===================== Product Identification =====================
MSDS NAME:D4794 1,2-DICHLOROETHANE HPLC GRADE
NIIN:00F039687
MSDS Number: BWXLG
=== Responsible Party ===
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:SAINT LOUIS
State:MO
ZIP:63178-5000
Country:US
Info Phone Num:314-771-5765/800-325-3010
Emergency Phone Num:314-771-5765/800-325-3010
CAGE:21076
=== Contractor Identification ===
Company:ALDRICH CHEMICAL CO INC
Address:1001 WEST ST PAUL AVE
Box:355
City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:60928
Company:FLUKA CHEMICAL CORP
Address:1001 WEST ST PAUL
Box:City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:63181
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Phone:314-771-5765
CAGE:21076
============= Composition/Information on Ingredients =============
Name:1,2-DICHLOROETHANE, ETHYLENE DICHLORIDE (SUSPECTED ANIMAL
CARCINOGEN BY IARC, SUSPECTED CARC BY NTP - GROUP 2B) *95-1*
CAS:107-06-2
RTECS #:KI0525000
Other REC Limits:40 MG/CUM
ACGIH TLV:10 PPM
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT): 670 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF INGESTED, INHALED/ABSORBED
THROUGH SKIN. MAY CAUSE EYE/SKIN/MUCOUS MEMBRANE & UPPER
RESPIRATORY TRACT IRRITATION, CNS DEPRESSION, DERMATITIS, LIVER &
KIDNEY DAMAGE. MAY ALTER GENETIC MATERI AL.
Explanation of Carcinogenicity:SEE INGREDIENTS
Effects of Overexposure:IRRITATION, NAUSEA, HEADACHE, VOMITING, GI
DISTURBANCES.
======================= First Aid Measures =======================
First Aid:EYES/SKIN: IMMEDIATELY FLUSH W/COPIOUS AMOUNTS OF WATER FOR
15 MINS. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF
NEEDED. INGESTION: RINSE MOUTH OUT W/WATER IF CONSCIOUS. OBTAIN
MEDICAL ATTENTI ON IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:60F
Lower Limits:6.2
Upper Limits:15.6
Extinguishing Media:CO2, DRY CHEMICAL POWDER, APPROPRIATE FOAM.
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING. WATER MAY BE EFFECTIVE FOR COOLING, BUT MAY
NOT EFFECT EXTINGUISHMENT.
Unusual Fire/Explosion Hazard:FLAMMABLE LIQUID. VAPOR MAY TRAVEL TO
DISTANT IGNITION SOURCE & FLASH BACK. AUTOIGNITION TEMP: 775F.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA & SHUT OFF ALL IGNITION SOURCES.
WEAR SCBA, RUBBER BOOTS & HEAVY RUBBER GLOVES. ABSORB ON
SAND/VERMICULITE & PLACE IN CLOSED CONTAINERS FOR DISPOSAL.
VENTILATE AREA & WASH SITE AFTER MAT ERIAL PICKUP IS COMPLETE.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE UNDER NITROGEN. KEEP TIGHTLY
CLOSED & AWAY FROM HEAT, SPARKS & OPEN FLAME.
Other Precautions:DON'T BREATHE VAPOR, GET IN EYES/ON SKIN/CLOTHING.
AVOID PROLONGED/REPEATED EXPOSURE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR A NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL RESISTANT
Eye Protection:SAFETY GOGGLES
Other Protective Equipment:PROTECTIVE CLOTHING
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES
BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:181.4F
Melt/Freeze Pt:M.P/F.P Text:-31F
Vapor Pres:87
Vapor Density:3.4
Spec Gravity:1.256
Appearance and Odor:COLORLESS LIQUID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, ALUMINUM.
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME & OTHER IGNITION
SOURCES.
Hazardous Decomposition Products:CO, CO2, HYDROGEN CHLORIDE GAS,
PHOSGENE GAS.
==================== Disposal Considerations ====================
Waste Disposal Methods:BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AN
AFTERBURNER & SCRUBBER IAW/FEDERAL, STATE & LOCAL REGULATIONS.
EXERT EXTRA CARE IN IGNITING AS THIS MATERIAL IS HIGHLY FLAMMABLE.
UN1184
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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