===================== Product Identification =====================
MSDS NAME:SALICYLIC ACID, 99+%, W513407
NIIN:00N092105
Status Code:A
MSDS Number: CJLXB
=== Responsible Party ===
Company:ALDRICH CHEMICAL CO INC
Address:1001 W ST PAUL
City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Info Phone Num:414-273-3850
Emergency Phone Num:414-273-3850
CAGE:60928
=== Contractor Identification ===
Company:ALDRICH CHEMICAL CO INC
Address:1001 WEST ST PAUL AVE
Box:355
City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:60928
============= Composition/Information on Ingredients =============
Name:SALICYLIC ACID
CAS:69-72-7
RTECS #:VO0525000
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL IF SWALLOWED, INHALED,
OR ABSORBED THROUGH SKIN. CAUSES EYE AND SKIN IRRITATION. MATERIAL
IS IRRITATING TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. MILD
CHRONIC SALICYLATE INTOXICA TION IS TERMED SALICYLISM. SYMPTOMS
INCLUDE: HEADACHE, DIZZINESS, RINGING IN THE EARS, DIFFICULTY IN
HEARING, DIMNESS OF VISION, MENTAL CONFUSION, LASSITUDE,
DROWSINESS, SWEATING, THIRST, HYPERVENTILA TION, NAUSEA, VOMITING,
& OCCASIONALLY DIARRHEA. A MORE SEVERE DEGREE OF SALICYLATE
INTOXICATION IS CHARACTERIZED BY MORE PRONOUNCED CNS DISTURBANCES
(INCLUDING GENERALIZED CONVULSION AND COMA), SKIN ERUPTIONS, AND
MARKED (EFTS OF OVEREXP)
Effects of Overexposure:HLTH HAZ: ALTERATIONS IN ACID-BASE BALANCE.
CHRONIC: MAY CAUSE CONGENITAL MALFORMATION IN THE FETUS. TARGET
ORGAN (S): CENTRAL NEROUS SYSTEM, BLOOD. TO THE BEST OF MFR'S
KNOWLEDGE, THE CHEMICAL, PHYSI CAL, AND TOXICOLOGICAL PROPERTIES
HAVE NOT BEEN THOROUGHLY INVESTIGATED.
======================= First Aid Measures =======================
First Aid:EYES OR SKIN: IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR
SKIN WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WIHLE
REMOVING CONTAMINATED CLOTHING AND SHOES. INHALATION: IF INHALED,
REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION.
IF BREATHING IS DIFFICULT, GIVE OXYGEN. INGESTION: WASH OUT MOUTH
WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN. WASH
CONTAMINATED CLOTHING BEFORE REUSING.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL POWDER OR
APPROPRIOATE FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. WEAR NIOSH APPROVED
SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY RUBBER
GLOVES. SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL. AVOID
RAISING DUST. VENTILATE AREA AN D WASH SPILL SITE AFTER MATERIAL
PICKUP IS COMPLETE.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT BREATHE DUST. DO NOT GET IN
EYES, ON SKIN, ON CLOTHING. KEEP TIGHTLY CLOSED. STORE IN A COOL
DRY PLACE.
Other Precautions:OTHER INFO: IS PRESENTED HERE. SEE ACTUAL ENTRY IN
RTECS FOR COMPLETE INFORMATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:RUBBER GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:<158.C, 316.4F
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG BASES, SENSITIVE TO LIGHT, SENSITIVE TO
MOISTURE.
Hazardous Decomposition Products:TOXIC FUMES OF: CARBON MONOXIDE,
CARBON DIOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:RTECS #: VO0525000 SALICYLIC ACID. IRRIT
DATA: SKN-RBT: 500 MG/24H MLD. BIOFX* 21-3/1971. EYE-RBT 100 MG SEV
BIOFX* 21-3/1971. TOXICITY DATA: ORL-RAT LD50: 891 MG/KG BIOFX*
21-3/1971. IHL-RAT LC50: >9 00 MG/M3/1H BIOFX* 21-3/1971. SKN-RAT
LD50:> 2 GM/KG ATDAEI 15 (SUPPL 1), S81, 1996. IPR-RAT LD50:157
MG/KG 57(7-8), 31,1992 GISAAA. ORL-MUS LD50: 480 MG/KG HBTXAC
5,148,1959. IPR-MUS LD50:300 MG/KG G NRIDX 3,675,1969. IVN-MUS
LD50: 184 MG/KG. YKKZAJ 91,550,1971. ORL-CAT LD50: 400 MG/KG HBTXAC
5,148,1959. ORL-RBT LD50: 1300 MG/KG NIIRDN 6,291,1982. SKN-RBT
LD50:>10 GM/KG BIOFX*21-3/1971. (STATE REG ULATORY INFO)
===================== Ecological Information =====================
Ecological:DATA NOT YET AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OVSERVE ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:CONTACT ALDRICH CHEMICAL COMPANY FOR
TRANSPORTATION INFORMATION.
===================== Regulatory Information =====================
SARA Title III Information:FED REGULATORY: NOHS 1974: HZD 67680; NIS
39; TNF 6955; NOS 57; TNE 61410. NOES 1983: HZD 67680; NIS 40, TNF
2133; NOS 50; TNE 51922; TFE 20096. EPA GENETOX PROGRAM 1988,
POSITIVE: S CEREVISIAE-REVERS ION. EPA GENETOX PROGRAM 1988,
NEGATIVE: HISTIDINE REVERSION-AMES TEST. EPA TSCA SECTION 8 (B)
CHEMICAL INVENTORY. EPA TSCA SECTION 8 (D) UNPUBLISHED
HEALTH/SAFETY STUDIES. EPA TSCA TEST SUBMISSION (T SCATS) DATA
BASE, DECEMBER 1998
Federal Regulatory Information:EUROPEAN INFO: TOXIC R 61. MAY CAUSE
HARM TO THE UNBORN CHILD. R 22 HARMFUL IF SWALLOWED. R 36/37/38
IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN. S 45 IN CASE OF
ACCIDENT OF IF YOU FEEL UNWELL, SE EK MEDICAL ADVICE IMMEDIATELY
(SHOW THE LABEL WHERE POSSIBLE). S 26 IN CASE OF CONTACT WITH EYES,
RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL ADVICE. S
36/37/39 WEAR SUITABLE PROTECTIVE CL OTHING, GLOVES AND EYE/FACE
PROTECTION. S 22 DO NOT BREATHE DUST. REVIEWS, STANDARDS, AND
REGULATION S OEL=MAK. EPA FIFRA 1988 PESTICIDE SUBJECT TO
RESPIRATION OR RE-REGISTRATION FEREAC 54, 7740, 1989. (SARA TITLE
III)
State Regulatory Information:TOX INFO: IHL-MAM LC50:>300 MG/M3 GISAAA
57 (7-8),31,1992. TARGET ORGAN DATA: SENSE ORGANS AND SPECIAL
SENSES (CHANGE IN ACUITY). SENSE ORGANS AND SPECIAL SENSES
(TINNITUS). BEHAVIORAL (SOMNOLENCE). B EHAVIORAL (TREMOR).
BEHAVIORAL (CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD). BEHAVIOR
(MUSCLE WEAKNESS). CARDIAC (PULSE RATE INCREASED WITHOUT FALL IN
BP). CARDIAC (CHANGE IN RATE). LUNGS, THORAX OR R ESPIRATION
(RESPIRATORY DEPRESSION). LIVER (OTHER CHANGES). SKIN AND
APPENDAGES (HAIR). MATERNAL EFF ECTS (UTERUS, CERVIX, VAGINA).
MATERNAL EFFECTS (PARTURITATION). (OTHER INFO)
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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