**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 67-63-0 |Isopropyl alcohol | 99.5 % | 200-661-7 |
|----------------|--------------------------------------|----------|-----------|
| 77-09-8 |Phenolphthalein | 0.5 % | 201-004-7 |
+----------------+--------------------------------------+----------+-----------+
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
Produces irritation, characterized by a burning sensation, redness,
tearing, inflammation, and possible corneal injury.
Skin:
Prolonged and/or repeated contact may cause defatting of the skin
and dermatitis. May cause irritation with pain and stinging,
especially if the skin is abraded.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause kidney damage. May cause central nervous system
depression, characterized by excitement, followed by headache,
dizziness, drowsiness, and nausea. Advanced stages may cause
collapse, unconsciousness, coma and possible death due to respiratory
failure.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by headache, dizziness, unconsciousness and
coma. Inhalation of vapor may cause respiratory tract irritation.
Chronic:
Possible cancer hazard based on tests with laboratory animals.
Prolonged or repeated skin contact may cause defatting and
dermatitis. Prolonged or repeated exposure may cause adverse
reproductive effects. May cause kidney injury.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower lids. Get medical aid
immediately.
Skin:
Flush skin with plenty of soap and water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air
immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Use water
spray to keep fire-exposed containers cool. Containers may explode
in the heat of a fire. This chemical poses an explosion hazard.
Flammable Liquid. May form explosive peroxides. Vapors may be heavier
than air. They can spread along the ground and collect in low or
confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water. Cool containers with flooding quantities of water until well
after fire is out.
Autoignition Temperature: 750 deg F ( 398.89 deg C)
Flash Point: 75 deg F ( 23.89 deg C)
NFPA Rating: Not published.
Explosion Limits, Lower: 2.0
Upper: 12.7
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material, (e.g., dry sand or earth), then
place into a chemical waste container. Remove all sources of
ignition. A vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Ground and bond
containers when transferring material. Use spark-proof tools and
explosion proof equipment. Avoid contact with eyes, skin, and
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Avoid
contact with heat, sparks and flame. Avoid ingestion and inhalation.
Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep from contact with oxidizing materials. Store in a
cool, dry, well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133.
Skin:
Wear appropriate protective clothing to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29CFR
1910.134. Always use a NIOSH-approved respirator when
necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Appearance: colourless
Odor: alcohol-like
pH: Not available.
Vapor Pressure: 40 mm Hg
Vapor Density: 2.1 (air=1)
Evaporation Rate: 2.88 (butyl acetate=1)
Viscosity: Not available.
Boiling Point: 83 deg C
Freezing/Melting Point: -129 deg C
Decomposition Temperature: Not available.
Solubility: Not available.
Specific Gravity/Density: 0.7855
Molecular Formula: Mixture
Molecular Weight: Not applicable
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. This material may be
sensitive to peroxide formation.
Conditions to Avoid:
This material may be sensitive to peroxide formation., incompatible
materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
2-Propanol is incompatible with strong oxidizers, acetaldeyde,
chlorine, ethylene oxide, acids and isocyanates, hydrogen +
palladium, nitroform, oleum, phosgene, potassium t-butoxide, oxygen,
trinitromethane, barium perchlorate, tetrafluoroborate, chromium
trioxide, sodium dichromate + sulfuric acid, aluminum, and aluminum
triisopropoxide. It also has been reported to be susceptible to
autoxidation and should therefore be considered peroxidizable.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, acrid smoke and fumes.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 67-63-0: NT8050000
CAS# 77-09-8: SM8380000
LD50/LC50:
CAS# 67-63-0: Oral, mouse: LD50 = 3600 mg/kg; Oral, rabbit: LD50 =
6410 mg/kg; Oral, rat: LD50 = 5045 mg/kg; Skin, rabbit: LD50 = 12800
mg/kg.
CAS# 77-09-8.
Carcinogenicity:
Isopropyl alcohol -
IARC: Group 3 carcinogen
Phenolphthalein -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
For further information, contact Fisher Scientific.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
CDG/CPL
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3260
Packing Group: III
IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3260
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.
Dangerous Goods Code: 8(16C)
UN Number: 3260
Canadian TDG
No information available.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 67-63-0: 1
CAS# 77-09-8: 1
Canada
CAS# 67-63-0 is listed on Canada's DSL/NDSL List.
CAS# 77-09-8 is listed on Canada's DSL/NDSL List.
WHMIS: Not available.
CAS# 67-63-0 is listed on Canada's Ingredient Disclosure List.
CAS# 77-09-8 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 67-63-0:. OEL-AUSTRALIA:TWA 400 ppm (980 mg/m3);STEL 500 ppm (12
25 mg/m3). OEL-BELGIUM:TWA 400 ppm (985 mg/m3);STEL 500 ppm (1230 mg/m
3). OEL-DENMARK:TWA 200 ppm (490 mg/m3);Skin. OEL-FRANCE:STEL 400 ppm
(980 mg/m3). OEL-GERMANY:TWA 400 ppm (980 mg/m3). OEL-JAPAN:STEL 400 p
pm (980 mg/m3). OEL-THE NETHERLANDS:TWA 400 ppm (980 mg/m3);Skin. OEL-
THE PHILIPPINES:TWA 400 ppm (980 mg/m3). OEL-RUSSIA:STEL 400 ppm (10 m
g/m3). OEL-SWEDEN:TWA 150 ppm (350 mg/m3);STEL 250 ppm (600 mg/m3). OE
L-SWITZERLAND:TWA 400 ppm (980 mg/m3);STEL 800 ppm. OEL-TURKEY:TWA 200
ppm (500 mg/m3). OEL-UNITED KINGDOM:TWA 400 ppm (980 mg/m3);STEL 500
ppm;Skin. OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV. OE
L IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 67-63-0 is listed on the TSCA inventory.
CAS# 77-09-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/21/1995 Revision #6 Date: 10/16/1997
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
|
|
|