RUST-OLEUM CORP -- GRAY PRIMER, 2182 838
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CJJML
MSDS NAME: GRAY PRIMER, 2182 838
Responsible Party
Name: RUST-OLEUM CORP
Address: 11 HAWTHORNE PKWY
City: VERNON HILLS IL 60061
Info Phone: 847-367-7700
Emergency Phone Number: 847-367-7700
Resp. Party Other MSDS No.: 9703955
Preparer's Name: LJW
Proprietary Ind: Y
Review Ind: Y
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: RUST-OLEUM CORP
Address: 11 HAWTHORN PARKWAY
City: VERNON HILLS IL 60061-1583
Phone: 847-367-7700
=======================================================
Ingredients
=======================================================
Name: *** PROPRIETARY ***
-----------------------------
=======================================================
Health Hazards Data
=======================================================
Signs And Symptions Of Overexposure: HLTH HAZ: LIST INFO & SAFE HNDLG
& EXPOS INFO (FP N). MAY CAUSE CNS DISORDER (E.G., NARCOSIS INVOLVING A
LOSS OF COORDINATION, WEAK, FATIGUE, MENTAL CONFUSION, & BLURRIED VISION)
&/ DMG. RPTS HAVE AS SOCD RPTD & PRLNG OCCUP OVEREXP TO SOLVW/PERM
BRAIN & NERVOUS SYS DMG. OVEREXP TO XYLENE IN LAB ANIMALS HAS BEEN ASSOCD
W/LIVER ABNORM, KIDNEY, LUNG, SPLEEN & EYE DMG AS WELL AS ANEMIA. EFTS IN
HUMANS HAVE INCL LIVER & CARDIAC ABNORB. OVEREXP TO TOLUENE IN LAB
ANIMALS HAS BEEN ASSOCD W/LIVER ABNORM, KIDNEY, LUNG & SPLEEN DMG. EFTS
IN HUMANS HAVE INCL LIVER & CARDIAC ABNORM. CNTNS CARBON BLACK.CHRO NIC
INFLAMM, LUNG (SUPDAT)
First Aid: EYES: HOLD EYELIDS APART AND FLUSH WITH PLENTY OF WATER FOR AT LEAST
15 MINUTES. GET MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER. GET
MEDICAL ATTENTION IF IRRITATION DEVELOPS OR PERSISTS. INHALA TION: NO
INFORMATION. REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) (FP
N). INGESTION: ASPIRATION HAZARD: DO NOT INDUCE VOMITING OR GIVE ANYTHING BY
MOUTH BECAUSE THIS MATERIAL CAN ENTER THE LUNGS AND CAUSE SEVERE LUNG
DAMAGE. GET IMMEDIATE MEDICAL ATTENTION.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: EVACUATE THE AREA, REMOVE ALL SOURCES OF IGNITION AND
VENTILATE WELL. CONTAIN SPILLED LIQUID WITH SAND OR EARTH. DO NOT USE
COMBUSTIBLE MATERIALS SUCH AS SAWDUST. REMOVE ALL SOURCES OF IGNITION, VENTI
LATE AREA AND REMOVE WITH INERT ABSORBENT AND NON-SPARKING TOOLS. DISPOSE OF
ACCORDING TO LOCAL, STATE (PROVINCIAL) AND FEDERAL REGULATIONS. DO NOT
INCINERATE CLOSED CONTAINERS.
Waste Disposal Methods: DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE AND
FEDERAL REGULATIONS AND ORDINANCES. DO NOT ALLOW TO ENTER STORM DRAINS OR
SEWER SYSTEMS.
Handling And Storage Precautions: USE ONLY IN A WELL-VENTILATED AREA. FOLLOW
ALL MSDS/LABEL PRECAUTIONS EVEN AFTER CONTAINER IS EMPTIED BECAUSE IT MAY
RETAIN PRODUCT RESIDUES. AVOID BREATHING VAPOR OR MIST. KEEP CONTAINERS
TIGHTLY CLO SED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS & OPEN
FLAME. DO NOT STORE ABOVE 120 DEGREES F.
Other Precautions: STORE LARGE QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED
FOR STORAGE OF NFPA CLASS I FLAMMABLE LIQUIDS. CONTENTS UNDER PRESSURE. DO
NOT EXPOSE TO HEAT OR STORE ABOVE 120 DEGREES F.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point: <-6.7C, 20.F
Lower Limits: 1.0%
Upper Limits: 9.5%
Extinguishing Media: DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). EVACUATE AREA AND FIGHT FIRE FROM A SAFE DISTANCE.
Unusual Fire/Explosion Hazard: WATER SPRAY MAY BE INEFT. CLOSED CNTNRS MAY
EXPLODE WHEN EXPOSED TO EXTREME HEAT DUE TO BUILDUP OF STEAM. CLOSED CNTNRS
MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. VAPS MAY FORM EXPLO MIX W/AIR. VAPS
CA N TRAVEL TO SOURCE OF IGNIT & FLASH BACK. KEEP CNTNRS TIGHTLY CLOSED.
ISOLATE FROM HEAT, ELEC EQUIP, (TOXICOLOGICAL)
=======================================================
Control Measures
=======================================================
Respiratory Protection: A RESP PROT PROGRAM THAT MEETS OSHA 1910.134 & ANSI
Z88.2 REQUIREMENTSS MUST BE FOLLOWED WHENEVER WORKPLACE CNDTNS WARRANT A
RESP'S USE. A NIOSH APRVD AIR PURIFYING RESP W/ORG VAP CARTRIDGE/CANISTER M
AY BE PERMISSIBLE UNDER CERTAIN CIRCUMISTANCES WHERE AIRBORNE CONCS ARE
EXPECTED TO EXCEED EXPOS LIMS. PROT PROVIDED BY AIR PURIFYING RESP IS LTD.
(ECOLOGICAL)
Ventilation: USE PROCESS ENCLOSURES, LOC EXHST VENT/OTHER ENGINEERING CONTROLS
TO CONTROL AIRBORNE LEVELS BELOW REC EXPOS LIMIT. USE (ECOLOGICAL)
Protective Gloves: IMPERVIOUS GLOVES, NITRILE OR NEOPRENE GLOVES.
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST
FOR FURTHER INFORMATION REGARDING PERSONAL PROTECTIVE EQUIPMENT AND ITS
APPLICATION.
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. WASH HANDS BEFORE
EATING. WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR
SMOKING.
Supplemental Safety and Health: EFTS OF OVEREXP: FIBROSIS, & LUNG TUMORS
HAVE BEEN OBSERVED IN SOME RATS EXPERIMENTALLY EXPOSED FOR LONG PERIODS OF
TIME TO EXCESS CONCS OF CARBON BLACK & SEVERAL INSOLUBLE FINE DUST
PARTICLES. TUMOR S HAVE NOT BEEN OBSERVED IN OTHER ANIMAL SPECIES (I E,
MOUSE & HAMPSTER) UNDER SIMILAR CIRCUMSTANCES & (OTHER INFO)
=======================================================
Physical/Chemical Properties
=======================================================
Boiling Point: =140.C, 284.F
B.P. Text: -44 - 284F
Vapor Density: HVR/AIR
Spec Gravity: 1.1751
Evaporation Rate & Reference: FASTER THAN ETHER
Solubility in Water: SLIGHT
Appearance and Odor: LIQUID; SOLVENT ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: AVOID TEMPERATURES ABOVE 120 DEGRESS F. AVOID ALL
POSSIBLE SOURCES OF IGNITION.
Materials To Avoid: INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND
STRONG ALKALIES.
Hazardous Decomposition Products: BY OPEN FLAME, CARBON MONOXIDE AND CARBON
DIOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR UNDER NORMAL STORAGE
CONTAINERS.
=======================================================
Toxicological Information
=======================================================
Toxicological Information: COMPONENT TOXICOLOGICAL INFORMATION: CHEMICAL NAME:
TOLUENE LD50: RAT 5000MG/KG, LC50: MOUSE 5320 PPM 8HR, PROPANE: LD50 N.E. LC
50: N.E., XYLENE: LD50: RATE4300 MG/KG, LC50: RAT 5000PPM 4 HR, MAGNESI UM
SILICATE: LD50: NONE, LC50: NONE. TITANIUM DIOXIDE: LD50: 2400MG/KG RATS.
LC50: 6820MG/M3 RATS, CALCIUM CARBONATE: LD50: NONE, LC50: NONE.
N-BUTANE:LD50: RAT 658G/M
3 4HR, LC50: N/E. ETHYLBENZENE: LD50: RAT 3500 MG/KG. LC50: N/A, ISOBUTANE:
LD50: N.E., LC: N.E. EXPLO HAZ: SPARKS & OPEN FLAME. PERFORATION OF PRESS
CNTNR MAY CAUSE BURSTING OF CAN. CLOSED CNTNRS MAY EXPLODE WHEN EXPOSED TO
EXTREME HEAT.
=======================================================
Ecological Information
=======================================================
Ecological: PRODUCT IS A MIXTURE OF LISTED COMPONENTS. RESP PROT: USE A
POSITIVE NIOSH PRESSURE AIR SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR
AN UNCONTROLLED RELEASE, EXPOSURE LEVELS ARE NOT KNOWN, OR ANY OTHER
CIRCUMSTANCES WHERE AIR PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE
PROTECTION. VENT: EXPLOSION-PROOF VENTILATION EQUIPMENT. PREVENT BUILD-UP OF
VAPORS BY OPENING ALL DOORS AND WINDOWS TO AC HIEVE CROSS-VENTILATION.
=======================================================
MSDS Transport Information
=======================================================
Transport Information: NO TRANSPORTATION INFORMATION IS AVAILABLE.
=======================================================
Regulatory Information
=======================================================
Sara Title III Information: THIS PRODUCT HAS BEEN REVIEWED ACCORD TO THE EPA
'HAZARD CATEGORIES' PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND
AMENDMENT AND REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERE
D, UNDER APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES: IMMEDIATE
HEALTH HAZARD, CHRONIC HEALTH HAZARD, FIRE HAZARD, PRESSURIZED GAS HAZARD.
SARA SECTION 313: THIS PRODUCT CONTAINS FOLLOWIN G SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND
AMMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372. TOLUENE,
XYLENE, ETHYLBENZENE, 1,2,4-TR IMETHYLBENZENE.
Federal Regulatory Information: OSHA: HAZARDOUS BY DEFINITION OF HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200). TOXIC SUBSTANCES CONTROL ACT: THIS
PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE REPORTING
REQUIM ENTS OF TSCA 12 (B) IF EXPORTED FROM THE UNITED STATES: NO INFORMATION
IS AVAILABLE.
State Regulatory Information: N J RIGHT-TO-KNOW: FOLLOWING MATLS ARE NON-HAZ,
BUT ARE AMONG TOP 5 COMPONENTS IN THIS PROD:CHEM NAME:ALKYD RESIN SOLUTION.
CAS #:66070-60-8. PA RIGHT-TO-KNOW: FOLLOWING NON-HAZ INGREDIENTS ARE PRESEN
T IN PROD AT > 3%: CHEM NAME ALKYD RESIN SOLUTION. CAS #: 66070-60-8, CHEM
NAME:ACRYLIC POLYMER:CAS #: PA. TRADE SCT. CA PROPOSITION 65: WARNING:
CHEM(S) NOTED BELOW & CNTND IN THIS PROD, ARE KNOWN TO STATE OF CA TO
CAUSE CANCER, BIRTH DEFECTS/OTHER REPROD HARM: CHEM NAME:TOLUENE CAS #:
108-88-3. IN TERNATIONAL REGS: AS FOLLOWS: CANDIAN W: THIS MSDS HAS BEEN
PREPARED IN COMPLIANCE W/CONTROLLED PROD REGS EXCEPT FOR USE OF 16 HEADINGS.
=======================================================
Other Information
=======================================================
Other Information: SUPDAT: STUDY CNDTN. EPIDEMIOLOGICAL STUDIES OF NORTH
AMERICAN WORKERS SHOW NO EVID OF CLINICALLY SIGNIFICANT ADVERSE HLTH EFTS DUE
TO OCCUP EXPOS TO CARBON BLACK. CARBON BLACK IS LISTED AS A GROUP 2B
-"POSSIBLY CARCIN TO HUMANS" BY IARC &IS PROPOSED TO BE LISTED AS A4
-"NOT CLASSIFIED AS A HUMAN CARCIN" BY AMERICAN CONFERENCE OF GOVT INDUSTRIAL
HYGIENISTS. SIGNIFICANT EXPOS IS NOT ANTIC DURING BRU SH APPLICATION/DRYING.
RISK OF OVEREXP DEPENDS ON DURATION & LEVEL OF EXPOS TO DUST FROM RPTD
SANDING OF SURFACES/SPRAY MIST & ACTUAL CONC OF CARBON BLACK IN FORMULA.
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: GRAY PRIMER, 2182 838
Company: RUST-OLEUM CORP
Street: 11 HAWTHORN PARKWAY
City: VERNON HILLS IL
Zipcode: 60061-1583
Health Emergency Phone: 847-367-7700
Label Required IND: Y
Date Of Label Review: 07/28/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: EXTREMELY FLAMMABLE! ACUTE: EYE: CAUSES IRRIT. SKIN:
IRRITATION. INHALATION: MAY BE HARMFUL. IRRITATING TO EYES, NOSE, THROAT,
AND LUNGS. INGESTION: MAY BE HARMFUL. ASPIRATION HAZARD, CAN ENTER L UNGS
AND CAUSE DAMAGE. CHRONIC: CONTAINS MATERIAL WHICH APPEARS ON THE NAVY
OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS LIST (FP N). CANCER HAZARD.
CONTAINS MATERIAL WHICH IS LISTED AS AN ANIMAL LUN G CARCINOGEN (FP N).
CENTRAL NERVOUS SYS DISORDERS AND/OR DAMAGE. POSSIBLE PERM BRAIN AND NERV SYS
DAMAGE. LIVER, KIDNEY, LUNG, SPLEEN AND EYE DAMAGE. ANEMIA. CARDIAC
ABNORMALITIES POSSIBLE. SKIN: PR OLONGED OR REPEATED CONTACT MAY CAUSE SKIN
IRRIT.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
|
|