**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 79200-56-9 |(-)-2-Azabicyclo[2.2.1]hept-5-en-3-one| 98 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 41 43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Risk of serious damage to eyes. May cause
sensitization by skin contact.
Potential Health Effects
Eye:
Causes severe eye irritation and possible burns.
Skin:
May cause skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated.
Chronic:
Repeated exposure may cause sensitization dermatitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse. Remove contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid. Get medical aid immediately. Do NOT induce vomiting. If
conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or
water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. This
material in sufficient quantity and reduced particle size is capable
of creating a dust explosion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid breathing dust.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 79200-56-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: off-white to beige
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 92 - 100 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C6H7NO
Molecular Weight: 109.13
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 79200-56-9 unlisted.
LD50/LC50:
Not available.
Oral rat LD50: 671 mg/kg.
Carcinogenicity:
(-)-2-Azabicyclo[2.2.1]hept-5-en-3-one -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 41 Risk of serious damage to eyes.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 24 Avoid contact with skin.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 79200-56-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 79200-56-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 79200-56-9 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 4/01/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Bromophenol, 99% (GC)
| 591-20-8 |
|
Furylacrylic acid, 99%
| 539-47-9 |
|
Cholesteryl Chloride, 98%
| 910-31-6 |
|
n-Tridecylamine, 98%
| 2869-34-3 |
|
1,2-Naphthoquinone-4-sulfonic acid sodium salt, 99%
| 521-24-4 |
|
Erythrosin b (cert)
| 16423-68-0 |
|
4'-(Trifluoromethyl)Acetophenone, 99%
| 709-63-7 |
|
Fumaryl Chloride, 95%
| 627-63-4 |
|
Thymol blue sodium salt, reagent acs
| 62625-21-2 |
|
Valeraldehyde, 98%
| 110-62-3 |
|
4-Heptylbenzoic acid, 99%
| 38350-87-7 |
|
3-(2-Iodoacetamido)-PROXYL, free radical
| 27048-01-7 |
|
2-Chloropropionic acid
| 598-78-7 |
|
7-Oxabicyclo(2.2.1)Heptane (1,4-Epoxy-Cyclohexane), 99%
| 279-49-2 |
|
1,1,1,3,3,3-Hexamethyldisilazane, 98%
| 999-97-3 |
|
L-(-)-Alpha-Bromocamphor-Pi-Sulfonic Acid Ammonium Salt 99%
| 55870-50-3 |
|
8-Hydroxyquinoline
| 148-24-3 |
|
Poly(vinyl ethyl ether), low molecular weight
| 25104-37-4 |
|
4,8-Dihydroxyquinoline-2-carboxylic acid, 96%
| 59-00-7 |
|
N-Carbobenzyloxy-L-phenylalanine, 99+%
| 1161-13-3 |
|
2-Thiophenemethylamine, 90-96% (GC)
| 27757-85-3 |
|
Brij 99 (Contains 0.01% BHA and 0.005% Citric Acid added as
| 9004-98-2 |
|
Neodymium(III) oxide, 99.9%
| 1313-97-9 |
|
2-Chlorooctane (pract), 99% (gc)
| 628-61-5 |
|
Nitrosulfonazo III, Indicator Grade
| 1964-89-2 |
|
Dimethyl itaconate, 97%
| 617-52-7 |
|
3-Chlorophenyl isocyanate
| 2909-38-8 |
|
5-(3-Hydroxyphenyl)-5-phenylhydantoin 99+%
| 30074-03-4 |
|
2-Chlorobenzyl cyanide, 97%
| 2856-63-5 |
|
3-Hydroxy-2-methyl-4-pyrone 99%
| 118-71-8 |
|
2,6-Diamino-8-Durinol Hemisulfate Monohydrate
| 123333-49-3 |
|
2'-Hydroxyacetophenone, 99%
| 118-93-4 |
|
Lutetium atomic absorption standard solution, 1 mg/ml Lu in 0.5N HNO3
| 7439-94-3 |
|
Bis(2-ethoxyethyl) adipate, 97% (GC)
| 109-44-4 |
|
1,3-Dibromo-5-Fluoro-2-Iodobenzene, 99+%
| 62720-29-0 |
|
2-Cyanoacetamide, 99%
| 107-91-5 |
|
Molecular Sieves, 4A, 1-2 mm (10 to 18 Mesh)
| 0-00-1 |
|
Barium Cyclohexanebutyrate, 99%, ex Barium
| 62669-65-2 |
|
4-(N-Ethyl-N-2-methanesulfonylaminoethyl)-2-methylphenylenediamine
| 25646-71-3 |
|
Sodium Nitroprusside Dihydrate
| 13755-38-9 |
|
4-(4-Chlorobenzyl)-Pyridine, 98%
| 4409-11-4 |
|
N-(3'-Aminopropyl)-2-Pyrrolidinone, 95% (GC)
| 7663-77-6 |
|
11-Bromo-1-undecanol, 97%
| 1611-56-9 |
|
Heneicosanoic acid, 99%(gc)
| 2363-71-5 |
|
(-)-2-Azabicyclo[2.2.1]hept-5-en-3-one, 98%, >95% e.e.
| 79200-56-9 |
|
Coumarin 314, Laser Grade, 99% (UV-Vis)
| 55804-66-5 |
|
(+)-p-(2-Methylbutyl)benzoyl chloride, 98%
| 62796-32-1 |
|
S-Benzylthioglycolic Acid, 97%
| 103-46-8 |
|
N-Carbobenzyloxy-L-Leucine, 95%
| 2018-66-8 |
|
Isopropyl Methanesulfonate
| 926-06-7 |
|
|