===================== Product Identification =====================
MSDS NAME:Z8000 AMMONIUM BIFLUORIDE
NIIN:00F039681
MSDS Number: BWXKY
=== Responsible Party ===
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:SAINT LOUIS
State:MO
ZIP:63178-5000
Country:US
Info Phone Num:314-771-5765/800-325-3010
Emergency Phone Num:314-771-5765/800-325-3010
CAGE:21076
=== Contractor Identification ===
Company:ALDRICH CHEMICAL CO INC
Address:1001 WEST ST PAUL AVE
Box:355
City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:60928
Company:FLUKA CHEMICAL CORP
Address:1001 WEST ST PAUL
Box:City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:63181
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Phone:314-771-5765
CAGE:21076
============= Composition/Information on Ingredients =============
Name:AMMONIUM BIFLUORIDE
CAS:1341-49-7
RTECS #:BQ9200000
OSHA PEL:2.5 MG/CUM
ACGIH TLV:2.5 MG/CUM
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF INGESTED, INHALED/ABSORBED
THROUGH SKIN. MATERIAL IS EXTREMELY DESTRUCTIVE TO TISSUE OF MUCOUS
MEMBRANES & UPPER RESPIRATORY TRACT, EYES & SKIN. INHALATION MAY BE
FATAL AS A RESULT OF SPASM , INFLAMMATION & EDEMA OF LARYNX &
BRONCHI, CHEMICAL PNEUMONITIS & PULMONARY EDEMA.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:BURNING SENSATION, COUGHING, WHEEZING,
LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA, VOMITING.
======================= First Aid Measures =======================
First Aid:EYES/SKIN: IMMEDIATELY FLUSH W/COPIOUS AMOUNTS OF WATER FOR
15 MINS. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF
NEEDED. INGESTION: WASH MOUTH OUT W/WATER IF CONSCIOUS. OBTAIN
MEDICAL ATTENTI ON IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY CHEMICAL POWDER, WATER SPRAY.
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR SELF CONTAINED BREATHING APPARATUS.
EVACUATE AREA. SWEEP UP, PLACE IN A BAG & HOLD FOR WASTE DISPOSAL.
VENTILATE AREA & WASH SITE AFTER MATERIAL PICKUP IS COMPLETE.
Neutralizing Agent:SODIUM CARBONATE
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL DRY PLACE. KEEP
TIGHTLY CLOSED. TOXIC, CORROSIVE & HYGROSCOPIC.
Other Precautions:AVOID INHALATION. DON'T GET IN EYES, ON
SKIN/CLOTHING.AVOID PROLONGED/REPEATED EXPOSURE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL RESISTANT
Eye Protection:SAFETY GOGGLES
Other Protective Equipment:PROTECTIVE CLOTHING
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES
BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
WASTE DISPOSAL CONT'D: ADD CALCIUM CHLORIDE IN EXCESS OF AMOUNT NEEDED
TO PRECIPITATE FLUROIDE &/CARBONATE. SEPARATE INSOLUBLE & BURY IN
AN APPROVED LANDFILL FOR HAZARDOUS WASTE DISPOSAL IAW/FEDERAL,
STATE & LOCAL REGULATIONS.
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:257F
Spec Gravity:1.5
Appearance and Odor:WHITE CRYSTALS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS, BASES, GLASS.
Stability Condition to Avoid:MOISTURE.
Hazardous Decomposition Products:AMMONIA, HYDROGEN FLUORIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:CAUTIOUSLY DISSOLVE MATERIAL IN WATER.
NEUTRALIZE IMMEDIATELY/FIRST ADD A LITTLE HYDROCHLORIC ACID
FOLLOWED BY SODIUM CARBONATE IF MATERIAL DOESN'T DISSOLVE
COMPLETELY. (SEE SUPP)
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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