HUMMEL CROTON INC -- IRON OXIDE, RED
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Material Safety Data Sheet
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MSDS Num: CJJLW
MSDS NAME: IRON OXIDE, RED
Responsible Party
Name: HUMMEL CROTON INC
Address: 10 HARMICH ROAD
City: SOUTH PLAINFIELD NJ 07080
Info Phone: 908-754-1800
Emergency Phone Number: 908-754-1800
Preparer's Name: MARK DUGAN
Chemtrec IND/Phone: (800)424-9300
Review Ind: Y
Published: Y
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Contractor Summary
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Name: HUMMEL CROTON INC
Address: 10 HARMICH ROAD
City: SOUTH PLAINFIELD NJ 07080
Phone: 908-754-1800
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Item Description Information
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Ingredients
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Cas: 1309-37-1
RTECS #: NO7400000
Name: IRON III OXIDE; (RED)
Percent by Wt: 100.
OSHA PEL: 10 MG/M3
ACGIH TLV: 5 MG/M3;2 PPM
ACGIH STEL: NOT ESTABLISHED
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Health Hazards Data
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LD50 LC50 Mixture: SEE TOXICOLOGICAL INFORMATION.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: INHALATION: MAY IRRITATE RESPIRATORY TRACT.
SYMPTOMS MAY INCLUDE COUGHING, SHORTNESS OF BREATH, SORE THROAT AND RUNNY
NOSE. IF SUFFICIENT AMOUNTS ARE INHALED AND ABSORBED, SYMPTOMS MAY RESEMBLE
THOSE IN ACUTE INGESTION. SKIN CONTACT: MAY CAUSE IRRITATION WITH SYMPTOMS OF
REDNESS, SWELLING, ITCHING AND PAIN. EYE CONTACT: MAY CAUSE IRRITATION WITH
SYMPTOMS OF REDNESS, SWELLING, ITCHING, TEARI NG AND PAIN. INGESTION: MAY
CAUSE GASTROENERITIS (INFLAMMATION OF THE LINING MEMBRANE OF THE STOMACH AND
INTESTINES) WITH ABDOMINAL PAIN, NAUSEA, VOMITING AND DIARRHEA. SYSTEMIC
EFFECTS MAY FOLLOW AND MAY INCLUDE RINGING (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: THIS PRODUCT IS NOT LISTED BY NTP, IARC OR
REGULATED AS A CARCINOGEN BY OSHA.
Signs And Symptions Of Overexposure: HLTH HAZ: OF EARS, DIZZINESS, ELEVATED
BLOOD PRESSURE, BLURRED VISION AND TREMORS.
Medical Cond Aggravated By Exposure: PERSONS WITH PREEXISTING EYE OR SKIN
CONDITIONS OR IMPAIRED PULMONARY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE
EFFECTS OF THIS PRODUCT.
First Aid: EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES. CALL MD. SKIN: FLUSH WITH WATER. WASH CLOTHING BEFORE REUSE. CALL MD
IF IRRITATION OCCURS. INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING,
GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL MD.
INGESTION: CALL MD IMMEDIATELY.
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Handling and Disposal
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Spill Release Procedures: UTILIZE RECOMMENDED PROTECTIVE CLOTHING &
EQUIPMENT. CLEAN SPILLS IN A MANNER THAT DOES NOT DISPERSE DUST INTO THE AIR.
SPILL AREA CAN BE WASHED WITH WATER. COLLECT WASH WATER FOR APPROVED
DISPOSAL. K EEP FROM ENTERING WATER OR GROUND WATER.
Waste Disposal Methods: WASTE DISP SHOULD BE I/A/W EXISTING FED, STATE &
LOC ENVIRON REGS IF DISCARDED IN ITS PURCHASED FORM, THIS PROD WOULD NOT BE
HAZ WASTE EITHER BY LISTING/BY CHARACT. HOWEVER, UNDER RCRA, IT IS RESPONS
IBILITY OF PROD USER TO DETERMINE AT TIME OF DISP, WHETHER MATL CNTNG
PROD/DERIVED FROM PROD SHOULD BE CLASSIFIED AS HAZ WASTE (40 CFR 261.20-24).
Handling And Storage Precautions: STORAGE TEMPERATURE (MIN/MAX):
AMBIENT/AMBIENT. SHELF LIFE: UNLIMITED IN TIGHTLY CLOSED CONTAINER. SPECIAL
SENSITIVITY: NONE. EDUCATE & TRAIN EMPLOYEES IN THE SAFE USE &
HANDLING OF HAZARDOUS CHEMICAL S.
Other Precautions: AVOID BREATHING DUST.AVOID GETTING IN EYES OR ON SKIN. STORE
IN A DRY PLACE AWAY FROM DIRECT SUNLIGHT, HEAT & INCOMPATIBLE MATERIALS.
RESEAL CONTAINERS IMMEDIATELY AFTER USE. STORE AWAY FROM FOOD & BE
VERAGES.
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Fire and Explosion Hazard Information
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Autoignition Temp Text: N/E
Extinguishing Media: MEDIA SUITABLE FOR SURROUNDING FIRE (FP N). NONCOMBUSTILE.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT
(FP N).
Unusual Fire/Explosion Hazard: EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
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Control Measures
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Respiratory Protection: WORK AMBIENT CONCENTRATIONS SHOULD BE MONITORED &
IF RECOMMENDED EXPOSURE LIMIT IS EXCEEDED, A NIOSH APPROVED DUST RESPIRATOR
MUST BE WORN.
Ventilation: USE LOCAL VENTILATION IF DUSTING IS A PROBLEM, TO MAINTAIN AIR
LEVELS BELOW RECOMMENDED EXPOSURE LIMIT.
Protective Gloves: PVC GLOVES
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA (FP N). IMPERVIOUS BOOTS, APRON OR COVERALLS.
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. EMPLOYEES SHOULD WASH
THEIR HANDS & FACE BEFORE EATING, DRINKING OR USING TOBACCO PRODUCTS.
Supplemental Safety and Health: PHYSICAL DATA: MOLECULAR WEIGHT: 159.70; BULK
DENSITY: NOT ESTABLISHED.
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Physical/Chemical Properties
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Melt/Freeze Pt: =1565.C, ######F
Vapor Density: N/A(AIR=1)
Spec Gravity: 5.24
PH: NEUTRAL
Solubility in Water: INSOLUBLE
Appearance and Odor: FINE, RED POWDER; ODORLESS.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: EXCESSIVE TEMPERATURES. STABLE UNDER ORDINARY
CONDITIONS OF USE & STORAGE.
Materials To Avoid: STRONG ACIDS, PEROXIDES & CHLOROFORMATES.
Hazardous Decomposition Products: NONE. DECOMPOSITION TEMPERATURE: STABLE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
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Toxicological Information
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Toxicological Information: ACUTE EFFECTS: MAY BE HARMFUL BY INHALATION,
INGESTION OR SKIN ABSORPTION. CAUSES EYE & SKIN IRRITATION. MATERIAL IS
IRRITATING TO MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT. TOXICITY DATA:
LD50:(IPR, RAT) 5500 MG/KG - GTPZAB 26(4),23,82; LD50:(IPR,MUS) 5400 MG/KG --
GTPZAB 26(4),23,82. ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL
SUBSTANCES (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY I N RTECS FOR
COMPLETE INFORMATION.
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Ecological Information
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Ecological: DATA NOT AVAILABLE AT THE PRESENT TIME.
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MSDS Transport Information
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Transport Information: CONTACT HUMMEL CROTON FOR CURRENT SHIPPING INFORMATION.
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Regulatory Information
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Sara Title III Information: OTHER INFO:RESPIRABLE FRACTION CFRGBR
29,1926.55,94. OSHA PEL (SHIPYARD):8H TWA 15 MG/M3, TDUST - CFRGBR
29,1915.1000,93. OSHA PEL (SHIPYARD):8H TWA 5 MG/M3, RESPIRABLE FRACTION -
CFRGBR 29,1916.1000, 93. OEL-FRANCE:TWA 5 MG/M3 (FUME JAN 93. OEL-GERMANY:TWA
6 MG/M3 (FUME) JAN 93. OEL-UNITED KINGDOM:TWA 10 MG/M3 (TDUST) JAN 93.
OEL-UNITED KINGDOM:TWA 5 MG/M3 (RESP DUST) JAN 93. OEL-UNITED KINGDOM:TW A 5
MG/M3; STEL 10 MG/M3 (FUME) JAN 93. NIOSH REL TO IRON OXIDE, DUST & FUME
(AS FE)-AIR:10H TWA 5 MGM/3 NIOSH* DHHS #92-100,92. NOHS 1974:HZD M1463; NIS
265; TNF 41132; NOS 153; TNE 483117. NOES 1983 :HZD M1463; (FEDERAL
REGULATORY)
Federal Regulatory Information: OSHA STATUS: THIS PRODUCT IS HAZARDOUS UNDER
CRITERIA OF FEDERAL OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200.
TSCA: ON TSCA INVENTORY. EUROPEAN INFORMATION: IRRITANT: R 36/37/3 IRRITATING
TO E YES, RESPIRATORY SYSTEM & SKIN. S 26 INCASE OF CONTACT WITH EYES,
RINSE IMMEDIATELY WITH PLENTY OF WATER & SEEK MEDICAL ADVICE. S 37/39
WEAR SUITABLE GLOVES & EYE/FACE PROTECTION. -- SARA TITLE III:NI S 308;
TNF 62557; NOS 185; TNE 965275; TFE 139397. EPA TSCA SECTION 8(B) CHEM
INVENTORY. EPA TSCA TE ST SUBMISSION (TSCATS) (STATE REGULATORY INFO)
State Regulatory Information: CALIFORNIA PROPOSITION 65: TO THE BEST OF MFR'S
KNOWLEDGE, THIS PRODUCT CONTAINS NO LEVELS OF LISTED SUBSTANCES, WHICH THE
STATE OF CALIFORNIA HAS FOUND TO CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODU
CTIVE EFFECTS. -- FEDERAL REGULATORY:DATA BASE, OCT 1995. NIOSH ANALYTICAL
METHOD, 1994: ELEMENTS BY ICP, 7300. OSHA ANALYTICAL METHOD #ID-125G.
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Other Information
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Other Information: REVIEWS, STDS & REGS: OEL=MAK. ACGIH TLV-TWA 10 MG/M3
TDUST - 85INA8 6,1351,91. ACGIH TLV-TWA 5 MG(FE)/ME (VAPOR) - 85INA8
6,803,91. ACGIH TLV-TWA 5 MG(FE)/M3 (DUST) - 85INA8 6,803,91. IARC CANCER REV
IEW:ANIMAL NO EVID - IMEMDT 1,29,72. IARC CANCER REVIEW:HUMAN INADEQ EVID -
IMEMDT 1,29,72. IARC CANCER REVIEW:GRP 3. MSHA STD:NUISANCE PARTICULATES -
DTLWS* 3,27,73. OSHA PEL (GEN INDU):8H TWA 15 MG/ M3, TDUST - CFRGBR
29,1910.1000,94. OSH APEL (GEN INDU):8H TWA 5 MG/M3, RESPIRABLE FRACTION -
CFRGBR 29,1910.1000,94. OSHA PEL (CONSTRUC):8H TWA 15 MG/M3, TDUST - CFRGBR
29,1926.55,94. OSHA PEL (CONST RUC):8H TWA 5 MG/M3, (SARA TITLE III)
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HAZCOM Label
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MSDS NAME: IRON OXIDE, RED
Company: HUMMEL CROTON INC
Street: 10 HARMICH ROAD
City: SOUTH PLAINFIELD NJ
Zipcode: 07080
Health Emergency Phone: 908-754-1800
Label Required IND: Y
Date Of Label Review: 07/28/1999
Status Code: A
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: INHAL: MAY IRRITRESP TRACT. SYMPTOMS MAY INCLUDE
COUGHING, SHORTNESS OF BREATH, SORE THROAT & RUNNY NOSE. IF SUFFICIENT
AMTS ARE INHALED & ABSORBED, SYMPS MAY RESEMBLE THOSE IN ACUTE INGEST. S
KIN CONT:MAY CAUSE IRRIT W/SYMPS OF REDNESS, SWELLING, ITCHING & PAIN.
EYE CONT: MAY CAUSE IRRIT W/SYMPS OF REDNESS, SWELLING, ITCHING, TEARING
& PAIN. INGEST: MAY CAUSE GASTROENERITIS (INFLAMMATION O F THE LINING
MEMBRANE OF THE STOMACH AND INTESTINES) W/ABDOM PAIN, NAUS, VOMIT &
DIARR. SYSTEMIC EFTS MAY FOLLOW & MAY INCLUDE RINGING OF EARS, DIZZ,
ELEVATED BLOOD PRESSURE, BLURRED VISION & TREMORS. CHRONIC: NONE
SPECIFIED BY MANUFACTURER (FP N).
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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