===================== Product Identification =====================
MSDS NAME:GRAY, 11453 000196 406
NIIN:00N083590
MSDS Number: CGQZC
=== Responsible Party ===
Company:RAABE CORP
Address:N92 W14701 ANTHONY AVE
Box:1090
City:MENOMONEE FALLS
State:WI
ZIP:53052-1090
Country:US
Info Phone Num:414-255-9500
Emergency Phone Num:800-424-9300 (CHEMTREC)
CAGE:0A3L4
=== Contractor Identification ===
Company:RAABE CORPORATION THE PRECISION COLOR COMPANY
Address:N92 W14701 ANTHONY AVE.
Box:1090
City:MENOMONEE FALLS
State:WI
ZIP:53051-1630
Country:US
Phone:414-255-9500/800-966-7580
CAGE:0A3L4
============= Composition/Information on Ingredients =============
Name:BUTANE; (N-BUTANE) LEL: 1.80%
CAS:106-97-8
RTECS #:EJ4200000
Fraction by Wt: 8%
OSHA PEL:800 PPM
ACGIH TLV:800 PPM
Name:PROPANE; VP: 108 @ 68F; LEL: 2.20%
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 16%
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT
Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 4%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Name:ACETONE (SARA 313) (CERCLA) LEL: 2.60%
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 35%
OSHA PEL:1000 PPM
ACGIH TLV:750 PPM/1000 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:2-BUTANONE; (METHYL ETHYL KETONE) (SARA 313) (CERCLA) LEL:
1.80%
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 8%
OSHA PEL:200 PPM
ACGIH TLV:200 PPM/300 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER; (PROPYLENE
GLYCOL METHYL ETHER ACETATE) LEL: 1.30%
CAS:108-65-6
RTECS #:AI8925000
Fraction by Wt: 6%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:TOLUENE (SARA 313) (CERCLA) LEL: 1.40%
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 11%
OSHA PEL:200 PPM
ACGIH TLV:50 PPM, S
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:VOLATILE ORGANIC COMPOUND: 3.3460
RTECS #:9999999VO
OSHA PEL:N/K
ACGIH TLV:N/K
Name:EFTS OF OVEREXP: RPTS HAVE ASSOC RPTD & PRLNG OVEREXP TO
SOLVS W/PERM BRAIN & NERV SYS DMG. RPTD BRTHG/SKIN (ING 10)
RTECS #:9999999ZZ
Name:ING 9: CONT OF METHYL ETHYL KETONE MAY INCR POTENCY OF
NEUROTOXINS SUCH AS HEXANE IF EXPOS OCCUR AT SAME TIME. (ING 11)
RTECS #:9999999ZZ
Name:ING 10: RATS EXPOSED TO TITANIUM DIOXIDE DUST AT 250 MG/M3
DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOS LEVELS (ING 12)
RTECS #:9999999ZZ
Name:ING 11: ARE NOT ATTAINABLE IN WORKPLACE W/THIS MATL. PROD
CONTAINS TOLUENE WHICH MAY BE HARMFUL TO FETUS BASED (ING 13)
RTECS #:9999999ZZ
Name:ING 12: ON ANIMAL STUDIES. RPTD EXPOS TO TOLUENE HAS BEEN
ASSOC W/HIGH FREQUENCY HEARING LOSS IN LAB ANIMALS. (ING 14)
RTECS #:9999999ZZ
Name:ING 13: HUMAN CONSEQUENCES OF THIS FINDING IS UNCERTAIN.
TOLUENE APPEARS ON THE NAVY OCCUP CHEM REPRO HAZ LIST. (ING 15)
RTECS #:9999999ZZ
Name:ING 14: CONSULT APPROP HEALTH PROFESSIONALS CONCERNING
LATEST HAZARD LIST INFO & SAFE HANDLING & EXPOSURE INFO .
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: LIQ CONT MAY CAUSE SEV
CORNEAL INJURY. SKIN: MAY CAUSE IRRIT. RPTD & PRLNG CONT MAY CAUSE
ALLERGIC DERM. INHAL: HIGH CONCS OF VAPS MAY CAUSE DIZZ, BRTHG
DFCLTY, HDCH/RESP IRRIT. EXTREMELY HIGH CONCS MAY CAUSE DROW,
STAG, CONFUSION, UNCON, COMA/DEATH. INTENTIONAL MISUSE BY
DELIBERATELY (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: CONCENTRATING & INHALING CONTENTS CAN
BE HARMFUL/FATAL. INGEST: MOD TOX. MAY CAUSE STOM DISCOMFORT, NAUS,
VOMIT, DIARR, & NARCOSIS. CHRONIC: CHRONIC OVEREXP HAS CAUSED THE
FOLLOWING EFTS IN LAB ANIMALS: KIDNEY, EYE, LUNG, LIVER, SPLEEN, &
BRAIN DMG. HAS CAUSED LIVER DMG IN HUMANS. (ING 9)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
Eyes: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN. GET
MED ATTN IF IRRIT PERSISTS. SKIN: WASH THORO W/SOAP & WATER & SEEK
MED ATTN. REMOVE CONTAM CLTHG. LAUNDER CONTAM CLTHG BEFORE REUSE.
INHAL: MOVE TO FRESH AIR. IF BRTHG STOPS, APPLY ARTF RESP & SEEK
MED ATTN. INGEST: THE DECISION OF WHETHER TO INDUCE VOMIT/NOT MUST
BE MADE BY MD AFTER CAREFUL CONSIDERATION OF ALL MATLS INGESTED.
===================== Fire Fighting Measures =====================
Flash Point:<-25F,<-32C
Lower Limits:1.30%
Upper Limits:13.10%
Extinguishing Media:USE DRY CHEMICAL, CARBON DIOXIDE OR CHEMICAL FOAM.
Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY SHOULD NOT BE USED EXCEPT TO KEEP DOWN VAPS/COOL CLSD
CONTRS TO PVNT BUILD-UP OF PRESS. (SUP DAT)
Unusual Fire/Explosion Hazard:CONTENTS UNDER PRESS. DO NOT USE/STORE
NEAR SOURCES OF HEAT, SPKS/OPEN FLAME. KEEP AWAY FROM ANY SOURCE OF
HEAT SUCH AS SUNLIGHT, HEATERS/STOVES THAT (SUP DAT)
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. AVOID HEAT,
SPARKS, FLAMES AND ANYTHING WHICH COULD CAUSE FIRE. VENTILATE AREA
OF SPILL AND ADJACENT LOW LYING AREAS. AVOID BREATHING SOLVENT
VAPORS. REMOVE WITH INERT ABSORBENT MATERIALS AND NON-SPARKING
TOOLS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY AREA WITH
VENTILATION SUITABLE FOR STORING MATERIALS SHOWN IN INGREDIENTS
SECTION. KEEP AWAY FROM HEAT, SPARKS AND FLAME.
Other Precautions:STORE IN A COOL PLACE AWAY FROM DIRECT SUNLIGHT OR
ANY SOURCE OF IGNITION. DO NOT STORE AT TEMPERATURES ABOVE 120F.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF WORKPLACE EXPOSURE LIMITS ARE EXCEEDED FOR
ANY COMPONENT, A NIOSH APPROVED RESPIRATOR SUITABLE FOR COMPONENTS
LISTED IS RECOMMENDED.
Ventilation:SUFFICIENT VENT, IN VOL & PATTERN, SHOULD BE PROVIDED TO
KEEP AIR CONTAM BELOW CURRENT APPLIC OSHA PEL/ACGIH TLV.
Protective Gloves:CHEMICAL RESISTANT PLASTIC OR RUBBER.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH & DELUGE
SHOWER . IMPERVIOUS CLOTHING IS RECOMMENDED FOR PROLONGED/REPEATED
CONT.
Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING. WASH
HANDS BEFORE EATING OR SMOKING. SMOKE IN DESIGNATED AREAS ONLY.
Supplemental Safety and Health
% VOLAT:41.237(WT). FIRE FIGHT PROC:IF WATER USED, FOG NOZZ PREF. EXPLO
HAZ:COULD CAUSE CONTR TO BURST. DO NOT PUNCTURE/INCIN. DO NOT
CRUSH/PLACE IN GARBAGE COMPACTOR. DO NOT STORE >120F. AEROSOL CONT
RS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. PROD VAPS ARE HVR/AIR
& MAY TRAVEL LONG DIST TO IGNIT SOURCE & FLASH BACK.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>31F,>-1C
Vapor Pres:108.000
Spec Gravity:0.7680
Evaporation Rate & Reference:0.3900 (N-BU AC=1)
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER
Percent Volatiles by Volume:SUPDAT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID CONTACT WITH HEAT, SPARKS, AND OPEN
FLAME. PRODUCT MAY EXPLODE IF HEATED. KEEP COOL, AVOID EXPOSURE TO
HEAT.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE
CARBON DIOXIDE, CARBON MONOXIDE, AND UNIDENTIFIED ORGANIC
MATERIALS.
==================== Disposal Considerations ====================
Waste Disposal Methods:PLACE IN CLOSED CONTAINERS. DISPOSE OF PRODUCT
IN ACCORDANCE WITH LOCAL, COUNTY, STATE, AND FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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