ITW DEVCON -- PLASTIC STEEL PUTTY (A) RESIN, 0100
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Material Safety Data Sheet
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MSDS Num: CKXCT
MSDS NAME: PLASTIC STEEL PUTTY (A) RESIN, 0100
Responsible Party
Name: ITW DEVCON
Address: 30 ENDICOTT ST.
City: DANVERS MA 01923
Info Phone: (978) 777-1100
Emergency Phone Number: (800) 424-9300
Chemtrec IND/Phone: (800)424-9300
Review Ind: Y
Published: Y
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Contractor Summary
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Name: ITW DEVCON
Address: 30 ENDICOTT ST.
City: DANVERS MA 01923
Phone: (978) 777-1100
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Ingredients
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Cas: 25068-38-6
RTECS #: CE6880000
Name: BISPHENOL A DIGLYCIDYL ETHER RESIN. (DGEBPA)
% low Wt: 20.
% high Wt: 30.
Other REC Limits: N/E
OSHA PEL: N/E
ACGIH TLV: N/E
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Health Hazards Data
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Route Of Entry Inds - Inhalation: NO
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: CAUTION: EYE AND SKIN IRRITANT (EVIDENCED BY ITCHING
REDNESS). POTENTIAL SKIN SENSITIZER. AVOID CONTACT WITH EYES. AVOID PROLONGED
OR REPEATED SKIN CONTACT. DO NOT TAKE INTERNALLY. WASH THOROUGHLY AFT ER
HANDLING.
Explanation Of Carcinogenicity: CANCER-SUSPECT CONSTITUENT(S): NONE.
Signs And Symptions Of Overexposure: ACUTE OVEREXPOSURE: SKIN: MODERATE
IRRITANT. CONTACT AT ELEVATED TEMPERATURES CAN CAUSE THERMAL BURNS. MAY CAUSE
SKIN SENSITIZATION (RASHES, HIVES). EYES: MODERATE IRRITANT. CONTACT AT
ELEVATED TEMPER ATURES CAN CAUSE THERMAL BURNS. INHALATION: THE LOW VAPOR
PRESSURE OF THE RESIN MAKES INHALATION UNLIKELY IN NORMAL USE. INGESTION:
ACUTE ORAL TOXICITY IS LOW. MAY CAUSE GASTRIC DISTRESS. CHRONIC OVE
REXPOSURE: PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE SENSITIZATION, WITH
ITCHING, SWELLING, OR RASHES ON LATER EXPOSURE.
Medical Cond Aggravated By Exposure: PREEXISTING EYE AND SKIN DISORDERS.
DEVELOPMENT OF PREEXISTING SKIN OR LUNG ALLERGY SYMPTOMS MAY INCREASE.
First Aid: EYES: FLUSH EYE WITH CLEAN WATER FOR AT LEAST 15 MINUTES WHILE
GENTLY HOLDING EYELIDS OPEN. GET IMMEDIATE MEDICAL ATTENTION. SKIN:
IMMEDIATELY REMOVE CONTAMINATED CLOTHING AND EXCESS CONTAMINANT. FLUS H SKIN
WITH WATER. WASH THOROUGHLY WITH SOAP AND WARM WATER. CONSULT A PHYSICIAN IF
IRRITATION DEVELOPS. INHALATION: REMOVE PATIENT TO FRESH AIR. ADMINISTER
OXYGEN IF BREATHING IS DIFFICULT. GET MEDIC AL ATTENTION IF SYMPTOMS PERSIST.
INGESTION: DO NOT INDUCE VOMITING. GIVE TWO GLASSES OF WATER TO DILUTE, IF
PATIENT IS CONSCIOUS. GET MEDICAL ATTENTION. NOTE TO PHYSICIAN: IN GENERAL,
EMESIS INDUCTIO N IS UNNECESSARY IN HIGH (NEUT AGENT)
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Handling and Disposal
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Spill Release Procedures: AVOID PERSONAL CONTACT. ELIMINATE IGNITION SOURCES.
VENT AREA. DIKE, CONTAIN & ABSORB WITH CLAY, SAND, OTHER SUITABLE
MATERIAL. LARGE SPILL: PUMP TO STORAGE/SALVAGE VESSELS. SOAK UP RESIDUE WITH
ABSOR BENT SUCH AS CLAY, SAND, OTHER SUITABLE MATERIAL & DISPOSE OF
PROPERLY. FLUSH AREA WITH WATER TO REMOVE TRACE RESIDUE. PREVENT SPILL FROM
ENTERING DRAINAGE/SEWER SYSTEM, WATERWAYS, & SURFACE WATERS.
Neutralizing Agent: N/P. FIRST AID (CONT'D): VISCOSITY, LOW VOLATILITY
PRODUCTS, E.G., NEAT EPOXY RESINS.
Waste Disposal Methods: IF THIS RESIN BECOMES A WASTE, IT WOULD NOT BE A
HAZARDOUS WASTE BY RCRA CRITERIA (40 CFR 261). DISPOSE OF ACCORDING TO
APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS.
Handling And Storage Precautions: HANDLING: AVOID CONTACT WITH SKIN, EYES, OR
CLOTHING. HANDLE MIXED RESIN AND HARDENER IN ACCORDANCE WITH THE POTENTIAL
HAZARD OF THE CURING AGENT USED. PROVIDE APPROPRIATE VENTILATION AND
RESPIRATORY PROTECTION AGAINST DECOMPOSITION PRODUCTS DURING WELDING/FLAME
CUTTING OPERATIONS AND (OTHER PREC)
Other Precautions: HANDLING/STORAGE (CONT'D): TO PROTECTAGAINST NUISANCE DUST
DURING SANDING/GRINDING OF CURED PRODUCT. STORAGE: STORE IN A COOL, DRY AREA
AWAY FROM HIGH TEMPERATURES AND FLAMES.
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Fire and Explosion Hazard Information
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Flash Point Method: PMCC
Flash Point: >204.4C, 400.F
Lower Limits: N/D
Upper Limits: N/D
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures: MATERIAL WILL NOT BURN UNLESS PREHEATED. DO NOT ENTER
CONFINED SPACE WITHOUT FULL BUNKER GEAR. FIREFIGHTERS SHOULD WEAR NIOSH
APPROVED SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
COOL FIRE EXPOSED CONTAINERS WITH WATER.
Unusual Fire/Explosion Hazard: HEATING ABOVE 300 DEG F IN PRESENCE OF AIR MAY
CAUSE SLOW OXIDATIVE DECOMPOSITION AND ABOVE 500 DEG F MAY CAUSE
POLYMERIZATION. HAZARD PRODUCTS OF COMBUSTION: WHEN HEATED TO DECOMPOSITION
IT EMITS FUM ES OF CI-,CARBON MONOXIDE, OTHER FUMES AND VAPORS VARYING IN
COMPOSITION AND TOXICITY.
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Control Measures
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Respiratory Protection: NONE REQUIRED AT NORMAL HANDLING TEMPERATURES AND
CONDITIONS. USE NIOSH APPROVED ORGANIC VAPOR CARTIDGES FOR UNCURED RESIN AND
DUST/PARTICLE RESPIRATORS DURING GRINDING/SANDING OPERATIONS OF CURED RES INS
AS EXPOSURE LEVELS DICTATE.
Ventilation: LOCAL EXHAUST VENTILATION IS PREFERRED ALTHOUGH GOOD MECHANICAL
VENTILATION IS USUALLY ADEQUATE FOR MOST INDUSTRIAL APPLICATIONS. LOCAL
EXHAUST IS (SUPP SFTY)
Protective Gloves: CHEMICAL-RESISTANT GLOVES.
Eye Protection: ANSI APPROVED SAFETY GLASSES WITH SIDE SHIELDS.
Other Protective Equipment: EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA (FP N). OTHER PROTECTIVE GEAR AS REQUIRED TO PREVENT SKIN CONTACT.
Work Hygienic Practices: WASH THOROUGHLY WITH SOAP AND WATER AFTER USING
PRODUCT AND PARTIULARLY BEFORE EATING, DRINKING, SMOKING, APPLYING COSMETICS,
OR USING TOILET FACILITIES . LAUNDER CONTAMINATED CLOTHING AND (SUPP SFTY)
Supplemental Safety and Health: PHYSICAL/CHEMICAL PROPERTIES (CONT'D): PERCENT
SOLID BY WEIGHT: 100. PH (5% SOLUTION OR SLURRY IN WATER): NEUTRAL. HYGIENE
PRACTICE (CONT'D): PROTECTIVE GEAR BEFORE RE-USE. DISCARD CONTAMINATED LEATHE
R ARTICLES. VENTILATION (CONT'D ): RECOMMENDED FOR CONFINED AREAS.
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Physical/Chemical Properties
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Boiling Point: >260.C, 500.F
M.P/F.P Text: N/D
Vapor Pres: 0.03 MM HG AT 171 F
Vapor Density: >1
Spec Gravity: 2.8
PH: NEUTRAL
Solubility in Water: NEGLIGIBLE.
Appearance and Odor: DARK GRAY PASTE WITH LITTLE ODOR.
Percent Volatiles by Volume: 0
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: THIS MATERIAL IS CHEMICALLY STABLE. OPEN FLAME
AND EXTREME HEAT.
Materials To Avoid: STRONG LEWIS OR MINERAL ACIDS, STRONG OXIDIZING AGENTS,
STRONG MINERAL AND ORGANIC BASES (ESPECIALLY PRIMARY AND SECONDARY ALIPHATIC
AMINES).
Hazardous Decomposition Products: OXIDES OF CARBON; ALDEHYDES, ACIDS AND OTHER
ORGANIC SUBSTANCES MAY BE FORMED DURING COMBUSTION OR ELEVATED TEMPERATURE
(>500 DEG F) DEGRADATION.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: HEAT IS GENERATED WHEN RESIN IS MIXED WITH
CURING AGENTS; RUN-AWAY CURE REACTIONS MAY CHAR AND DECOMPOSE (OTHER
INFORMATION)
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Toxicological Information
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Toxicological Information: ACUTE ORAL EFFECTS: LD50 (RAT): NOT AVAILABLE.
ACUTE DERMAL EFFECTS: LD50 (RABBIT): NOT AVAILABLE. ACUTE INHALATION EFFECTS
LC50 (RAT): NOT AVAILABLE. EYE IRRITATION: NOT AVAILABLE. SUBCHRONIC EFFEC
TS: NO DATA AVAILABLE. CARCINOGENCITY, TERATOGENICITY, AND MUTAGENICITY: BOTH
THE RESIN AND THE DIGLYCIDYL ETHER OF BISPHENOL A (A COMPONENT OF THIS
PRODUCT) HAVE PROVED TO BE INACTIVE WHEN TESTED BY IN VIVO MUTAGENICITY
ASSAYS. BOTH HAVE SHOWN ACTIVITY BY IN VITRO MICROBIAL MUTAGENICITY SCREENING
AND HAVE PRODUCED CHROMOSOMAL ABERRATIONS IN CULTURED RAT LIVER CELLS. OTHER
CHRONIC EFFECTS: 2-YEAR BIOASSAYS IN MICE (ECOLOGICAL).
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Ecological Information
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Ecological: ECOTOXICITY, MOBILITY AND PERSISTENCE,AND ENVIRONMENTAL FATE: NO
DATA AVAILABLE. (TOX, CONT'D) EXPOSED BY THE DERMAL ROUTE TO EPON 828,
DGEBPA, OR OTHER COMMERCIAL RESINS YIELDED LIMITED EVIDENCE OF WEAK
CARCINOGENICITY. THE AUTHORS CONCLUDED THAT THE RENAL TUMOR EVIDENCE WITH
EPON 828 "WAS OF NO BIOLOGICAL SIGNIFICANCE" AND THAT THE RESIN "IS NOT A
SYSTEMIC CARCINOGEN WHEN APPLIED TO THE DORS AL SKIN OF CF1 MICE."
TOXICOLOGICAL INFORMATION ON HAZARDOUS CHEMICAL COMPONENTS OF THIS PRODUCT:
BISPHENOL A DIGLYCIDYL ETHER RESIN: ORAL LD50 (RAT): 30 G/KG, DERMAL LD50
(RABBIT): >20 M./KG, INHALA TION LC50 4 HR (RAT): NO DEATHS.
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MSDS Transport Information
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Transport Information: PROPER SHIPPING NAME: NON-REGULATED. TECHNICAL NAME,
HAZARD CLASS, UN NUMBER, PACKING GROUP, EMERGENCY RESPONSE GUIDE NO., AND
IMDG PAGE NUMBER: N/A.
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Regulatory Information
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Sara Title III Information: FOR PURPOSES OF SARA SECTION 312 HAZARDOUS MATERIAL
INVENTORY REPORTING, THE FOLLOWING HAZARD CLASSES APPLY TO THIS MATERIAL:
IMMEDIATE HEALTH HAZARD. DELAYED HEALTH HAZARD.
Federal Regulatory Information: TSCA: ALL INGREDIENTS OF THIS PRODUCT ARE
LISTED, OR ARE EXEMPT FROM LISTING ON THE TSCA INVENTORY. EXPORT NOTIFICATION
IS REQUIRED UNDER TSCA SEC. 12B. THE FOLLOWING RCRA CODE(S) APPLY TO THIS
MATERI AL IF IT BECOMES WASTE: NONE. REGULATORY STATUS OF HAZARDOUS CHEMICAL
COMPONENTS OF THIS PRODUCT: BISPHENOL A DIGLYCIDYL ETHER RESIN:
EXTREMELYHAZARDOUS: NO. TOXIC CHEMICAL: NO. CERCLA RQ (LBS): 0.0. TSCA 12B
EXPORT NOTIFICATION: REQUIRED. CANADIAN REGULATIONS: W HAZARD CLASS: D2B. ALL
COMPONENT S OF THIS PRODUCT ARE ON THE DOMESTIC SUBSTANCES LIST.
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Other Information
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Other Information:: HEALTH -2, FLAMMABILITY -1, REACTIVITY -1. PRODUCT
IDENTIFIER: EPOXY RESIN. GENERAL USE: THIS INFORMATION APPLIES TO THE RESIN
COMPONENT OF THE TWO-PART KIT; HANDLE FRESHLY-MIXED RESIN AND HARDE NER AS
RECOMMENDED FOR THE HARDENER. AFTER CURING, THE PRODUCT IS NOT HAZARDOUS.
CHEMICAL FAMILY: METAL FILLED EPOXY RESIN. THIS PRODUCT APPEARS IN THE
FOLLOWING STOCK NUMBERS: 10110, 10110G, 10120, A ND 10130. CONDITIONS TO
AVOID POLYMERIZATION (CONT'D): RESIN, GENERATING UNIDENTIFIED FUMES AND
VAPORS WHICH MAY BE TOXIC.
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HAZCOM Label
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MSDS NAME: PLASTIC STEEL PUTTY (A) RESIN, 0100
Assigned IND: Y
Company: ITW DEVCON
Street: 30 ENDICOTT ST.
City: DANVERS MA
Zipcode: 01923
Health Emergency Phone: (800) 424-9300
Label Required IND: Y
Date Of Label Review: 11/01/2000
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Slight
Reactivity Hazard: Slight
Hazard And Precautions: CAUTION: EYE & SKIN IRRIT (EVIDENCED BY ITCHING
REDNESS). POTENTIAL SKIN SENSITIZER. AVOID CONTACT W/EYES. AVOID
PROLONGED/REPEATED SKIN CONTACT. DO NOT TAKE INTERNALLY. WASH THOROUGHLY
AFTER HANDLING . ACUTE OVEREXPOS: SKIN: MODERATE IRRIT. CONTACT AT ELEVATED
TEMPS CAN CAUSE THERMAL BURNS. MAY CAUSE SKIN SENSITIZATION (RASHES, HIVES).
EYES: MODERATE IRRIT. INHAL: THE LOW VAPOR PRESSURE OF THE R ESIN MAKES
INHAL UNLIKELY IN NORMAL USE. INGEST: ACUTE ORAL TOX IS LOW. MAY CAUSE
GASTRIC DISTRESS. CHRONIC OVEREXPOS: PROLONGED/REPEATED SKIN CONTACT MAY
CAUSE SENSITIZATION, W/ITCHING, SWELLING, OR RASHES ON LATER EXPOS.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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