**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 627-63-4 |Fumaryl Chloride | 95 | 211-005-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 21/22 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful in contact with skin and if swallowed. Causes burns.Moisture
sensitive.Corrosive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns. May be harmful if absorbed through the skin.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May be harmful if swallowed.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
Do NOT use water directly on fire. In case of fire, use water, dry
chemical, chemical foam, or alcohol-resistant foam. Use water spray
to cool fire-exposed containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Do not get on
skin or in eyes. Avoid ingestion and inhalation. Do not ingest or
inhale. Use with adequate ventilation. Discard contaminated shoes. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Store in a tightly
closed container. Store in a cool, dry, well-ventilated area away
from incompatible substances. Corrosives area. Store protected from
moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 627-63-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: 1.86 hPa @ 20 C
Viscosity: Not available.
Boiling Point: 161.0 - 164.0 deg C @ 760.00m
Freezing/Melting Point: -2 deg C
Autoignition Temperature: Not available.
Flash Point: 73 deg C ( 163.40 deg F)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: decomposes
Specific Gravity/Density: 1.4150g/cm3
Molecular Formula: C4H2Cl2O2
Molecular Weight: 152.96
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, irritating and toxic
fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 627-63-4: LT2800000
LD50/LC50:
CAS# 627-63-4: Draize test, rabbit, eye: 5 mg/24H Severe; Draize
test, rabbit, skin: 750 ug/24H Severe; Oral, rat: LD50 = 810 uL/kg;
Skin, rabbit: LD50 = 1410 uL/kg.
Carcinogenicity:
Fumaryl Chloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FUMARYL CHLORIDE
Hazard Class: 8
UN Number: 1780
Packing Group: II
IMO
Shipping Name: FUMARYL CHLORIDE
Hazard Class: 8
UN Number: 1780
Packing Group: II
RID/ADR
Shipping Name: FUMARYL CHLORIDE
Hazard Class: 8
UN Number: 1780
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 21/22 Harmful in contact with skin and if
swallowed.
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 627-63-4: No information available.
Canada
CAS# 627-63-4 is listed on Canada's DSL List.
CAS# 627-63-4 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 627-63-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/23/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Bromophenol, 99% (GC)
| 591-20-8 |
|
Furylacrylic acid, 99%
| 539-47-9 |
|
Cholesteryl Chloride, 98%
| 910-31-6 |
|
n-Tridecylamine, 98%
| 2869-34-3 |
|
1,2-Naphthoquinone-4-sulfonic acid sodium salt, 99%
| 521-24-4 |
|
Erythrosin b (cert)
| 16423-68-0 |
|
4'-(Trifluoromethyl)Acetophenone, 99%
| 709-63-7 |
|
Fumaryl Chloride, 95%
| 627-63-4 |
|
Thymol blue sodium salt, reagent acs
| 62625-21-2 |
|
Valeraldehyde, 98%
| 110-62-3 |
|
4-Heptylbenzoic acid, 99%
| 38350-87-7 |
|
3-(2-Iodoacetamido)-PROXYL, free radical
| 27048-01-7 |
|
2-Chloropropionic acid
| 598-78-7 |
|
7-Oxabicyclo(2.2.1)Heptane (1,4-Epoxy-Cyclohexane), 99%
| 279-49-2 |
|
1,1,1,3,3,3-Hexamethyldisilazane, 98%
| 999-97-3 |
|
L-(-)-Alpha-Bromocamphor-Pi-Sulfonic Acid Ammonium Salt 99%
| 55870-50-3 |
|
8-Hydroxyquinoline
| 148-24-3 |
|
Poly(vinyl ethyl ether), low molecular weight
| 25104-37-4 |
|
4,8-Dihydroxyquinoline-2-carboxylic acid, 96%
| 59-00-7 |
|
N-Carbobenzyloxy-L-phenylalanine, 99+%
| 1161-13-3 |
|
2-Thiophenemethylamine, 90-96% (GC)
| 27757-85-3 |
|
Brij 99 (Contains 0.01% BHA and 0.005% Citric Acid added as
| 9004-98-2 |
|
Neodymium(III) oxide, 99.9%
| 1313-97-9 |
|
2-Chlorooctane (pract), 99% (gc)
| 628-61-5 |
|
Nitrosulfonazo III, Indicator Grade
| 1964-89-2 |
|
Dimethyl itaconate, 97%
| 617-52-7 |
|
3-Chlorophenyl isocyanate
| 2909-38-8 |
|
5-(3-Hydroxyphenyl)-5-phenylhydantoin 99+%
| 30074-03-4 |
|
2-Chlorobenzyl cyanide, 97%
| 2856-63-5 |
|
3-Hydroxy-2-methyl-4-pyrone 99%
| 118-71-8 |
|
2,6-Diamino-8-Durinol Hemisulfate Monohydrate
| 123333-49-3 |
|
2'-Hydroxyacetophenone, 99%
| 118-93-4 |
|
Lutetium atomic absorption standard solution, 1 mg/ml Lu in 0.5N HNO3
| 7439-94-3 |
|
Bis(2-ethoxyethyl) adipate, 97% (GC)
| 109-44-4 |
|
1,3-Dibromo-5-Fluoro-2-Iodobenzene, 99+%
| 62720-29-0 |
|
2-Cyanoacetamide, 99%
| 107-91-5 |
|
Molecular Sieves, 4A, 1-2 mm (10 to 18 Mesh)
| 0-00-1 |
|
Barium Cyclohexanebutyrate, 99%, ex Barium
| 62669-65-2 |
|
4-(N-Ethyl-N-2-methanesulfonylaminoethyl)-2-methylphenylenediamine
| 25646-71-3 |
|
Sodium Nitroprusside Dihydrate
| 13755-38-9 |
|
4-(4-Chlorobenzyl)-Pyridine, 98%
| 4409-11-4 |
|
N-(3'-Aminopropyl)-2-Pyrrolidinone, 95% (GC)
| 7663-77-6 |
|
11-Bromo-1-undecanol, 97%
| 1611-56-9 |
|
Heneicosanoic acid, 99%(gc)
| 2363-71-5 |
|
(-)-2-Azabicyclo[2.2.1]hept-5-en-3-one, 98%, >95% e.e.
| 79200-56-9 |
|
Coumarin 314, Laser Grade, 99% (UV-Vis)
| 55804-66-5 |
|
(+)-p-(2-Methylbutyl)benzoyl chloride, 98%
| 62796-32-1 |
|
S-Benzylthioglycolic Acid, 97%
| 103-46-8 |
|
N-Carbobenzyloxy-L-Leucine, 95%
| 2018-66-8 |
|
Isopropyl Methanesulfonate
| 926-06-7 |
|
|