane density standard
| 540-84-1 |
|
2,2,4-Trimethylpentane, 99+%
| 540-84-1 |
|
2,2,4-Trimethylpentane, reagent ACS, spectro grade
| 540-84-1 |
|
2,2,4-Trimethylpentane, reagent ACS
| 540-84-1 |
|
2,2,4-Trimethylpentane, for HPLC
| 540-84-1 |
|
3-Amino-4-Chlorobenzenesulfonyl Fluoride, 99+%
| 368-72-9 |
|
Succinic Anhydride, 99%
| 108-30-5 |
|
2,6-Di-Tert.-Butylphenol, 99%
| 128-39-2 |
|
2-Acetylthiophene, 99%
| 88-15-3 |
|
Methylamine Hydrochloride, 98%
| 593-51-1 |
|
1-Octanesulfonic Acid, Sodium Salt Monohydrate, 98%
| 207596-29-0 |
|
Phenyl Salicylate, 99% (GC)
| 118-55-8 |
|
Diethylcarbamyl chloride, 99%
| 88-10-8 |
|
1,5-Naphthalenedisulfonic Acid Disodium Salt, Dihydrate, 98% (HPLC)
| 1655-29-4 |
|
1-Hexanethiol, 96%
| 111-31-9 |
|
2-Aminopyrimidine, 99%
| 109-12-6 |
|
Polystyrene: 1% Divinylbenzene Copolymer Beads, 100-200 Mesh
| 1321-74-0 |
|
Polystyrene: 2% Divinylbenzene Copolymer Beads, 200-400 Mesh
| 1321-74-0 |
|
Dl-sec-Butyl Acetate, 99%
| 105-46-4 |
|
Cyclohexylbenzene, 98-100%
| 827-52-1 |
|
3,3'-Iminobispropylamine, 98%
| 56-18-8 |
|
DL-Leucine, 99+%
| 328-39-2 |
|
Erythrosin B, high purity biological stain
| 16423-68-0 |
|
2-Chloropropionic acid, 98%
| 598-78-7 |
|
8-Hydroxyquinoline, 99%
| 148-24-3 |
|
Triethylene glycol di-p-tosylate, 98%
| 19249-03-7 |
|
3-Phenylphenol, 90%, Balance Mainly Para-Isomer
| 580-51-8 |
|
Potassium Tetraborate Tetrahydrate, 99.5%
| 12045-78-2 |
|
8-Hydroxyquinoline, reagent ACS
| 148-24-3 |
|
Neodymium(iii)-oxide, 99.999%
| 1313-97-9 |
|
2,4-Dichloro-6-nitroaniline, 99%
| 2683-43-4 |
|
Benzenesulfonamide, 98+%
| 98-10-2 |
|
1-Naphthaldehyde, 95%
| 66-77-3 |
|
|