US PAINT CORPORATION -- HI-CAT TM #85 CONVERTER FOR HIGH SOLIDS POLYU
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Material Safety Data Sheet
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MSDS Num: CJJLH
MSDS NAME: HI-CAT TM #85 CONVERTER FOR HIGH SOLIDS POLYURETHANE TOP COA
Responsible Party
Name: US PAINT CORPORATION
Address: 831 S 21ST ST
City: ST LOUIS MO 63103-3092
Info Phone: 314-621-0525
Emergency Phone Number: (314) 621-0525
Resp. Party Other MSDS No.: K3002
Preparer's Name: ENVIR, HLTH & SFTY DEPT
Review Ind: Y
Published: Y
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Contractor Summary
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Name: US PAINT CORPORATION
Address: 831 SOUTH 21ST STREET
City: ST LOUIS MO 63103-3092
Phone: 314-621-0525
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Item Description Information
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Ingredients
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Cas: 763-69-9
RTECS #: UF3325000
Name: ETHYL 3-ETHOXYPROPIONATE. VP: 1.5 @ 20C. LD50: (ORAL,RAT) 5
Percent by Wt: 12.
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Name: ALIPHATIC POLYISOCYANATE (HOMOPOLYMER OF HDI). LD50: (ORAL,RAT) >10
Percent by Wt: .5
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Cas: 3779-63-3
Name: HEXAMETHYLENE DIISOCYANATE CYCLIC TRIMER. LD50: (ORAL,RAT) >5000
Percent by Wt: 86.
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Cas: 822-06-0
RTECS #: MO1740000
Name: HEXAMETHYLENE DIISOCYANATE
ACGIH TLV: 0.034 MG/M3;.005 PPM
ACGIH STEL: NOT ESTABLISHED
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
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Health Hazards Data
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Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: MAY CAUSE MOD IRRIT, REDNESS, TEARING & BLURRED
VISION. LIQ, AEROSOLS & VAPS ARE IRRITATING & CAN CAUSE PAIN,
TEARING, REDDENING, & SWELL ACCOMPANIED BY STINGING SENSATION AND/OR
FEELING THAT O F FINE DUST IN EYES. SKIN: CAN CAUSE IRRIT. MAY BE ABSORBED
THRU SKIN. ISOCYANATES REACT W/SKIN PROTEIN & MOISTURE & CAN CAUSE
IRRIT WHICH MAY INCLUDE FOLLOWING SYMPS: REDDENING, SWELL, RASH, SCALING/
BLISTERING. SOME PERSONS MAY DEVELOP SKIN SENSITIZ FROM SKIN CONT. CURED MATL
IS DFCLT TO REMOVE. PERSONS W/PRE-EXISTING SKIN DISORDERS MAY BE MORE
SUSCEPTIBLE TO EFTS OF THIS MATL. INHAL: CAN CAUSE N ASAL & RESP TRACT
(EFTS OF OVEREXP)
Signs And Symptions Of Overexposure: HLTH HAZ: IRRIT. EXPOS WELL ABOVE TLV MAY
LEAD TO BRONCH, BRONCHIAL SPASM & PULM EDEMA (FLUID IN LUNGS). THESE EFTS
ARE USUALLY REVERSIBLE. CHEM/HYPERSENSITIVE PNEUM, W/FLU-LIKE SYMPS (E.G.
FEVER, CHI LLS) HAS ALSO BEEN RPTD. THESE SYMPS CAN BE DELAYED.
SENSITIZER-MAY CAUSE ALLERGIC RESP RXN. ISOCYANATE VAPS/MIST @ CONCS >TLV
CAN IRRITATE (BURNING SENSATION) MUC MEMB IN RESP TRACT(NOSE, THROAT, LUN G)
CAUSING RUNNY NOSE, SORE THROAT, COUGH, CHEST DISCOMFORT, SHORTNESS OF BREATH
& REDUCED LUNG FUNC (BRTHG OBSTRUCTION). EXPOS WELL ABOVE TLV MAY LEAD TO
BRONCHIAL SPASM & PULM EDEMA (SUPDAT)
Medical Cond Aggravated By Exposure: PERSONS WITH PRE-EXISTING NON-SPECIFIC
BRONCHIAL HYPERREACTIVITY CAN RESPOND TO CONCENTRATIONS BELOW TLV WITH
SIMILAR SYMPTOMS AS WELL AS AN ASTHMA ATTACK.
First Aid: EYES: FLUSH W/WATER FOR AT LST 15 MINS WHILE HOLDING EYELIDS APART.
SEEK MED ATTN. SKIN: REMOVE CONTAMD CLTHG & FLUSH CONTAMD SKIN W/LG AMTS
OF WATER. IF SKIN IS DMGD/IF SYMPS PERSIST SEEK MED ATTN. L AUNDER CLTHG
BEFORE REUSE. INHAL: IMMED MOVE AWAY FROM EXPOS & INTO FRESH AIR. SEEK
IMMED MED ATTN. KEEP PERSON WARM & QUIET. IF NOT BRTHG, BEGIN ARTF RESP.
IF BRTHG IS DFCLT, ADMIN OXYG. ASTHMATIC-TY PE SYMPS MAY DEVELOP & MAY BE
IMMED/DELAYED UP TO SEVERAL HOURS. INGEST: DO NOT INDUCE VOMIT UNLESS
DIRECTED TO DO SO BY MED PERS. ASPIR OF MATL INTO LUNGS CAN CAUSE CHEM PNEUM
WHICH MAY (STATE REGUL ATORY INFO)
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Handling and Disposal
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Spill Release Procedures: SM SPILL: ABSORB LIQ ON INERT MATL SUCH AS PAPER,
VERMICULITE, FLOOR ABSORB, & TRANSFER TO HOOD. LG SPILL: ELIM ALL IGNIT
SOURCES(FLARES/FLAMES, INCL PILOT LIGHT/ELEC SPKS). PERSONS NOT WEARING PROT
E QUIP SHOULD BE EXCLUDED FROM AREA UNTIL CLEANUP HAS BEEN COMPLETED. STOP
SPILL @ SOURCE, CNTN AREA OF SPILL TO PVNT SPREADING, PUMP LIQ TO SALVAGE
TANK. REMAINING LIQ MAY BE ABSORBED W/(NEUT AGENT)
Neutralizing Agent: INERT MATL SUCH AS SAND/CLAY/EARTH/FLOOR ABSORB &
SHOVELED INTO CNTNRS W/NON-SPKG TOOLS. CONT NEHC FOR MORE INFO
Waste Disposal Methods: DISPOSE OF CONTAMINATED ABSORBENT, CONTAINER, AND
UNUSED CONTENTS IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS. DO
NOT INCINERATE CLOSED CONTAINERS.
Handling And Storage Precautions: SENSITIVITY TO STATIC
DISCHARGE-GROUNDING/BONDING REQD. KEEP CNTNR TIGHT & UPRIGHT TO PVNT
LEAKAGE. KEEP CNTNR CLSD WHEN NOT IN USE. DO NOT STORE >49C/120F. DO NOT
TRANSFER CONTENTS TO BOTTLES/OTHER U NLBLD CNTNRS. PROTECT FROM FREEZING.
Other Precautions: CNTNRS OF THIS MATL MAY BE HAZ WHEN EMPTIED BECAUSE THEY
RETAIN PROD RESIDUES (VAP, LIQ, AND/OR SOLID). WHEN EMPTY, MAY CNTN EXPLO
VAPS. DO NOT CUT, PUNCTURE/WELD ON/NEAR CNTNR. ALL HAZ PRECS GIVEN IN DATA
SHEET MUST BE OBSERVED FOR EMPTY CNTNRS. CLSD CNTNR MAY BURST WHEN CONTAMD
W/H*2O(THRU EVOLUTI ON OF CO*2).
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Fire and Explosion Hazard Information
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Flash Point Method: TCC
Flash Point: =58.C, 136.4F
Autoignition Temp: =377.C, 710.6F
Lower Limits: 1.00%
Extinguishing Media: CO*2/DRY CHEM FOR SM FIRES; ALCOHOL-TYPE AQUEOUS,
FILM-FORMING FOAM/WATER SPRAY FOR LG FIRES. WATER MAY BE INEFTIVE BUT SHOULD
BE USED TO COOL FIRE-EXPOSED STRUCTURES & VESSELS.
Fire Fighting Procedures: USE NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N).
IN CASE OF FIRE, USE DRY CHEM, FOAM, CO*2/OTHER APPRVD METH FOR TREATING
CLASS B FIRE. SUMMON PROFESSIONAL FIREFIGHTERS. DURING FIRE, TOXIC GASES
& SMOK E ARE IRRITANTS PRESENT FROM DECOMP/COMBUST. FOR MORE INFO CONT
NEHC (FP N).
Unusual Fire/Explosion Hazard: KEEP AWAY FROM HEAT, SPKS & FLAME. DO NOT
SMOKE. EXTING ALL PILOT LIGHTS & TURN OFF ALL SOURCES OF IGNIT, INCL
HEATERS, FANS, & OTHER NON-EXPLO PROOF ELEC EQUIP, DURING USE & UNTIL
ALL VAPS ARE GONE. VAPS MAY IGNITE EXPLOSIVELY. VAPS MAY SPREAD LONG DIST,
& BEYOND CLSD DOORS. FOR MORE INFO CONT NEHC (FP N).
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Control Measures
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Respiratory Protection: USE ONLY W/ADEQ VENT. MAINTAIN CONTINUOUS FLOW OF FRESH
AIR. DO NOT BREATHE VAPS, SPRAY MIST/SANDING DUST. WEAR APPROP PROPERLY
FITTED RESP (NIOSH APPRVD) DURING & AFTER APPLIC UNLESS AIR MONITORING
DEMONSTRATES VAP & PARTICULATE LEVELS ARE BELOW APPLIC LIMITS. FOR MORE
SPECIFIC INFORMATION CONT NEHC (FP N).
Ventilation: PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST)
VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves: SOLVENT IMPERMEABLE GLOVES.
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N).
IMPERMEABLE CLOTHING, AND BOOTS SHOULD BE WORN TO PREVENT SKIN CONTACT.
Work Hygienic Practices: DO NOT GET IN EYES, ON SKIN OR CLOTHING.
Supplemental Safety and Health: EFTS OF OVEREXP: (FLUID IN LUNGS). THESE EFTS
ARE USUALLY REVERSIBLE. CHEM/HYPERSENSITIVE PNEUM, W/FLU-LIKE SYMPS (E.G.
FEVER, CHILLS) HAS ALSO BEEN RPTD. CAN CAUSE CNS EFTS INCL (DIZZ, WEAK, FATG,
NA US, HDCH & POSS UNCON. ASTHMA, OTHER RESP DISORDERS (BRONCH,
EMPHYSEMA, BRONCHIAL HYPERREACTIVITY). (TOX INFO)
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Physical/Chemical Properties
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Boiling Point: =165.C, 329.F
Spec Gravity: 1.12
VOC Pounds/Gallon: 1.16
VOC Grams/Liter: 139
Evaporation Rate & Reference: 0 (N-BUTYL ACETATE =1)
Appearance and Odor: LIQUID
Percent Volatiles by Volume: 14.68
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: STABLE; HOWEVER, FORMS PEROXIDES OF UNKNOWN
STABILITY.
Materials To Avoid: ACIDS, ALKALIS, ALCOHOLS, AMINES, STRONG BASES, METAL
COMPOUNDS AND SURFACE ACTIVE METALS, OXIDIZING AGENTS AND WATER (INCL HIGH
HUMIDITY, MOISTURE AND STEAM).
Hazardous Decomposition Products: CARBON DIOXIDE, CARBON MONOXIDE, HCN, HDI,
OXIDES OF NITROGEN AND VARIOUS HYDROCARBONS.
Hazardous Polymerization Indicator: YES
Conditions To Avoid Polymerization: CONT W/MOISTURE, OR OTHER MATLS WHICH REACT
W/ISOCYANATES/ TEMPS ABOVE 204C/400F, MAY CAUSE POLYM. MAY OCCUR @ HIGH
TEMPS.
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Toxicological Information
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Toxicological Information: NO ADDITIONAL TOXICOLOGICAL DATA AVAILABLE. PLEASE
REFER TO INGRED & HAZARDS IDENTIFICATION SECTIONS. SUPDAT: INGEST: SINGLE
DOSE ORAL TOX IS LOW. CAN CAUSE IRRIT OF DIGESTIVE TRACT, NAUS, VOMIT &
DIA RR. MAY CAUSE SIGNS OF NERV SYS DEPRESSINCL DROW, DIZZ, LOSS OF
COORDINATION, FATG, HDCH & NAUS. MAY CAUSE BURNS OF MOUTH, THROAT &
STOM. POTNTL CHRONIC HLTH EFTS: PRLNGD & RPTD BRTHG OF VAPS, SPRAY M IST
AND/OR SANDING DUST OVER PERIOD OF YEARS MAY CAUSE DISEASES OF LUNGS. AS RSLT
OF PREVIOUS RPTD OVEREXP OR SINGLE LG DOSE, CERTAIN INDIVIDUALS WILL DEVELOP
ISOCYANATE (ECOLOGICAL INFO)
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Ecological Information
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Ecological: NO ECOLOGICAL DATA AVAILABLE FOR THIS PRODUCT. TOXICOLOGICAL INFO:
SENSITIZ (CHEM ASTHMA) WHICH WILL CAUSE THEM TO REACT TO LATER EXPOS TO
ISOCYANATE @ LEVELS WELL BELOW TLV. THESE SYMS WHICH INCL: CH EST TIGHTNESS,
WHEEZING, COUGH, SHORTNESS OF BREATH/ASTHMATIC ATTACK COULD BE IMMED/DELAYED
UP SEVERAL HRS AFTER EXPOS. SIMILAR TO MANY NON-SPECIFIC ASTHMATIC RESPONSES,
THERE ARE REPORTS THAT ONCE SE NSITIZED AN INDIVIDUAL CAN EXPERIENCE THESE
SYMPS UPON EXPOSURE TO DUST, COLD AIR/OTHER IRRITANTS. THIS INCREASED LUNG
SENSITIVITY CAN PERSIST FOR WEEKS & IN SEV CASES FOR SEVERAL YEARS.
(TRANSPORT IN FO)
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MSDS Transport Information
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Transport Information: D.O.T. HAZARD CLASS 3. D.O.T. PACKAGING GROUP III.
D.O.T. LABEL: FLAMMABLE LIQUID. D.O.T. PROPER SHIPPING NAME: PAINT. D.O.T.
PLACARD: FLAMMABLE. UN/NA NUMBER: 1263. ECOLOGICAL INFO: CHRONIC OVEREXP T O
ISOCYANATES HAS ALSO BEEN RPTD TO CAUSE LUNG DMG, INCL DECREASE IN LUNG FUNC,
WHICH MAY BE PERM. SENSITIZ MAY BE EITHER TEMPORARY/PERM. PRLNGD CONT
W/ISOCYANATES CAN CAUSE REDDENING, SWELL RASH, SCA LING, BLISTERING, & IN
SOME CASES, SKIN SENSITIZ. INDIVIDUALS WHO HAVE SKIN SENSITIZ CAN DEVELOP
THESE SYMPS FROM CONT W/LIQ OR VAPS. FOR MORE INFORMATION CONT NEHC (FP N).
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Regulatory Information
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Sara Title III Information: THIS PRODUCTION CONTAINS NONE OF SUBSTANCES SUBJECT
TO RPTG REQUIREMENTS OF SECTION 313 OF TITLE III OF SUPERFUND AMENDMENTS
& REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372.
Federal Regulatory Information: THIS PRODUCTION CONTAINS NONE OF SUBSTANCES
SUBJECT TO RPTG REQUIREMENTS OF SECITON 313 OF TITLE III OF SUPERFUND
AMENDMENTS & REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372.
State Regulatory Information: FIRST AID PROC: BE FATAL IF INDIVIDUAL IS
DROWSY/UNCON, PLACE ON THEIR SIDE W/HEAD DOWN. SEEK MED ATTN. IF POSS, DO NOT
LEAVE INDIVIDUAL UNATTENDED. NOTE TO PHYS: EYES: STRAIN FOR EVID OF CORNEAL
INJU RY. IF CORNEA IS BURNED, INSTILL ANTIBIOTICS/STEROID PREPARATION
FREQUENTLY. WORKPLACE VAPS COULD PRDCE REVERSIBLE CORNEAL EPITHELIAL EDEMA
IMPAIRING VISION. SKIN: THIS PROD IS KNOWN SENSITIZER. TREAT SYMPTOMATICALLY
AS FOR CONT DERM/THERM BURNS. INGEST: TREAT SYMPTOMATICALLY. THERE IS NO
ANTIDOTE. INDUCING VOMIT IS CONTRAINDICATED BECAUSE OF IRRIT NATURE OF PROD.
FOR MORE INFO CONT NEHC (FP N).
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Other Information
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Other Information: IMPORTANT: THIS PROD MAY BE BLENDED W/OTHER PRODS PRIOR TO
USE. READ ALL WARNINGS & PRECS ON MSDSS & LBLS OF ALL PRODS BEING
BLENDED AS COMBINATION MAY CNTN HAZS OF EACH COMPONENT. FOR INDUST USE ONLY .
THIS PROD IS FOR USE BY PROFESSIONAL, TRAINED PERSONNEL USING PROPER EQUIP,
& IS NOT INTENDED FOR SALE TO, OR USE BY GEN PUBLIC. MONOMER CONTENT IS
<0.7% BASED ON RESIN SOLIDS @ TIME OF MFR. HOWEVER , AFTER 3-6 MONTHS
STORAGE, FREE MONOMER CONTENT MAY RISE TO MAX OF 6%. VOC OF MATL: 139 G/L OR
1.16 LBS/GAL. % VOLAT BY WT: 12.5. FORMULA WT/VOL: 9.28 LBS/GAL.
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HAZCOM Label
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MSDS NAME: HI-CAT TM #85 CONVERTER FOR HIGH SOLIDS POLYURETHANE TOP COA
Company: US PAINT CORPORATION
Street: 831 SOUTH 21ST STREET
City: ST LOUIS MO
Zipcode: 63103-3092
Health Emergency Phone: (314) 621-0525
Label Required IND: Y
Date Of Label Review: 04/21/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: COMBUST. ACUTE: EYES: MAY CAUSE MOD IRRIT, REDNESS,
TEARING & BLURRED VISION. LIQ, AEROSOLS & VAPS ARE IRRITATING &
CAN CAUSE PAIN, TEARING, REDDENING, & SWELL ACCOMPANIED BY STINGING
SENSATION AND/OR FEELING THAT OF FINE DUST IN EYES. SKIN: CAN CAUSE IRRIT.
MAY BE ABSORBED THRU SKIN. ISOCYANATES REACT W/SKIN PROTEIN & MOISTURE
& CAN CAUSE IRRIT WHICH MAY INCLUDE FOLLOWING SYMPS: REDDENING, SWELL,
RASH, SCALING/BLISTERING. INHAL: CAN CAUSE NASAL & RESP TRACT IRRIT. VAPS
CAN IRRITATE RESP TRACT, NOSE, THROAT AND LUNGS. INGEST: CAN IRRITATE GI
TRACT, CAUSE NAUS, VOMIT & DIARR. CHRONIC: SKIN AND RESPIRATORY
SENSITIZATION.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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