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MSDS  : 40-3905 RESIN
CAS  :
NAME  : *** proprietary ***
EPOXIES, ETC... -- 40-3905 RESIN
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CKXGL
MSDS NAME: 40-3905 RESIN
Responsible Party
Name: EPOXIES, ETC...
Box: 508
City: GREENVILLE RI 02828
Info Phone: (800) 255-3924
Emergency Phone Number: (800) 255-3924
Proprietary Ind: Y
Review Ind: Y
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: EPOXIES, ETC...
Box: 508
City: GREENVILLE RI 02828
Phone: (800) 255-3924
=======================================================
Ingredients
=======================================================
Name: *** PROPRIETARY ***
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: LD50 (ORAL, RAT): 11.4 G/KG
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: SKIN: BASED ON SIMILAR PRODUCT TESTING PRODUCT IS
MODERATELY IRRITATING TO SKIN & MAY CAUSE SKIN SENSITIZATION. CONTACT
WITH PRODUCT AT ELEVATED TEMPERATURES CAN RESULT IN THERMAL BURNS. EYES:
BASED O N SIMILAR PRODUCT TESTING PRODUCT IS MODERATELY IRRITATING TO EYES.
CONTACT W/PRODUCT AT ELEVATED TEMPERATURES CAN RESULT IN THERMAL BURNS.
INHALATION: BECAUSE OF ITS LOW VOLATILITY THIS PRODUCT IS NO T LIKELY TO BE
AN INHALATION HAZARD. INGESTION: BASED ON PRODUCT TESTING PRODUCT IS
CONSIDERED TO HAVE A LOW ORDER OF ACUTE ORAL TOXICITY. SIGNS & SYMPTOMS:
IRRITATION. SKIN SENSITIZER (ALLERGY) MAY B E EVIDENCED BY RASHES, ESPECIALLY
HIVES.
Medical Cond Aggravated By Exposure: PREEXISTING EYE, SKIN & RESPIRATORY
DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO PRODUCT. PREEXISTING SKIN/LUNG
ALLERGY MAY INCREASE CHANCE OF DEVELOPING INCREASED ALLERGY SYMPS FROM
EXPOSURE TO PRODUCT.
First Aid: SKIN: REMOVE CONTAMINATED CLOTHING/SHOES. WIPE EXCESS FROM SKIN
& WASH WITH PLENTY OF SOAP & WATER. GET PROMPT MEDICAL ATTENTION IF
IRRITATION OCCURS. IF CONTACT WITH HOT PRODUCT OCCURS, IMMEDIATELY F LUSH
WITH COOL WATER FOR FIFTEEN MINUTES. CAREFULLY REMOVE CLOTHING; IF CLOTHING
IS STUCK TO A BURN AREA DO NOT PULL IT OFF, BUT CUT AROUND IT. COVER BURN
AREA WITH CLEAN MATERIAL. GET MEDICAL ATTENTI ON IMMEDIATELY. EYES: IRRIGATE
EYES IMMEDIATELY WITH WATER FOR AT LEAST 15 MINS. WHILE HOLDING EYELIDS OPEN.
GET MEDICAL ATTENTION. (OTHER INFO)
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: MAY BURN ALTHOUGH NOT READILY IGNITABLE. USE CAUTIOUS
JUDGEMENT WHEN CLEANING UP LARGE SPILLS. LARGE SPILLS: WEAR RESPIRATOR AND
PROTECTIVE CLOTHING AS APPROPRIATE. SHUT OFF SOURCE OF LEAK IF SAFE TO DO
SO. DIKE AND CONTAIN. REMOVE WITH AN ABSORBENT SUCH AS CLAY, SAND OR OTHER
SUITABLE MATERIAL; DISPOSE OF PROPERLY, FLUSH AREA WITH WATER TO REMOVE TRACE
RESIDUE. SMALL SPILLS: TAKE (NEUT AGENT)
Neutralizing Agent: N/P. SPILL PROCEDURES (CONT'D): UP WITH AN ABSORBENT
MATERIAL AND DISPOSE OF PROPERLY.
Waste Disposal Methods: INCINERATE OR BURY IN AN APPROVED CHEMICAL DISPOSAL
FACILITY IN A MANNER WHICH COMPLIES WITH ALL LOCAL, STATE AND FEDERAL
REGULATIONS.
Handling And Storage Precautions: PRACTICE & OBSERVE GOOD HOUSEKEEPING
PROCEDURES IN PERSONAL HYGIENE & CLEANLINESS. AVOID SKIN & EYE
CONTACT, AS WELL AS, BREATHING OF VAPOR/FUMES ESPECIALLY WHEN MATERIAL IS
HEATED. TO PREVENT THERMAL S BURNS, AVOID SKIN & EYE CONTACT W/HOT
LIQUID. CONTAINERS, EVEN THOSE THAT HAVE BEEN (OTHER PREC)
Other Precautions: HNDLG/STOR (CONT'D): EMPTIED, CAN CONTAIN HAZARDOUS PRODUCT
RESIDUES. HANDLE IN ACCORDANCE WITH HAZARD POTENTIAL OF CURING AGENT(S) USED.
STORE IN COOL, DRY AREA. KEEP AWAY FROM OPEN FLAMES & HIGH TE MPS. IF
THIS RESIN IS HANDLED, SHIPPED, OR STORED IN BULK, THE RECOMMENDED PUMPING
TEMP IS 180F MAX. (TRANSPORT INFO)
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: PMCC
Flash Point: =248.9C, 480.F
Extinguishing Media: USE WATER FOG, FOAM, DRY CHEMICAL, OR CO2.
Fire Fighting Procedures: MATERIAL WILL NOT BURN UNLESS PREHEATED. DO NOT ENTER
CONFINED FIRE SPACE W/O FULL BUNKER GEAR (HELMET WITH FACESHIELD, BUNKER
COAT, GLOVE & RUBBER BOOT). FIREFIGHTERS SHOULD WEAR FULL EMERGENCY EQUIP
INCLUDING NIOSH APPROVED SCBA. USE COLD SPRAY TO COOL DOWN FIRE & HEAT
EXPOSED CONTAINERS TO KEEP THEM FROM RUPTURING.
Unusual Fire/Explosion Hazard: HEATING RESIN ABOVE 300 DEG F IN THE PRESENCE OF
AIR MAY CAUSE SLOW OXIDATIVE DECOMPOSITION. ABOVE 500 DEG. F, POLYMERIZATION
MAY OCCUR. SOME CURING AGENTS, E.G. ALIPHATIC POLYAMINES CAN PRODUCE EXOTH
ERMIC REACTIONS, WHICH IN LARGE MASSES CAN CAUSE RUNAWAY POLYMERIZATION AND
(STATE REG)
=======================================================
Control Measures
=======================================================
Respiratory Protection: NIOSH APPROVED RESPIRATOR APPROPRIATE FOR THE EXPOSURE
OF CONCERN (FP N). NOT ORDINARILY REQUIRED (MFR).
Ventilation: LOCAL EXHAUST RECOMMENDED.
Protective Gloves: CHEMICALLY RESISTANT RUBBER TYPE GLOVES RECOMMENDED.
Eye Protection: ANSI APPROVED CHEMICAL SAFETY GOGGLES WITH SIDE SHIELDS
RECOMMENDED.
Other Protective Equipment: WEAR CHEMICAL RESISTANT CLOTHING TO MINIMIZE
CONTACT. EYE WASH FOUNTAINS AND SAFETY SHOWERS MEETING ANSI DESIGN CRITERIA
SHOULD BE AVAILABLE FOR EMERGENCY USE.
Work Hygienic Practices: WASH WIITH SOAP AND WATER BEFORE EATING, DRINKING,
SMOKING, APPLYING COSMETICS, OR USING TOILET FACILITIES. LAUNDER
CONTAMINATED CLOTHING BEFORE REUSE. CONTAMINATED LEATHER ARTICLES, (SUPP
SFTY)
Supplemental Safety and Health: HYGIENE PRACTICE (CONT'D): INCLUDING SHOES, CAN
NOT BE DECONTAMINATED AND SHOULD BE DESTROYED TO PREVENT USE.
=======================================================
Physical/Chemical Properties
=======================================================
Boiling Point: >260.C, 500.F
Vapor Pres: .03 (MM HG)
Spec Gravity: 1.20
Solubility in Water: NEGLIGIBLE.
Appearance and Odor: LIQUID FORM, MILD ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES E HEAT. (CNDTNS, STAB)
Stability Condition To Avoid: N/P. MATERIALS TO AVOID (CONT'D): RUNAWAY
CHAIN REACTIONS MAY CHAR AND DECOMOSE THE RESIN SYSTEM, GENERATING
UNIDENTIFIED FUMES AND VAPORS THAT MAY BE TOXIC.
Materials To Avoid: CAN REACT VIGOROUSLY WITH STRONG OXIDATION AGENTS, STRONG
LEWIS OR MINERAL ACIDS, AND STRONG MINERAL, ORGANIC BASES/ESPECIALLY PRIMARY
AND SECONDARY ALIPHATIC AMINES. REACTIONS WITH SOME CURING AGENTS MAY PRODUCE
CONSIDERAB
Hazardous Decomposition Products: CARBON MONOXIDE, ALDEHYDES, ACIDS, AND OTHER
ORGANIC SUBSTANCES MAYBE FORMED DURING COMBUSTION OR ELEVATED (>500.F.)
TEMPERATURE DEGRADATION.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL N OT OCCUR.
=======================================================
Toxicological Information
=======================================================
Toxicological Information: PRODUCT IS AN EPOXY RESIN PRODUCED BY THE
CONDENSATION REACTION OF EPICHLOROHYDRIN & BISPHENOL-A. THESE RAW
MATERIALS ARE CONSUMED IN THE PROCESS. RESIDUAL LEVELS OF EPICHLOROHYDRIN ARE
CONTROLLED TO 1 PPM. MA. IN THE PRODUCT. ACUTE TOXICITY DATA: ORAL (RAT)
LD50: 11.4 G/KG, (MOUSE) 15.6 G/KG. DERMAL LD50: >20ML/KG (RABBIT).
INHALATION LC50: NO DEATHS IN SAT'D AIR, 8 HR. THIS INHALATION TEST MA Y NOT
BE RELEVANT DUE TO LOW VOLATILITY OF THE RESIN. CHRONIC STUDIES: RECENT
2-YEAR BIOASSAYS IN MICE EXPOSED BY THE DERMAL ROUTE TO THE DIGLYCIDYL ETHER
OF BISPHENOL-A RESIN (DGEBPA) OR TWO OTHER CO MMERCIAL RESINS WHICH ARE
(SARA)
=======================================================
Ecological Information
=======================================================
Ecological: KEEP OUT OF SURFACE WATERS, SEWERS AND WATERWAYS ENTERING OR
LEADING TO SURFACE WATERS. NOTIFY AUTHORITIES IF ANY EXPOSURE TO THE GENERAL
PUBLIC OR ENVIRONMENTAL OCCURS OR IS LIKELY TO OCCUR. IF THIS PRODUCT
BECOMES A WASTE, IT WOULD NOT BE A HAZARDOUS WASTE BY RCRA CRITERIA (40 CFR
261). PLACE IN AN APPROPRIATE DISPOSAL FACILITY IN COMPLIANCE WITH LOCAL
REGULATIONS.
=======================================================
MSDS Transport Information
=======================================================
Transport Information: D.O.T. SHIPPING NAME: NOT A REGULATED MATERIAL.
TECHNICAL SHIPPING NAME: NONE ESTABLISHED. D.O.T. HAZARD CLASS: NONE
ESTABLISHED. UN/NA NUMBER: NONE ESTABLISHED. OTHER PRECAUTIONS (CONT'D):
CAUTION: M AY CAUSE IRRITATION. AVOID CONTACT WITH EYES. AVOID PROLONGED AND
REPEATED CONTACT WITH SKIN.
=======================================================
Regulatory Information
=======================================================
Sara Title III Information: N/P. TOXICOLOGICAL INFO (CONT'D): COMPOSED
PREDOMINANTLY OF DIGLYCIDYL ETHER OF BISPHENOL-A HAVE YIELDED VERY LITTLE
EVIDENCE OF WEAK CARCINOGENICITY. DGEBPA IS A COMPONENT OF THIS RESIN.
AUTHORS OF THIS WORK CONCLUDED THAT RENAL TUMOR EVIDENCE WITH THIS RESIN
"WAS OF NO BIOLOGICAL SIGNIFICANCE" & THAT THE RESIN "IS NOT A SYSTEMATIC
CARCINOGEN WHEN APPLIED TO DORSAL SKIN OF CF1 MICE." BASED UPON THIS &
ALL OTHER AVAILABLE INFORMATION. THE INTERNAL AGENCY FOR RESEARCH ON CANCER
(IARC) CONCLUDED (1988) THAT DGEBPA WAS NOT CLASSIFIED AS A CARCINOGEN (IARC
GROUP 3) BASED ON THE FOLLOWING: HUMAN EVIDENCE - INADEQUATE: ANIMAL (FED
REG)
Federal Regulatory Information: ALL INGREDIENTS OF THIS COMPOUND ARE LISTED ON
THE EPA/TSCA INVENTORY OF CHEMICAL SUBSTANCES. PROTECTION OF STRATOSPHERIC
OZONE (PURSUANT TO SECTION 611 OF CLEAN AIR ACT AMENDMENTS OF 1990); PER 40
CF R PART 82. THE BASE RESIN DOES NOT CONTAIN NOR WAS IT DIRECTLY
MANUFACTURES WITH ANY CLASS 1 OR CLASS 2 OZONE DEPLETING SUBSTANCES. SARA
(CONT'D): EVIDENCE -- INADEQUATE. MUTAGENICITY: DGEBPA (A COMP ONENT OF THIS
PRODUCT) HAVE PROVED TO BE INACTIVE WHEN TESTED BY IN VIVO MUTAGENICITY
ASSAYS. IT HAS SHOWN ACTIVITY BY IN VITRO MICROBIAL MUTAGENICITY SCREENING
& HAVE BOTH PRODUCED CHROMOSOMAL ABERRATIONS IN CULTURED RAT LIVER.
State Regulatory Information: N/P. FEDERAL REGS (CONT): THE SIGNIFICANCE OF
THIS INFORMATION TO MAN IS UNKOWN. EXPLOSION HAZARDS (CONT'D): CHARRING OF
THE REACTANTS. FUMES & VAPORS FROM THESE THERMAL & CHEMICAL
DECOMPOSITIONS VAR Y WIDELY IN COMPOSITION & TOXICITY. DO NOT BREATHE
FUMES. USE A NIOSH APPROVED RESPIRATOR AS REQUIRED TO PREVENT OVEREXPOSURE.
IN ACCORD WITH 20 CFR1910.134, USE EITHER AN ATMOSPHERE SUPPLY RESPIRATOR OR
AN AIR-PURIFYING RESPIRATOR FOR ORGANIC VAPORS.
=======================================================
Other Information
=======================================================
Other Information: FIRST AID (CONT'D): IF CONTACT WITH HOT PRODUCT OCCURS
IMMEDIATELY FLUSH WITH COOL WATER FOR 15 MINS. GET MEDICAL ATTENTION
IMMEDIATELY. INHALATION: REMOVE TO FRESH AIR, GIVE OXYGEN IF BREATHING IS DI
FFICULT. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. IN
GENERAL, NO TREATMENT IS NECESSARY UNLESS LARGE QUANTITIES OF PRODUCT ARE
INGESTED. HOWEVER, GET MEDICAL ADVICE. NOTE TO PHYSICIAN : IN GENERAL EMISIS
INDUCTION UNNECESSARY IN HIGH VISCOSITY, LOW VOLATILITY PRODUCTS, E.G., NEAT
EPOXY RESINS. : HEALTH -2, FLAMMABILITY-1, REACTIVITY-0. CHEMICAL FAMILY:
EPOXY RESIN. FORMULA: P ROPRIETARY/TRADE SECRET.
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: 40-3905 RESIN
Assigned IND: Y
Company: EPOXIES, ETC...
PO Box: 508
City: GREENVILLE RI
Zipcode: 02828
Health Emergency Phone: (800) 255-3924
Label Required IND: Y
Date Of Label Review: 01/04/2001
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Moderate
Fire Hazard: Slight
Reactivity Hazard: Slight
Hazard And Precautions: ACUTE: SKIN: BASED ON SIMILAR PROD TESTING PROD IS
MODERATELY IRRIT TO SKIN. BASED ON SIMILAR PROD TESTING PROD MAY CAUSE SKIN
SENSITIZATION. CONTACT W/PRODUCT AT ELEVATED TEMP CAN RESULT IN THERMAL B
URNS. EYES: BASED ON SIMILAR PRODTESTINGPROD IS MODERATELY IRRIT TO EYES.
CONTACT W/PROD AT ELEVATED TEMP CAN RESULT IN THERMAL BURNS. INHAL: BECAUSE
OF ITS LOW VOLATILITY THIS PROD IS NOT LIKELY TO B E AN INHAL HAZ. INGEST:
BASED ON PROD TESTING PROD IS CONSIDERED TO HAVE A LOW ORDER OF ACUTE ORAL
TOXICITY. SIGNS & SYMPTOMS: IRRITATION. CHRONIC: SKIN SENSITIZER
(ALLERGY) MAY BE EVIDENCED BY RASHES , ESPECIALLY HIVES.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.

*** END OF RECORD ***
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