ARISTECH ACRYLICS LLC -- LB 1132-21
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Material Safety Data Sheet
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MSDS Num: CKXJB
MSDS NAME: LB 1132-21
Responsible Party
Name: ARISTECH ACRYLICS LLC
Address: 7350 EMPIRE DRIVE
City: FLORENCE, KY 41042
Info Phone: 412-433-7654/412-571-5888
Emergency Phone Number: (412) 571-5888
Resp. Party Other MSDS No.: C6029C
Proprietary Ind: Y
Review Ind: Y
Published: Y
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Contractor Summary
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Name: ARISTECH ACRYLICS LLC
Address: 7350 EMPIRE DRIVE
City: FLORENCE, KY 41042
Phone: (412) 433-7654 (412) 571-5888
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: LD50:>2000 MG/KG (UNSAT. POLY RESIN)
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: YES
OSHA: NO
Effects of Exposure: EMERGENCY OVERVIEW: WARNING! FLAMMABLE LIQUID AND VAPOR.
MAY CAUSE IRRIT TO THE EYES, SKIN AND RESP TRACT. MAY BE HARMFUL IF SWALLOWED
OR ABSORBED THROUGH THE SKIN. POSSIBLE ASPIRATION HAZARD. MAY CAU SE SKIN
SENSITIZATION. MAY CAUSE CNS EFFECTS. MAY CAUSE LIVER EFFECTS. SIGNS AND
SYMPTOMS OF ACUTE OVEREXPOSURE: INHALATION OF MISTS AND VAPORS MAY CAUSE URT
IRRITATION. SYMPTOMS MAY INCLUDE BURNING SENSATION OF EYES AND NOSE,
COUGHING, RUNNY NOSE, SNEEZING AND SORE THROAT. SEVERE INH MAY CAUSE CNS
DEPRESSION, CHARACTERIZED BY DROWSINESS, NAUSEA, HEADACHE, FATIGUE, NARCOSIS,
DIZZINESS & INCOORDIN ATION.(SIGNS & SYMPTOMS OF OVEREXPOSURE)
Explanation Of Carcinogenicity: STYRENE: IARC GROUP 2B, VOLUME 60, PAGE 233,
1994. IARC HAS RECLASSIFIED STYRENE FROM A GROUP 3 TO A GROUP 2B, NOW LABELED
AS POSSIBLY CARCINOGENIC TO HUMANS. THE NEW CLASSIFICATION IS NOT BASED ON AN
Y SIGNIFICANT NEW EVIDENCE THAT STYRENE MIGHT BE CARCINOGENIC, BUT RATHER ON
A BROADENING OF THE DEFINITION OF THE GROUP B CLASSIFICATION. (OTHER INFO)
Signs And Symptions Of Overexposure: HEALTH HAZARDS (CONT): SKIN CONTACT MAY
PRODUCE IRRITATION. SYMPTOMS MAY INCLUDE REDNESS, BURNING, AND ITCHING.
REPEATED OR PROLONGED EXPOSURE MAY DEVELOP INTO DERMATITIS, ECZEMA OR EVEN
SKIN SENSITIZ ATION. SYMPTOMS CAN INCLUDE BURNING, RASH, SCALING,CRACKED, DRY
SKIN AND POSSIBLE SWELLING. CONTACT WITH EYES MAY CAUSE IRRITATION, CAUSING
BURNING, PAIN, REDNESS AND TEARING. IF SWALLOWED, THIS PROD UCT MAY CAUSE
SORE THROAT, ABDOMINAL PAIN, VOMITING AND DIARRHEA. THIS PRODUCT CONTAINS
SYTRENE WHICH, IF SWALLOWED, MAY BE ASPIRATED INTO THE LUNGS CAUSING CHEMICAL
PNEUMONIA WHICH MAY BE LIFE THREAT ENING. SIGNS AND SYMPTOMS OF (SARA III)
Medical Cond Aggravated By Exposure: INDIVIDUALS W/CHRONIC RESPIRATORY
DISORDERS MAY BE ADVERSELY AFFECTED BY ANY FUME OR AIRBORNE PARTICULATE
MATTER EXPOS. PERSONS W/PREEXISTING SKIN DISORDERS MAY BE MORE SUSCEPTIBLE TO
EFFECTS THIS MATL.
First Aid: EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
CALL A PHYSICIAN IMMEDIATELY. SKIN: REMOVE CONTAMINATED CLOTHING. WASH SKIN
THOROUGHLY WITH SOAP AND PLENTY OF WATER. CALL A PHYSICIAN. CONTAMINATED
CLOTHING SHOULD BE LAUNDERED BEFORE REUSE. INGESTION: DO NOT INDUCE
VOMITING/POSSIBLE ASPIRATION HAZARD! CALL A PHYSICIAN OR POISON CONTROL
CENTER IMMEDIATELY. INHALATION: REMOVE FROM EX POSURE. IF BREATHING IS
DIFFICULT, ADMINISTR ARTIFICIAL RESPIRATION (MOUTH-TO-MOUTH) OR OXYGEN AS
INDICATED. CALL A PHYSICIAN IMMEDIATELY. NOTES TO PHYSICIAN: NONE KNOWN.
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Handling and Disposal
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Spill Release Procedures: REMOVE ALL IGNITION SOURCES. INCREASE VENTILATION TO
MAXIMIZE VAPOR DISPERSAL. DIKE LARGE SPILLS TO PREVENT RUNOFF INTO SEWERS OR
WATERWAYS. COVER SPILL WITH INORGANIC ABSORBENT MATERIAL (VERMICULITE) .
SWEEP UP AND PLACE IN LABELLED DRUM FOR DISPOSAL. STYRENE APPEARS ON THE
CERCLA LIST OF HAZARDOUS SUBSTANCES AND SPILLS OF REPORTABLE QUANTITIES MUST
BE REPORTED TO THE NATIONAL (NEUTRALIZING AGENT)
Neutralizing Agent: N/P. SPILL PROC (CONT): RESPONSE CENTER 800-424-8802.
THE CERCLA REPORTABLE QUANTITY FOR SYTRENE IS 1,000 LB.
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REQUIREMENTS. THIS PRODUCT MEETS THE FEDERAL EPA HAZARDOUS WASTE CRITERIA FOR
IGNITABILITY D001. OTHER PRECAUTIONS (CONT): ARE UNINHIBITED AND MAY
CAUSE BLOCKAGE OF VENTILATION VENTS DUE TO POLYMERIZATION. PERIODIC
INSPECTION MAY BE NECESS ARY TO PREVENT BLOCKAGE.
Handling And Storage Precautions: HANDLING: AVOID PROLONGED OR REPEATED CONTACT
WITH SKIN AND EYES. AVOID BREATHING MISTS AND VAPORS. USE APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT WHEN NECESSARY. USE WITH ADEQUATE VENTILATION.
STORAG E: FLAMMABLE MATERIAL, KEEP AWAY FROM IGNITION SOURCES AND EXCESSIVE
HEAT. STORE (OTHER PRECAUTIONS)
Other Precautions: HANDLING & STORAGE PRECAUTIONS (CONT): IN COOL, DRY AREA
AWAY FROM OXIDIZERS. DO NOT STORE IN DIRECT SUNLIGHT. WORK WITH ADEQUATE
GENERAL AND LOCAL EXHAUST VENTILATION TO MINIMIZE EXPOSURE TO VAPORS. BOND
& GROUND CONTAINERS FOR TRANSFER OF THIS PRODUCT TO PREVENT STATIC
SPARKS. STYRENE VAPORS (WAST E DISPOSAL METHOD)
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Fire and Explosion Hazard Information
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Flash Point Method: PMCC
Flash Point: =31.1C, 88.F
Lower Limits: 1.1% STYRENE
Upper Limits: 6.1% STYRENE
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL (SMALL FIRES); ALCOHOL FOAM
AND WATER FOG (LARGE FIRES). WATER MAY BE INEFFECTIVE, BUT SHOULD BE USED TO
KEEP FIRE-EXPOSED CONTAINERS COOL.
Fire Fighting Procedures: FIREFIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING
APPARATUS (NIOSH APPROVED - FP N) AND FULL PROTECTIVE CLOTHING WHEN FIGHTING
FIRES. USE COLD WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard: HIGH TEMPERATURE EXPOSURE FOR EXTENDED PERIODS
OF TIME WILL RESULT IN SPONTANEOUS UNCONTROLLED EXOTHERMIC POLYMERIZATION.
KNOWN OR ANTICIPATED HAZARDOUS PRODUCTS OF COMBUSTION: CO2, CO AND OTHER PO
TENTIALLY TOXIC PRODUCTS OF COMBUSTION.
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Control Measures
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Respiratory Protection: RESPIRATORY EQUIPMENT APPROVED BY NIOSH FOR PROTECTION
AGAINST ORGANIC VAPORS & MIST IS NECESS TO AVOID INHAL OF EXCESSIVE AIR
CONTAMINANTS. APPROPRIATE RESP SELECTION DEPENDS ON TYPE & MAGNITUDE OF E
XPOS (REFER TO 29 CFR 1910.134 FOR APPROPRIATE NIOSH APPROVED RESP &
NIOSH POCKET GUIDE TO CHEM HAZ, DHHS (NIOSH) PUBLICATION NO. 90117 FOR
EQUIPMENT SELECTION.
Ventilation: LOCAL EXHAUST VENT SHOULD BE USED TO CONTROL EMISSIONS OF AIR
CONTAMINANTS. GENERAL DILUTION VENT MAY ASSIST W/REDUCT OF AIR CONTAMINANT
CONCENTRATIONS.
Protective Gloves: POLYVINYL ALCOHOL AND POLYRTHYLENE GLOVES.
Eye Protection: ANSI APPROVED CHEMICAL SAFETY GOGGLES (FP N)
Other Protective Equipment: EMERGENCY EYE WASH STATIONS AND SAFETY SHOWERS
SHOULD BE AVAILABLE IN THE WORK AREA. PHYS/CHEM PROPERTIES (CONT):
OCTANOL/WATER PARTITION COEFF: N/A. WATER/OIL DIST COEFF: N/A. ODOR
THRESHOLD: N/A.
Work Hygienic Practices: WEAR PROTESTIVE CLOTHING AND GLOVES TO PREVENT CONTACT
WITH SKIN. CONTAMINATED CLOTHING AND GLOVES SHOULD BE REMOVED AND LAUNDERED
BEFORE RESUSE. POLYVINYL ALCOHOL AND (SUPPLEMENTAL SAFETY AND HEALTH)
Supplemental Safety and Health: SYNONYMS: UNSATURATED POLYESTER POLYOL. CHEM
NAME: POLYESTER. DIVISION: ACRYLICS. WORK HYGENIC PRACTICES (CONT):
POLYETHYLENE PROTECTIVE GARMENTS HAVE BEEN RECOMMENDED FOR PROTECTION AGAINST
MATERIALS OF THIS CHEMICAL CLASS. PHYS/CHEM PROPERTIES (CONT): MOL/CHEM
FORMULA: MIXTURE. REACTIVITY IN WATER: N/A.
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Physical/Chemical Properties
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Boiling Point: =145.C, 293.F
B.P. Text: (STYRENE)
Vapor Pres: 4.5 MM HG. (STYRENE).
Vapor Density: 3.6 STYREN
Spec Gravity: 1.10 (WATER=1).
Solubility in Water: NEGLIGIBLE.
Appearance and Odor: STRAW COLORED VISCOUS LIQUID. STYRENE ODOR.
Percent Volatiles by Volume: ~60
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: EXPOSURE TO EXCESSIVE HEAT OR OPEN FLAME; STORAGE
IN OPEN CONTAINERS; PROLONGED STORAGE (6 MONTHS).
Materials To Avoid: STRONG ACIDS, PEROXIDES AND OTHER OXIDIZING AGENTS.
REACTIVITY IN WATER: N/A.
Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE, LOW
MOLECULAR WEIGHT HYDROCARBONS AND ORGANIC ACIDS.
Hazardous Polymerization Indicator: YES
Conditions To Avoid Polymerization: MAY OCCUR. EXPOSURE TO HEAT, OPEN FLAME
OR CONTAMINATION WITH OXIDIZING AGENTS, AVOID STORAGE ABOVE 38C (100F).
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Toxicological Information
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Toxicological Information: STYRENE: ORAL LD50 (RAT) = 5000 MG/K. UNSATURATED
POLYESTER RESIN (DATA FOR SIMILAR RESIN): ORAL LD50 (RAT) >2000 MG/KG.
SEVERAL EMBRYOTOXIC EFFECTS HAVE BEEN SHOWN IN STYRENE STUDIES; HOWEVER, WITH
CONFLICTING RESULTS. EMBRYOTOXIC DATA ON HUMANS ARE INCONCLUSIVE (WHO ENVIR.
HEALTH CRITERIA 26:82, 1983). CHROMOSOMAL ABERRATIONS IN CULTURED PERIPHERAL
LYMPHOCYTES OCCURING IN WORKERS AT HIGH CONCEN TRATIONS HAVE BEEN REPORTED
WITH STYRENE EXPOSURE. NO CHANGES OCCURRED IN WORKERS AT LOW LEVEL
CONCENTRATIONS (IARC SUP. 4:229, 1982). THERE IS INSUFFICIENT EVIDENCE TO
ESTABLISH A RELATIONSHIP WITH CANCER AND STYRENE, (ECOLOGICAL INFO)
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Ecological Information
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Ecological: NO ECOLOGICAL DATA ARE CURRENTLY AVAILABLE. TOXICOLOGICAL
INFO (CONT): ALTHOUGH SEVERAL STUDIES HAVE IMPLIED AN ASSOCIATED RISK OF
LEUKEMIA AND LYMPHOMA (WHO ENVIR. HEALTH CRITERIA 26:82, 1983). STYRENE MAY
CAUSE CHANGES IN URINARY ENZYMES: SPECIFICALLY, A DECREASE IN CREATININE AND
AN INCREASED BLOOD UREA NITROGEN (BUN AND SGPT) (TOX. APPL. PHARM. 75:346,
1984). WORKERS EXPOSED TO CONCENT RATIONS OF STYRENE FROM 20 PPM TO 150 PPM
FOR 5 YEARS AT POLYSTYRENE MANUFACTURING FACILITIES DEVELOPED LIVER DAMAGE.
EYE CONTACT STUDIES WITH POLYESTER RESIN USING RABBITS RESULTED IN MODERATE
CORNE AL INJURY, IRITIS AND (TRANSPORT INFO)
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MSDS Transport Information
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Transport Information: U.S. DOT: PROPER SHIPPING NAME: RESIN SOLUTION. HAZARD
CLASS: 3. ID NUMBER UN1866. PACKING GROUP: III. ADDITIONAL INFORMATION IF
APPLICABLE: MARINE POLLUTANT (STYRENE MONOMER, INHIBITED). SEE (SPILL
RELEASE PROCEDURES) SECTION FOR REPORTABLE QTY (RQ) INFORMATION.
ECOLOGICAL INFO (CONT): CONJUNCTIVAL INJURY WITH CORNEAL VASCULARIZATION.
HOWEVER, ALL EYES HEALED BY DAY 21 (USS TOXICITY TEST REPORT NO. 47-503).
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Regulatory Information
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Sara Title III Information: SARA HAZARDS. ACUTE: Y. CHRONIC: Y. REACTIVITY: Y.
FIRE: Y. PRESSURE: N. SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA
313): STYRENE. SARA SECTION 110 PRIORITY LIST OF CERCLA HAZARDOUS SUBSTANC
ES: STYRENE. SIGNS AND SYMPTOMS OF OVEREXPOSURE (CONT): CHRONIC
OVEREXPOSURE: PROLONGED OR REPEATED SKIN CONTACT MAY LEAD TO ALLERGIC SKIN
REACTIONS. MAY CAUSE CANCER BASED ON ANIMAL STUDIES. P OTENTIAL HEALTH
EFFECTS: EYES: MAY CAUSE EYE IRRITATION. SKIN: MAY CAUSE IRRITATION,
DERMATITIS, ECZEMA OR SKIN SENSITIZATION. INGESTION: MAY CAUSE IRRITATION TO
THE GASTROINTESTINAL TRACT, VOMITING, DIARRHEA & STOMACH PAINS. (FEDERAL
REGS)
Federal Regulatory Information: TOXIC SUBSTANCES CONTROL ACT (TSCA) INVENTORY:
YES. CLEAN AIR ACT (SECTION 111) VOLATILE ORGANIC COMPOUND: STYRENE. CLEAN
AIR ACT (SECTION 112) STATUTORY AIR POLLUTANTS: STYRENE. CLEAN WATER ACT
(SECT ION 311) HAZARDOUS SUBSTANCES: STYRENE. INTERNATIONAL REGULATIONS:
CANADIAN INVENTORY (DSL): YES. SARA III (CONT): POSSIBLE ASPIRATION
HAZARD. INHALATION: MAY CAUSE UPPER RESPIRATORY TRACT IRRITA TION WITH
POSSIBLE CENTRAL NERVOUS SYSTEM EFFECTS.
State Regulatory Information: PENNSYLVANIA HAZARDOUS SUBSTANCES LIST:
STYRENE-(E). NEW JERSEY HAZARDOUS SUBSTANCE LIST: STYRENE (F3, MU, R2).
MASSACHUSETTS SUBSTANCE LIST: STYRENE (C,E). LABEL STATEMENTS:
WARNING! FLAMMABLE LIQUID AND VAPOR. MAY CAUSE IRRITATIONTO THE EYES, SKIN
AND RESPIRATORY TRACT. MAY BE HARMFUL IF SWALLOWED OR ABSORBED THROUGH SKIN.
POSSIBLE ASPIRATION HAZARD. MAY CAUSE SKIN SENSITIZATION. MAY CAUS E CENTRAL
NERVOUS SYSTEM EFFECTS. MAY CAUSE LIVER EFFECTS. AVOID CONTACT WITH EYES,
SKIN AND CLOTHIN G. AVOID BREATHING VAPOR. WASH THOROUGHLY AFTER HANDLING.
USE ONLY WITH ADEQUATE VENTILATION. (CONTACT NEHC FOR ADDITIONAL INFO - FP N)
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Other Information
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Other Information: NFPA: HEALTH: 2, FLAMMABILITY: 3, REACTIVITY: 1. CODES:
HEALTH: 2, REACTIVITY: 1, FLAMMABILITY: 3. (SEE STATE REGS FOR LABEL
STATEMENTS - FP N). MSDS ISSUE DATE: 7/18/95. EXP OF CARCINOGEN (C ONT):
THE PREVIOUS DEFINITION ONLY CLASSIFIED A SUBSTANCE AS GROUP 2B IF SUFFICIENT
CARCINOGENIC EVIDENCE EXISTED IN ANIMAL STUDIES. THE CURRENT DEFINITION
ACCEPTS LTD EVIDENCE FROM ANIMAL STUDIES IF IT IS COUPLED W/ SUPPORTING
EVIDENCE FROM OTHER RELEVANT STUDIES. INDUSTRY GROUPS AND INDEPENDENT
RESEARCH ORGANIZATIONS ARE CONTESTING THE RECLASSIFICATION DUE TO THE CURRENT
INCONCLUSIVE SCIENTIFIC EVIDENCE LINKING STYRENE WITH CANCER.
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HAZCOM Label
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MSDS NAME: LB 1132-21
Assigned IND: Y
Company: ARISTECH ACRYLICS LLC
Street: 7350 EMPIRE DRIVE
City: FLORENCE, KY
Zipcode: 41042
Health Emergency Phone: (412) 571-5888
Label Required IND: Y
Date Of Label Review: 01/04/2001
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE LIQUID AND VAPOR. ACUTE: MAY CAUSE
IRRITATION TO THE EYES, SKIN AND RESPIRATORY TRACT. MAY BE HARMFUL IF
SWALLOWED OR ABSORBED THROUGH THE SKIN. POSSIBLE ASPIRATION HAZARD. SEVERE
INHALATIO N MAY CAUSE CNS AND LIVER EFFECTS INCLUDING BURNING SENSATION OF
EYES AND NOSE, COUGHING, RUNNY NOSE, SNEEZING AND SORE THROAT. CHRONIC:
CANCER HAZARD. STYRENE IS LISTED AS A LIVER CARCINOGEN. MAY CA USE SKIN
SENSITIZATION. PROLONGED OR REPEATED SKIN CONTACT MAY LEAD TO ALLERGICSKIN
REACTIONS.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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