ITW DEVCON -- PUTTY HARDENER, 10650, 11410, 11420, DE087
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Material Safety Data Sheet
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MSDS Num: CKXLL
MSDS NAME: PUTTY HARDENER, 10650, 11410, 11420, DE087
Responsible Party
Name: ITW DEVCON
Address: 30 ENDICOTT ST.
City: DANVERS MA 01923
Info Phone: (978) 777-1100
Emergency Phone Number: (800) 424-9300
Chemtrec IND/Phone: (800)424-9300
Review Ind: Y
Published: Y
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Contractor Summary
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Name: ITW DEVCON
Address: 30 ENDICOTT ST.
City: DANVERS MA 01923
Phone: (978) 777-1100
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Ingredients
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Cas: 112-24-3
RTECS #: YE6650000
Name: TRIETHYLENETETRAMINE. (TETA)
% low Wt: 30.
% high Wt: 40.
Other REC Limits: 1 PPM(SKIN)( AIHA)
OSHA PEL: N/E
ACGIH TLV: N/E
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Cas: 25154-52-3
RTECS #: SM5600000
Name: NONYLPHENOL
% low Wt: 1.
% high Wt: 10.
Other REC Limits: N/E
OSHA PEL: N/E
ACGIH TLV: N/E
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Cas: 140-31-8
RTECS #: TK8050000
Name: AMINOETHYLPIPERAZINE. (AEP)
% low Wt: 1.
% high Wt: 10.
Other REC Limits: 1PPM (SKIN) (AIHA)
OSHA PEL: N/E
ACGIH TLV: N/E
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Cas: 68082-29-1
Name: DIMER/TOFA, REACTION PRODUCTS WITH TETA.
% low Wt: 40.
% high Wt: 50.
Other REC Limits: N/E
OSHA PEL: N/E
ACGIH TLV: N/E
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Health Hazards Data
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Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: SEVERE EYE, SKIN & RESPIRATORY TRACT IRRITANT
(EVIDENCED BY RASH, BURNING SENSATION, SORE THROAT, NAUSEA, SHORTNESS OF
BREATH). HARMFUL IF ABSORBED THRU SKIN. MAY CAUSE SKIN SENSITIZATION. INHA L:
IRRITATION OF NOSE & THROAT; NAUSEA & VOMITTING IN SEVERE CASES.
INGEST: IRRIT OF MOUTH, THROAT & GI TRACT. CHRONIC: OTHER EFFECTS:
REPEATED/PROLONGED EXPOSURE TO LOW CONCENTRATION OF VAPOR MAY CAU SE: SORE
THROAT, EYE IRRIT, NAUSEA, FAINTNESS, HEADACHE, WHICH ARE TRANSIENT.
RPTD/PRLNGD EXPOS MAY RESULT IN: ADVERSE SKIN EFFECTS (SUCH AS DEFATTING,
RASH, IRRIT OR CORROSION), ADVERSE EYE EFFECTS ( SIGNS/SYMPTOMS OF
OVEREXPOSURE)
Explanation Of Carcinogenicity: ACGIH: NO.
Signs And Symptions Of Overexposure: HEALTH HAZARDS ACUTE/CHRONIC (CONT'D):
(SUCH AS CONJUNCTIVITIS OR CORNEAL DAMAGE). PRIMARY ROUTES OF EXPOSURE: SKIN,
SKIN ABSORPTION, EYE, INHALATION AND INGESTION. SKIN: SEVERE IRRITANT. EYES:
SEVERE IRRITANT. EFFECTS OF CHRONIC OVEREXPOSURE: REPEATED SKIN CONTACT CAN
CAUSE SENSITIZATION, WITH ITCHING, RASHES OR SWELLING OF SKIN. TETA MAY CAUSE
RESPIRATORY SENSITIZATION AND CHRONIC LUNG TOXICITY (COUGH, TIGHTNESS OF
CHEST, SHORTNESS OF BREATH). NONYLPHENOL HAS CAUSED ALLERGIC SENSITIZATION IN
HUMANS.
Medical Cond Aggravated By Exposure: EYE DISEASE, SKIN DISORDERS AND ALLERGIES.
First Aid: FIRST AID FOR EYES: IMMEDIATELY FLUSH WITH CLEAN WATER FOR AT LEAST
15 MINUTES WHILE GENTLY HOLDING EYELIDS OPEN. GET MEDICAL HELP AS SOON AS
POSSIBLE. FIRST AID FOR SKIN: IMMEDIATELY REMOVE CONTAMINA TED CLOTHING AND
SHOES AND WASH WELL WITH SOAP AND WARM WATER. SEE A DOCTOR IF IRRITATION
DEVELOPS. FIRST AID FOR INHALATION: REMOVE PATIENT TO FRESH AIR. GIVE OXYGEN
OR ARTIFICIAL RESPIRATION IF NEED ED. SEE DOCTOR IF SYMPTOMS PERSIST. FIRST
AID FOR INGESTION: DO NOT INDUCE VOMITING. DILUTE WITH LOTS OF MILK OR WATER
AND GET IMMEDIATE MEDICAL HELP.
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Handling and Disposal
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Spill Release Procedures: AVOID PERSONAL CONTACT. ELIMINATE IGNITION SOURCES.
VENTILATE AREA. DIKE, CONTAIN AND ABSORB WITH CLAY, SAND OR OTHER SUITABLE
MATERIAL. FOR LARGE SPILLS: PUMP TO STORAGE/SALVAGE VESSELS. SOAK UP RESI DUE
WITH AN ABSORBENT SUCH AS CLAY, SAND OR OTHER SUITABLE MATERIAL AND DISPOSE
OF PROPERLY. FLUSH AREA WITH WATER TO REMOVE TRACE RESIDUE. PREVENT SPILL
FROM ENTERING DRAINAGE/ (NEUTRALIZING AGENT)
Neutralizing Agent: N/P. SPILL RELEASE (CONT): SEWER SYSTEMS, WATERWAYS AND
SURFACE WATERS.
Waste Disposal Methods: IF THIS MATERIAL BECOMES A WASTE, IT WOULD NOT BE A
HAZARDOUS WASTE BY RCRA CRITERIA (40 CFR 261). DISPOSE OF ACCORDING TO
APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS.
Handling And Storage Precautions: STORE IN COOL, DRY AREA AWAY FROM HIGH
TEMPERATURES AND FLAMES. HANDLING: AVOID CONTACT WITH SKIN, EYES OR CLOTHING.
WASH THOROUGHLY WITH SOAP AND WATER AFTER USING AND PARTICULARLY BEFORE
EATING, DRI NKING, SMOKING, APPLYING COSMETICS, OR USING TOILET FACILITIES.
(OTHER INFORMATION)
Other Precautions: PROVIDE APPROPRIATE VENTILATION AND RESPIRATORY PROTECTION
AGAINST DECOMPOSITION PRODUCTS DURING WELDING AND FLAME CUTTING OPERATIONS
AND TO PROTECT AGAINST NUISANCE DUST DURING SANDING OR GRINDING OF CURED
PRODUCT. LAUNDER CONTAMINATED CLOTHING AND PROTECTIVE GEAR BEFORE REUSE.
DISCARD CONTAMINATED LEATHER ARTICLES.
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Fire and Explosion Hazard Information
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Flash Point Method: TCC
Flash Point: >93.3C, 200.F
Lower Limits: N/D
Upper Limits: N/D
Extinguishing Media: WATER, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures: FIREFIGHTERS SHOULD WEAR NIOSH APPROVED
SELF-CONTAINED BREATHING APPARATUS AND SUFFICIENT PROTECTIVE GEAR TO PREVENT
ALL SKIN AND EYE CONTACT WITH THIS MATERIAL.
Unusual Fire/Explosion Hazard: NONE. HAZARDOUS PRODUCT OF COMBUSTION: ACRID AND
TOXIC FUMES WITH ORGANIC AMINES, AMMONIA, OXIDES OF CARBON AND NITROGEN.
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Control Measures
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Respiratory Protection: NONE NEEDED IN NORMAL USE WITH PROPER VENTILATION. IN
POORLY VENTILATED AREAS OR WHEN CREATING A DUST OR MIST, USE NIOSH APPROVED
ORGANIC VAPOR RESPIRATOR.
Ventilation: GENERAL MECHANICAL VENTILATION IS ADEQUATE FOR OCCASIONAL USE. FOR
PROLONGED OR REPEATED USE, LOCAL EXHAUST IS RECOMMENDED.
Protective Gloves: CHEMICAL RESISTANT RUBBER (FOR EXAMPLE , NEOPRENE, BUTYL
RUBBER OR (SUPP DATA)
Eye Protection: ANSI APPROVED SAFETY GLASSES WITH SIDESHIELDS OR CHEMICAL
GOGGLES.
Other Protective Equipment: HAVE EMERGENCY SHOWER AND EYE WASH STATIONS MEETING
ANSI DESIGN CRITERIA AVAILABLE.
Work Hygienic Practices: WASH THOROUGHLY WITH SOAP AND WATER AFTER USING AND
PARTICULARLY BEFORE EATING, DRINKING, SMOKING, APPLYING COSMETICS, OR USING
TOILET FACILITIES. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health: PRODUCT IDENTIFIER: EPOXY HARDENER. CHEMICAL
FAMILY: POLYAMINES & MODIFIED POLYAMINES. GENERAL USE: (FOR HARDENER
ONLY): PROPERLY MIXED & CURED EPOXIES ARE NOT HAZARDOUS. GLOVES (CONT'D):
NITRILE) GLO VES & OTHER PROTECTIVE GEAR AS NEEDED TO PREVENT SKIN
CONTACT. PHYS/CHEM DATA: VOL (G/L): 0. % SOLID BY WEIGHT: 100.
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Physical/Chemical Properties
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Boiling Point: >232.2C, 450.F
M.P/F.P Text: N/D
Vapor Pres: <0.01 AT 68F
Vapor Density: (AIR=1)>1
Spec Gravity: 0.98
PH: 10-11
Solubility in Water: 30-60%
Appearance and Odor: WHITE PASTE WITH MILD AMMONIA-LIKE ODOR.
Percent Volatiles by Volume: 0
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: EXTREME HEAT OR OPEN FLAME.
Materials To Avoid: STRONG OXIDIZERS, ACIDS AND CHLORINATED ORGANIC COMPOUNDS.
Hazardous Decomposition Products: ACRID AND TOXIC FUMES WITH ORGANIC AMINES,
AMMONIA, OXIDES OF CARBON AND NITROGEN.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: HEAT IS RELEASED WHEN THIS PRODUCT IS MIXED
WITH EPOXY RESINS. USE CARE WHEN MIXING LARGE QUANTITIES.
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Toxicological Information
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Toxicological Information: ACUTE ORAL EFFECTS: LD50 (RAT) >2000 MG/KG
(ESTIMATE). DERMAL EFFECTS: LD50 (RABBIT): >1000 MG/KG (ESTIMATE). TETA
FOUND TO BE TOXIC BY SKIN ABSORPTION (ANSI Z129.1 1988). TETA IS SEVERE
IRRITANT TO SKIN OF RABBIT. INHALATIONEFFECTS: LC50 (RAT): NO DATA. EYE
IRRITATION: TETA IS SEVERE IRRITANT TO EYES OF RABBIT. SUBCHRONIC EFFECTS: NO
DATA. CARCINODENCITY, TERATOGENICITY AND MUTAGENICITY: TETA W AS FOUND
FETOTOXIC AND TERATOGENIC WHEN FED TO RATS AT 0.83% AND 1.67% OF DIET. WHEN
APPLIED DERMALLY TO THE SKIN OF PREGNANT GUINEA PIGS, THERE WAS 90% ABORTION
RATE (ECOLOGICAL)
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Ecological Information
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Ecological: ECOTOXICITY: NO DATA. MOBILITY AND PERSISTENCE: NO DATA.
ENVIRONMENTAL FATE: NO DATA. TOXICOLOGICAL (CONT):OR DEATH OF FETUS
W/DEVELOPMENTAL ANOMALIES. NONYLPHENOL HAS CAUSED ALLERGIC SENSITIZATION I N
HUMANS. OTHER CHRONIC EFFECTS: IT HAS BEEN GENERALLY OBSERVED IN ANIMAL
STUDIES THAT ALIPHATIC AMINES CAN CAUSE CHANGES IN THE LUNG & HEART. TETA
HAS BEEN FOUND TO PRODUCE LIVER & KIDNEY DAMAGE & BR AIN CONGESTION
IN DERMALLY EXPOSED ANIMALS. TRIETHYLENETETRAMINE: ORAL LD50 (RAT) 2460
MG/KG, DERMAL LD50 (RABBIT) 805 MG/KG, INHALATION LC50-4HR (RAT) N/D.
AMINOETHYLPIPERAZINE: ORAL LD50 (RAT) 2140 MG/KG, DERMAL LD50 (RABBIT) 900
(SARA)
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MSDS Transport Information
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Transport Information: PROPER SHIPPING NAME: NON-REGULATED. TECHNICAL NAME:
N/A, HAZARD CLASS: N/A, UN NUMBER: N/A, PACKING GROUP: N/A, EMERGENCY
RESPONSE GUIDE NO: N/A, IMDG PAGE NUMBER: N/A, OTHER: N/A. THIS MATERIAL HA S
BEEN TESTED IN ACCORDANCE WITH REQUIREMENTS OF 49CFR 173.136 AND FOUND NOT TO
BE CORROSIVE FOR TRANSPORTATION.
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Regulatory Information
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Sara Title III Information: FOR PURPOSES OF SARA SECTION 312 HAZARDOUS
MATERIALS INVENTORY REPORTING, THE FOLLOWING HAZARD CLASSES APPLY: IMMED
HEALTH HAZARD - DELAYED HEALTH HAZARD. STATE REGULATORY (CONT): PROTECT
AGAINST NUIS ANCE DUST DURING SANDING/GRINDING OF CURED PRODUCT. ECOLOGICAL
(CONT): MG/KG. INHALATION LC50 4 HR (RAT) N/D. NONYLPHENOL: ORAL LD50 (RAT)
1620 MG/KG, DERMAL LD50 (RABBIT) 2140 MG/KG, INHALATION LC50 4HR, (RAT)
>1 MG/L. DIMER/TOFA, REACTION PRODUCTS WITH TETA: ORAL LD50 (RAT) N/D,
DERMAL LD50 (RABBIT) N/D, INHALATION LC50 4HR, (RAT) N/D.
Federal Regulatory Information: TSCA: ALL INGREDIENTS OF THIS PRODUCT ARE
LISTED OR ARE EXEMPT FROM LISTING ON THE TSCA INVENTORY. THE FOLLOWING RCRA
CODE(S) APPLIES TO THIS MATERIAL IF IT BECOMES WASTE: NONE. REGULATORY STATUS
OF H AZARDOUS CHEMICAL CONSTITUENTS OF THIS PRODUCT: TRIETHYLENETETRAMINE,
AMINOETHYLPIPERAZINE, NONYLPHENOL, DIME/TOFA, REACTION PRODUCTS WITH TETA -
(EXTREMELY HAZARDOUS*) NO, (TOXIC CHEMICAL**) NO, (CER CLA RQ (LBS)) 0.0,
(TSCA 12B EXPORT NOTIFICATION) NOT REQUIRED. CANADIAN REGULATIONS: W HAZARD
CLASS(ES): D2B, D2A ALL COMPONENTS OF THIS PRODUCT ARE ON THE DOMESTIC
SUBSTANCES LIST.
State Regulatory Information: N/P.
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Other Information
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Other Information: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM () RATINGS:
HEALTH: 3*, FLAMMABILITY: 1 AND REACTIVITY: 1. HANDLING/STORAGE (CONT'D):
HANDLE MIXED RESIN AND HARDENER IN ACCORDANCE WITH THE POTENTIAL HAZ ARD OF
THE CURING AGENT USED.
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HAZCOM Label
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MSDS NAME: PUTTY HARDENER, 10650, 11410, 11420, DE087
Assigned IND: Y
Company: ITW DEVCON
Street: 30 ENDICOTT ST.
City: DANVERS MA
Zipcode: 01923
Health Emergency Phone: (800) 424-9300
Label Required IND: Y
Date Of Label Review: 01/09/2001
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: WARNING: SEVERE EYE, SKIN & RESPIRATORY IRRIT.
ACUTE: SKIN: MAY BE ABSORBED THRU SKIN. MAY CAUSE SKIN SENSITIZATION,
ITCHING, RASHES, SWELLING. EYE: CONJUNCTIVITIS OR CORNEAL DMG. INHAL: IRRIT
OF NOSE & THROAT. NAUSEA & VOMITTING IN SEVERECASES. INGEST: IRRIT
OF MOUTH, THROAT & GI TRACT. CHRONIC: INHAL: RPTD/PRLNG EXPOS TO LOW
CONCENTRATION OF VAPOR MAY CAUSE SORE THROAT, EYE IRRIT, NAUSEA, FAINT,
HEADACHE, WHICH ARE TRANSIENT. SKIN: DEFATTING, RASH, IRRIT OR CORROSION.
TETA MAY CAUSE RESPIRATORY SENSITIZATION & CHRONIC LUNG TOXICITY (COUGH,
TIGHTNESS OF CHEST, SHORTNESS OF BREATH). NONYLPHENY L HAS CAUSED ALLERGIC
SENSITIZATION IN HUMANS.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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