ITW DEVCON -- FASMETAL RESIN, 0136
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Material Safety Data Sheet
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MSDS Num: CKXCL
MSDS NAME: FASMETAL RESIN, 0136
Responsible Party
Name: ITW DEVCON
Address: 30 ENDICOTT ST.
City: DANVERS MA 01923
Info Phone: (978) 777-1100
Emergency Phone Number: (800) 424-9300
Chemtrec IND/Phone: (800)424-9300
Review Ind: Y
Published: Y
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Contractor Summary
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Name: ITW DEVCON
Address: 30 ENDICOTT ST.
City: DANVERS MA 01923
Phone: (978) 777-1100
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Ingredients
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Cas: 25068-38-6
RTECS #: CE6880000
Name: BISPHENOL A DIGLYCIDYL ETHER RESIN (DGEBPA)
> Wt: 40.
Other REC Limits: N/E
OSHA PEL: N/E
ACGIH TLV: N/E
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Health Hazards Data
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Route Of Entry Inds - Inhalation: NO
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: THE EYE IS LISTED AS A ROUTE OF ENTRY. CAUTION! EYE AND
SKIN IRRITANT (EVIDENCED BY ITCHING, REDNESS). POTENTIAL SKIN SENSITIZER..
Explanation Of Carcinogenicity: CANCER-SUSPECT CONSTITUENT(S): NONE.
Signs And Symptions Of Overexposure: ACUTE: SKIN: MODERATE IRRITANT. CONTACT AT
ELEVATED TEMPERATURES CAN CAUSE THERMAL BURNS. MAY CAUSE SKIN SENSITIZATION
(RASHES, HIVES). EYES: MODERATE IRRITANT. CONTACT AT ELEVATED TEMPERATURES
CAN CA USE THERMAL BURNS. INHALATION: LOW VAPOR PRESSURE OF THE RESIN MAKES
INHALATION UNLIKELY IN NORMAL USE. INGESTION: ACUTE ORAL TOXICITY IS LOW. MAY
CAUSE GASTRIC DISTRES. CHRONIC: PROLONGED OR REPEATE D SKIN CONTACT MAY
CAUSE SENSITIZATION, WITH ITCHING, SWELLING OR RASHES ON LATER EXPOSURE.
Medical Cond Aggravated By Exposure: PREEXISTING EYE AND SKIN DISORDERS.
DEVELOPMENT OF PREEXISTING SKIN AND LUNG ALLERGY SYMPTOMS MAY INCREASE.
First Aid: EYES: FLUSH EYE W/CLEAN WATER FOR AT LEAST 15 MIN WHILE GENTLY
HOLDING EYELID OPEN. GET IMMEDIATE MEDICAL ATTENTION. SKIN: IMMEDIATELY
REMOVE CONTAMINATED CLOTHING & EXCESS CONTAMINANT. FLUSH SKIN W/W ATER.
WASH THOROUGHLY W/SOAP & WARM WATER. CONSULT A DOCTOR IF IRRIT DEVELOPS.
INHAL: REMOVE PATIENT TO FRESH AIR. ADMINISTER OXYGEN IF BREATHING IS
DIFFICULT. GET MEDICAL ATTEN IF SYMPTOMS PERSIST. I NGEST: DO NOT INDUCE
VOMITING. GIVE 2 GLASSES OF WATER TO DILUTE IF PATIENT IS CONSCIOUS. GET
MEDICAL ATTEN. NOTE TO PHYSICIAN: IN GENERAL, EMESIS INDUCTION IS UNNECESSARY
IN HIGH VISCOSITY, LOW VOLAT ILITY PRODUCTS, E.G., NEAT EPOXY RESINS.
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Handling and Disposal
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Spill Release Procedures: AVOID PERSONAL CONTACT. ELIMINATE IGNITION SOURCES.
VENTILATE AREA. DIKE, CONTAIN AND ABSORB WITH CLAY, SAND OR OTHER SUITABLE
MATERIAL. CLEANUP: FOR LARGE SPILLS, PUMP TO STORAGE OR SALVAGE VESSELS.
SOAK UP RESIDUE WITH AN ABSORBENT SUCH AS CLAY, SAND, OR OTHER SUITABLE
MATERIAL AND DISPOSE OF PROPERLY. FLUSH AREA WITH WATER TO REMOVE TRACE
RESIDUE. PREVENT SPILL (NEUTRALIZING AGENT)
Neutralizing Agent: SPILL RELEASE (CONT'D: FROM ENTERING DRAINAGE OR SEWER
SYSTEMS, WATERWAYS AND SURFACE WATERS.
Waste Disposal Methods: IF THIS RESIN BECOMES A WASTE, IT WOULD NOT BE A
HAZARDOUS WASTE BY RCRA CRITERIA (40CFR 261). DISPOSE OF ACCORDING TO
APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS.
Handling And Storage Precautions: HANDLING: AVOID CONTACT WITH SKIN, EYES, OR
CLOTHING. HANDLE MIXED RESIN AND HARDENER IN ACCORDANCE WITH THE POTENTIAL
HAZARD OF THE CURING AGENT USED. PROVIDE APPROPRIATE VENTILATION/RESPIRATORY
PROT ECTION AGAINST DECOMPOSITION PRODUCTS DURING WELDING/FLAME CUTTING
OPERATIONS (OTHER PRECAUTIONS)
Other Precautions: HANDLING/STORAGE (CONT'D): AND TO PROTECT AGAINST NUISANCE
DUST DURING SANDING/GRINDING OF CURED PRODUCT. STORAGE: STORE IN A COOL, DRY
AREA AWAY FROM HIGH TEMPEATURES AND FLAMES. WASH THOROUGHLY AFTE R HANDLING.
DO NOT TAKE INTERNALLY.
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Fire and Explosion Hazard Information
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Flash Point Method: PMCC
Flash Point: >204.4C, 400.F
Flash Point Text: >400
Lower Limits: N/D
Upper Limits: N/D
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures: MATERIAL WILL NOT BURN UNLESS PREHEATED. DO NOT ENTER
CONFINED SPACE WITHOUT FULL BUNKER GEAR. FIREFIGHTERS SHOULD WEAR NIOSH
APPROVED SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
COOL FIRE EXPOSED CONTAINERS WITH WATER.
Unusual Fire/Explosion Hazard: HEATING ABOVE 300 DEG F IN THE PRESENCE OF AIR
MAY CAUSE SLOW OXIDATIVE DECOMPOSITION AND ABOVE 500 DEG F MAY CAUSE
POLYMERIZATION. HAZARDOUS PRODUCTS OF COMBUSTION: WHEN HEATED TO
DECOMPOSITION IT EMITS FUMES OF CL-, CARBON MONOXIDE, OTHER FUMES AND VAPORS
VARYING IN COMPOSITION AND TOXICITY.
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Control Measures
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Respiratory Protection: NONE REQUIRED AT NORMAL HANDLING TEMPERATURES AND
CONDITIONS. USE NIOSH APPROVED ORGANIC VAPOR CARTIDGES FOR UNCURED RESIN AND
DUST/PARTICLE RESPIRATORS DURING GRINDING/SANDING OPERATIONS OF CURED RES IN
AS EXPOSURE LEVELS DICTATE.
Ventilation: LOCAL EXHAUST VENTILATION IS PERFERRED ALTHOUGH GOOD GENERAL
MECHANICAL VENTILAITON IS USUALLY ADEQUATE FOR MOST INDUSTRIAL APPLICATIONS.
LOCAL (SUPP SFTY)
Protective Gloves: CHEMICAL-RESISTANT GLOVES.
Eye Protection: ANSI APPROVED CHEMICAL SAFETY GOGGLES AND FULL FACESHIELD (FP
N). ( SUPP SFTY)
Other Protective Equipment: HAVE EMERGENCY SHOWER AND EYE WASH MEETING ANSI
DESIGN CRITERIA AVAILABLE. OTHER GEAR AS REQUIRED TO PREVENT SKIN CONTACT.
Work Hygienic Practices: WASH THOROUGHLY WITH SOAP AND WATER AFTER USING AND
PARTICULARLY BEFORE EATING, DRINKING, SMOKING, APPLYING COSMETICS OR USING
TOILET FACILITIES. LAUNDER CONTAMINATED CLOTHING AND PROTECTIVE (SUPP SFTY)
Supplemental Safety and Health: VENTILATION (CONT'D): EXHAUST IS RECOMMENDED
FOR CONFINED AREAS. HYGIENE PRACTICE CONT'D): GEAR BEFORE REUSE. DISCARD
CONTAMINATED LEATHER ARTICLES. EYE PROTECTION (CONT'D): SAFETY GLASSES WITH
SIDE SHIELDS (MFR). PHYSICAL/CHEMICAL PROPERTIES: PERCENT SOLIDS BY WEIGHT:
100.
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Physical/Chemical Properties
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Boiling Point: >260.C, 500.F
M.P/F.P Text: N/D
Vapor Pres: 0.03 MM HG AT 171 F
Vapor Density: (AIR=1) >1
Spec Gravity: 1.7
PH: NEUTRAL
Evaporation Rate & Reference: (BUTYL ACETATE=1)
Solubility in Water: NEGLIGIBLE.
Appearance and Odor: GRAY PASTE WITH LITTLE ODOR.
Percent Volatiles by Volume: 0
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: THIS MATERIAL IS CHEMICALLY STABLE. AVOID OPEN
FLAME AND EXTREME HEAT.
Materials To Avoid: STRONG LEWIS OR MINERAL ACIDS, STRONG OXIDIZING AGENTS,
STRONG MINERAL AND ORGANIC BASES (ESPECIALLY PRIMARY AND SECONDARY ALIPHATIC
AMINES).
Hazardous Decomposition Products: OXIDES OF CARBON; ALDEHYDES, ACIDS AND OTHER
ORGANIC SUBSTANCES MAY BE FORMED DURING COMBUSTION OR ELEVATED TEMPERATURE
(>500 DEG F) DEGRADATION.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: HEAT IS GENERATED WHEN RESIN IS MIXED WITH
CURING AGENTS; RUN-AWAY CURE REACTIONS MAY CHAR AND DECOMPOSE (OTHER
INFORMATION)
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Toxicological Information
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Toxicological Information: BISPHENOL A DIGLYCIDYL ETHER RESIN: LD50 (ORAL,
RAT) 30 G/KG, LD50 (DERMAL,RABBIT) >20 ML/KG, LC50, 4HR (, INHAL, RAT):
NO DEATHS. ACUTE ORAL EFFECTS: LD50 (RAT): NOT AVAILABLE. ACUTE DERMAL
EFFECTS : LD50 (RABBIT): NOT AVAILABLE. ACUTEINHALATION: LC50 (RAT): NOT
AVAILABLE. EXPOSURE: 8 HOURS. EYE IRRITATION: NOT AVAILABLE. SUBCHRONIC
EFFECTS: NO DATA AVAILABLE. CARCINOGENICITY, TERATOGENICITY, A ND
MUTAGENICITY: BOTH THE RESIN AND THE DIGLYCIDYL ETHER OF BISPHENOL A (A
COMPONENT OF THIS PRODUCT) HAVE PROVED TO BE INACTIVE WHEN TESTED BY IN VIVO
MUTAGENICITY ASSAYS. BOTH (ECOLOGICAL)
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Ecological Information
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Ecological: ECOTOXICITY, MOBILITY AND PERSISTENCE, ENVIRONMENTAL FATE: NO DATA
AVAILABLE. TOX INFO (CONT'D): HAVE SHOWN ACTIVITY BY IN VITRO MICROBIAL
MUTAGENICITY SCREENING AND HAVE PRODUCED CHROMOSOMAL ABERRATI ONS IN CULTURED
RAT LIVER CELLS. OTHER CHRONIC EFFECTS: 2-YEAR BIOASSAYS IN MICE EXPOSED BY
THE DERMAL ROUTE TO EPON 828, DGEBPA, OR OTHER COMMERCIAL RESINS YIELDED
LIMITED EVIDENCE OF WEAK CARCINOGEN ICITY. THE AUTHORS CONCLUDED THAT RENAL
TUMOR EVIDENCE WITH EPON 828 " WAS OF NO BIOLOGICAL SIGNIFICANCE" AND THAT
THE RESIN "IS NOT A SYSTEMIC CARCINOGEN WHEN APPLIED TO THE DORSAL SKIN OF
CF1 MICE."
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MSDS Transport Information
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Transport Information: PROPER SHIPPING NAME: NON-REGULATED. TECHNICAL NAME,
HAZARD CLASS, UN NUMBER, PACKING GROUP, EMERGENCY RESPONSE GUIDE NO., AND
IMDG PAGE NUMBER: N/A.
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Regulatory Information
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Sara Title III Information: FOR PURPOSES OF SARA SECTION 312 HAZARDOUS MATERAL
INVENTORY REPORTING, THE FOLLOWING HAZARD CLASSES APPLY TO THIS MATERIAL:
IMMEDIATE HEALTH HAZARD, DELAYED HEALTH HAZARD.
Federal Regulatory Information: TSCA: ALL INGREDIENTS OFTHIS PRODUCT ARE
LISTED, OR ARE EXEMPT FROM LISTING, ON THE TSCA INVENTORY. EXPORT
NOTIFICATION IS REQUIRED UNDER TSCA SEC. 12B. THE FOLLOWING RCRA CODE(S)
APPLIES TO THIS MAT ERIAL IF IT BECOMES WASTE: NONE. REGULATORY STATUS OF
HAZARDOUS CHEMICAL CONSTITUENTS OF THIS PROD: BISPHENOL A DIGLYCIDYL ETHER
RESIN: EXTREMELY HAZARDOUS: NO. TOXIC CHEMICAL: NO. CERCLA RQ (LBS): 0. 0.
TSCA 12B EXPORT NOTIFICATION: REQUIRED. CANADIAN REGULATIONS: W HAZARD
CLASS: D2B. ALL COMPO NENTS OF THIS PRODUCT ARE ON THE DOMESTIC SUBSTANCES
LIST.
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Other Information
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Other Information:: HEALTH - 2, FLAMMABILITY - 1, REACTIVITY - 1. PRODUCT
IDENTIFIER: EPOXY RESIN. GENERAL USE: THIS INFORMATION APPLIES TO THE RESIN
COMPONENT OF THE TWO-PART KIT; HANDLE FRESHLY-MIXED RESIN AND HA RDENER AS
RECOMMENDED FOR HARDENER. AFTER CURING, PRODUCT IS NOT HAZARDOUS. CHEMICAL
FAMILY: FILLED EPOXY RESIN. THIS PRODUCT APPEARS IN THE FOLLOWING STOCK
NUMBERS: 10780 AND DE120. CONDITIONS TO AVO ID POLYMERIZATION (CONT'D): THE
RESIN, GENERATING UNIDENTIFIED FUMES AND VAPORS WHICH MAY BE TOXIC.
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HAZCOM Label
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MSDS NAME: FASMETAL RESIN, 0136
Assigned IND: Y
Company: ITW DEVCON
Street: 30 ENDICOTT ST.
City: DANVERS MA
Zipcode: 01923
Health Emergency Phone: (800) 424-9300
Label Required IND: Y
Date Of Label Review: 12/29/2000
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Slight
Reactivity Hazard: Slight
Hazard And Precautions: CAUTION! EYE AND SKIN IRRITANT (EVIDENCED BY ITCHING,
REDNESS). POTENTIAL SKIN SENSITIZER. DO NOT TAKE INTERNALLY. AVOID PROLONGED
OR REPEATED CONTACT WITH SKIN. ACUTE: SKIN: MODERATE IRRIT. CONTACT AT
ELEVATED TEMPS CAN CAUSE THERMAL BURNS. MAY CAUSE SKIN SENSITIZATION (RASHES,
HIVES). EYES: MODERATE IRRIT. CONTACT AT ELEVATED TEMPERATURES CAN CAUSE
THERMAL BURNS. INHALATION: LOW VAPOR VAPOR PRE SSURE OF THE RESIN MAKES
INHALATION UNLIKELY IN NORMAL USE. INGESTION: ACUTE ORAL TOXICITY IS LOW. MAY
CAUSE GASTRIC DISTRES. CHRONIC: PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE
SENSITIZATION, WITH ITCHING, SWELLING OR RASHES ON LATER EXPOSURE.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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