===================== Product Identification =====================
MSDS NAME:TOLUENE,TECHNICAL
NIIN:00-290-0046
Status Code:A
MSDS Number: CJLTN
=== Responsible Party ===
Company:SOLVENTS AND CHEMICALS, INC.
Address:4704 SHANK ROAD
Box:490
City:PEARLAND
State:TX
ZIP:77581
Info Phone Num:713-485-5377
Emergency Phone Num:713-485-5377
Chemtrec Ind/Phone:(800)424-9300
CAGE:4W432
=== Contractor Identification ===
Company:SOLVENTS AND CHEMICALS, INC.
Address:4704 SHANK ROAD
Box:City:PEARLAND
State:TX
ZIP:77588-0490
Country:US
Phone:281-485-5377
Contract Num:SP0450-99-M-NG36
CAGE:4W432
============= Composition/Information on Ingredients =============
Name:TOLUENE
CAS:108-88-3
RTECS #:XS5250000
= Wt:100.
OSHA PEL:see Table Z-2
ACGIH TLV:188 MG/M3;50 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE & SKIN-PRIMARY IRRITATION
TO SKIN, DEFATTINGG, DERMATITIS. ABSORPTION THRU SKIN INCREASES
EXPOSURE. LIQUID CAN CAUSE EYE IRRITATION. WASH THOROUGHLU AFTER
HANDLING. INHALATION-IRRITATES RES PIRATORY TRACT. ACUTE
OVEREXPOSURE CAN CAUSE SERIOUS NERVOUS SYSTEM DEPRESSION. VAPOR
HARMFUL ACUTE OVEREXPOSURE CAN CAUSE DAMAGE TO KIDNEYS, BLOOD,
NERVES, LIVER & LUNGS. SWALLOWING-HARMFUL OR FATAL IF SWALLOWED.
CHRONIC: CHRONIC OVEREXPOSURE CAN CAUSE DAMAGE TO KIDNEYS, BLOOD,
NERVES, LIVER AND LUNGS.
Explanation of Carcinogenicity:THIS PRODUCT HAS NO CARCINOGENS LISTED
BY IARC, NTP, NIOSH, OSHA OR ACGIH, AS OF THIS DATE, GREATER OR
EQUAL TO 0.1%.
Effects of Overexposure:PRIMARY IRRITATION TO EYES, REDNESS, TEARING,
BLURRED VISION. SWALLOWING CAN CAUSE ABDOMINAL IRRITATION, NAUSEA,
VOMITING AND DIARRHEA.
Medical Cond Aggravated by Exposure:PERSONS WITH SEVERE SKIN, LIVER OR
KIDNEY PROBLEMS SHOULD AVOID USE.
======================= First Aid Measures =======================
First Aid:EYE-FLUSH WITH PLENTY OF WATER FOR 15 MIN & GET MEDICAL
ATTENTION. SKIN-IMMEDIATELY REMOVE CONTAMINATED CLOTHING. WASH
THOROUGHLY WITH SOAP & WATER. WASH CONTAMINATED CLOTHING BEFORE
REUSE. (DISCARD C ONTAMINATED SHOES). INHALATION-REMOVE FROM
EXPOSURE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF
BREATHING HAS STOPPED GIVE ARTIFICIAL RESPIRATION. CALL A PHYSICIAN
IMMEDIATELY! SWALLOWING -CALL A PHYSICIAN IMMEDIATELY. DO NOT
INDUCE VOMITING. HAVE PATIENT LIE DOWN & KEEP WARM. VOMITING MAY
LEAD TO PNEUMONITIS, WHICH MAY BE FATAL.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:=7.C, 44.6F
Autoignition Temp:=536.C, 996.8F
Lower Limits:1.4
Extinguishing Media:NFPA CLASS B EXTINGUISHERS(CARBON DIOXIDE OR
FOAM)FOR CLASS 1 B LIQUID FIRES
Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE ON FIRE BUT CAN
PROTECT FIRE-FIGHTERS & COOL CLOSED CONTAINERS.USE FOG NOZZLES IF
WATER IS USED. DO NOT ENTER CONFINED FIRESPACE WITHOUT FULL BUNKER
GEAR(HELMET WITH FAC E SHIELD,BUNKER COATS,GLOVES & RUBBER BOOTS).
USE NIOSH APPROVED POSITIVE PRESSURE SELF-CONTAINED BREATHING
APPARATUS.
Unusual Fire/Explosion Hazard:FLAMMABLE! KEEP CONTAINER TIGHTLY CLOSED.
ISOLATE FROM OXIDIZERS,HEAT,SPARKS,ELECTRIC EQUIPMENT & OPEN
FLAME.CLOSED CONTAINERS MAY EXPLODE IF EXPOSED TO EXTREME HEAT.
APPLYING TO HOT SURFACES REQUIRES SPECIAL PRECAUTIONSEMPTY
CONTAINER VERY HAZARDOUS! CONTINUE ALL LABEL PRECAUTIONS!
================== Accidental Release Measures ==================
Spill Release Procedures:STOP SPILL AT SOURCE. DIKE AREA AND CONTAIN.
CLEAN UP REMAINDER WITH ABSORBENT MATERIALS. MOP UP AND DISPOSE OF.
PERSONS WITHOUT PROPER PROTECTION SHOULD BE KEPT FROM AREA UNTIL
CLEANED UP.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE ABOVE 49C/120F. STORE
LARGE AMOUNTS IN STRUCTURES MADE FOR OSHA CLASS IB LIQUIDS. KEEP
CONTAINER TIGHTLY CLOSED AND UPRIGHT WHEN NOT IN USE TO PREVENT
LEAKAGE. ISOLATE FROM OXIDIZERS, HEA T, SPARKS, ELECTRIC EQUIPMENT
& OPEN FLAMES. USE ONLY WITH ADEQUATE VENTILATION.
Other Precautions:AVOID BREATHING OF VAPOR OR SPRAY MIST. AVOID
PROLONGED OR REPEATED CONTACT WITH SKIN. WEAR OSHA STANDRAD GOGGLES
OR FACE SHIELD. CONSULT SAFETY EQUIPMENT SUPPLIER. WEAR GLOVES,
SPRON & FOOTWARE IMPER VIOUS TO THIS MATERIAL. WASH CLOTHING BEFORE
RESUE. AVOID FREE FALL OF LIQUID. GROUND CONTAINERS WHE N
TRANSFERRING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:VENTILATE TO KEEP VAPORS OF THIS MATERIAL BELOW
25PPM. IF OVER TLV, IN ACCORDANCE WITH 29CFR1910.134,USE NIOSH
APPROVED POSITIVE-PRESSURE SELF-CONTAINED BREATHING
APPARATUS.CONSULT SAFETY EQUIPMENT SU PPLIER. USE EXPLOSION-PROOF
EQUIPMENT.
Ventilation:LOCAL EXHAUST: NECESSARY; MECHANICAL(GENERAL): ACCEPTABLE
Protective Gloves:WEAR GLOVES
Eye Protection:OSHA STANDARD GOGGLES OR FACE SHIELD
Other Protective Equipment:WEAR APRON AND FOOTWEAR IMPERVIOUS TO THIS
MATERIAL. WASH CLOTHING BEFORE REUSE.
Work Hygienic Practices:WASH CLOTHING BEFORE REUSE.
Supplemental Safety and Health
DO NOT FLAME FLAME, CUT, SAW, DRILL, BRAZE OR WELD. EMPTY CONTAINERS
VERY HAZARDOUS! CONTINUE ALL LABEL PRECAUTIONS!
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:=110.C, 230.F
B.P. Text:111-232
Vapor Pres:23.0
Vapor Density:3.2
Volatile Org Content %:100
Spec Gravity:.870
Solubility in Water:NEGLIGIBLE
Appearance and Odor:AROMATIC, LIQUID, WATER-WHITE
Percent Volatiles by Volume:100%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ISOLATE FROM STRONG OXIDIZERS SUCH AS PERMANGANATES,CHROMATES &
PEROXIDES.
Stability Condition to Avoid:ISOLATE FROM
OXIDIZERS,HEAT,SPARKS,ELECTRIC EQUIPMENT & OPEN FLAME.
Hazardous Decomposition Products:CARBON MONOXIDE,CARBON DIOXIDE FROM
BURNING.
=================== Toxicological Information ===================
Toxicological Information:TOLUENE: LOWEST KNOWN LD50 (ORAL) 3000 MG/KG,
RAT. LOWEST KNOWN LC50 (VAPOR) 5300 PPM, MICE. LOWEST KNOWN LD50
(SKIN) 4000 MG/KG, RABBIT. THRESHOLD LIMIT VALUE: 50 PPM (FRESHLY
PREPARED).
==================== Disposal Considerations ====================
Waste Disposal Methods:RECYCLE OR DISPOSE OF OBSERVING LOCAL, STATE,
AND FEDERAL HEALTH AND SAFETY POLLUTION LAWS. IF QUESTIONS EXIST,
CONTACT THE APPROPIATE AGENCIES.
=================== MSDS Transport Information ===================
Transport Information:DOT SHIPPING NAME: TOLUENE, 3, UN1294, PG-II.
===================== Regulatory Information =====================
SARA Title III Information:TOLUENE, 108-88-3, 100%, (311,312,313,RCRA),
RQ=1000 LBS. SECTION 311/312 HAZARDS: ACUTE HEALTH, FIRE.
Federal Regulatory Information:TOLUENE IS AN EPA HAZARDOUS AIR
POLLUTANT.
State Regulatory Information:CALIFORNIA PROPOSITION 65: THIS PRODUCT
CONTAINS THE FOLLOWING CHEMICALS KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE CANCER & REPRODUCTIVE TOXICITY: BENZENE, TOLUENE.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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