===================== Product Identification =====================
MSDS NAME:OXSOL (R) 100
NIIN:01-399-0676
Status Code:A
MSDS Number: CJLVZ
=== Responsible Party ===
Company:OCCIDENTAL CHEMICAL CORPORATION
Address:OCCIDENTAL TOWER, 5005 LBJ FREEWAY
Box:809050
City:DALLAS
State:TX
ZIP:75380
Country:US
Info Phone Num:800-752-5151, MSDS 800-699-4970
Emergency Phone Num:800-733-3665/214-404-3228
Resp. Party Other MSDS Num.:M29358
CAGE:0AH54
=== Contractor Identification ===
Company:HUNTER D H ENTERPRISES INC
Address:2801 NW 55TH CT
Box:City:FORT LAUDERDALE
State:FL
ZIP:33309
Country:US
Phone:954-484-1401
Contract Num:SP0450-99-M-NC27
CAGE:0BKD5
Company:OCCIDENTAL CHEMICAL CORPORATION
Address:5005 LYNDON B JOHNSON FWY
Box:City:DALLAS
State:TX
ZIP:75244-6198
Country:US
Phone:800-752-5151/972-404-3800
CAGE:0AH54
============= Composition/Information on Ingredients =============
Name:P-CHLOROBENZOTRIFLUORIDE (PCBTF) (BENZENE, 1-CHLORO-4-
(TRIFLUOROMETHYL)-BENZENE
CAS:98-56-6
RTECS #:XS9145000
Minumum % Wt:98.5
Maxumum % Wt:100.
Other REC Limits:NONE RECOMMENDED
Name:2-CHLOROBENZOTRIFLUORIDE;
1-CHLORO-2-(TRIFLUOROMETHYL)-BENZENE
CAS:88-16-4
Minumum % Wt:0.
Maxumum % Wt:.9
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT): > 6.8 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: MAY PRODUCE SYMPTOMS OF
CENTRAL NERVOUS SYSTEM DEPRESSION. EYES: MAY BE IRRITATING. SKIN:
MAY BE IRRITATING. INGESTION: PROLONGED/REPEATED BREATHING OR
SWALLOWING LARGE AMOUNTS MAY CAUSE LIVER AND KIDNEY DAMAGE. TARGET
ORGANS: CNS, KIDNEY, LIVER.
Explanation of Carcinogenicity:NOT KNOWN TO BE CARCINOGENIC.
Effects of Overexposure:INHALATION: HEADACHE, DIZZINESS, NAUSEA, LOSS
OF BALANCE, DROWSINESS. EYES: IRRITATION. SKIN: IRRITATION.
INGESTION:LIVER AND KIDNEY DAMAGE.
Medical Cond Aggravated by Exposure:NONE KNOWN.
======================= First Aid Measures =======================
Eyes: IMMEDIATELY FLUSH WITH WATER, A DIRECT STREAM OF WATER
FOR 15 MIN, FORCIBLY HOLDING EYELIDS APART. IF IRRITATION PERSISTS
GET MEDICAL ATTENTION. SKIN: WASH THOROUGHLY WITH SOAP AND WATER.
REMOVE CONTAMINATED CLOTHING . IF IRRITATION OCCURS, GET MEDICAL
ATTENTION. INHALATION: MOVE TO FRESH AIR. IF BREATHING IS
DIFFICULT, HAVE TRAINED PERSON ADMINISTER OXYGEN. IF NOT BREATHING,
GIVE CPR. GET M EDICAL ATTENTION. INGESTION: DO NOT INDUCE
VOMITING. THIS MATERIAL IS NOT SOLUBLE. DO NOT GIVE FLUIDS. IF
SPONTANEOUS VOMITING IS INEVITABLE, PREVENT ASPIRATION BY KEEPING
HEAD BELOW KNEES. GET MEDICA L ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:=42.8C, 109.F
Autoignition Temp:>500.C, 932.F
Lower Limits:0.9
Upper Limits:10.5
Extinguishing Media:WATER SPRAY OR FOG , CARBON DIOXIDE, DRY CHEMICAL,
FOAM.
Fire Fighting Procedures:SHUT DOWN MOTORS AND PUMPS TO PREVENT
SPREADING OF FIRE. USE WATER TO COOL CONTAINERS BUT AVOID GETTING
WATER INTO CONTAINERS. WEAR NIOSH/MSHA APPROVED POSITIVE-PRESSURE
SELF-CONTAINED BREATHING APPAR ATUS AND FULL PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:OVER HEATED DRUMS WILL EXPLODE. HEAVY
VAPORS MAY TRAVEL TO SOURCE OF IGNITION AND FLASHBACK. HIGH VAPOR
CONCENTRATIONS HAVE AN ANESTHETIC EFFECT.
================== Accidental Release Measures ==================
Spill Release Procedures:CONTAIN LIQUID AND PREVENT DISCHARGES TO
STREAMS OR SEWERS. CONTROL OR STOP LOSS OF VOLATILE MATERIALS TO
THE ATMOSPHERE. LEAKS SHOULD BE STOPPED, SPILLS SHOULD BE CONTAINED
AND CLEANED UP IMMEDIATEL Y. RECOVERY AND REUSE OF SPILLED PRODUCT,
RATHER THAN DISPOSAL, SHOULD BE THE ULTIMATE GOAL OF A CLEAN-UP
OPERATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED AND
PROPERLY LABELED. STORE IN A COOL, VENTILATED AREA AWAY FROM
INCOMPATIBLE MATERIALS. DO NOT REUSE CONTAINERS.
Other Precautions:AVOID BREATHING VAPOR, USE WITH ADEQUATE VENTILATION.
DO NOT GET IN EYES, ON SKIN OR CLOTHING. KEEP AWAY FROM HEAT,
SPARKS, PILOT LIGHTS, WELDING OPERATIONS AND OPEN FLAME. DO NOT
EAT, DRINK OR SMOKE IN AREAS WHERE THIS MATERIAL IS USED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOR EMERGENCIES AND UNKNOWN CONCENTRATIONS, USE
NIOSH/MSHA APPROVED POSITIVE PRESSURE SELF-CONTAINED BREATHING
APPARATUS. UTILIZE RESPIRATORY PROTECTIVE EQUIPMENT IN ACCORDANCE
WITH 29CFR 1910.134.
Ventilation:GENERAL ROOM VENTILATION PLUS LOCAL EXHAUST AT POINTS OF
EMISSION TO MAINTAIN LEVELS OF AIRBORNE CONTAMINANTS BELOW EXPOSURE
LIMITS.
Protective Gloves:WEAR CHEMICAL RESISTANT AS NORTH SILVER SHIELD (R),
VITON(R), PVC OR NITRILE.
Eye Protection:CHEMICAL SAFETY GOGGLES PLUS FULL FACE SHIELD.
Other Protective Equipment:PLASTIC OR RUBBER APRON AS NECESSARY TO
PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE
AVAILABLE.
Work Hygienic Practices:EMERGENCY SHOWER AND EYEWASH FACILITY SHOULD BE
IN CLOSE PROXIMITY.WASH THOROUGHLY WITH SOAP AND WATER AFTER
HANDLING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
VAPORS ARE HEAVIER THAN AIR AND WILL TEND TO COLLECT IN LOW AREAS.
AVOID USE IN CONFINED SPACES. AREAS OF POOR VENTILATION COULD
CONTAIN CONCENTRATIONS HIGH ENOUGH TO CAUSE UNCONSCIOUSNESS AND
DEATH.
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:=138.9C, 282.F
Melt/Freeze Pt:=-36.1C, -33.F
Decomp Temp:Decomp Text:NOT GIVEN
Vapor Pres:5.3 MMHG
Spec Gravity:1.34
Evaporation Rate & Reference:0.9 (N-BUTANOL=1)
Solubility in Water:29PPM@23C
Appearance and Odor:CLEAR, COLORLESS LIQUID, NAPHTHALENIC ODOR
Percent Volatiles by Volume:100 %
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZERS, OXIDIZING AGENTS.
Hazardous Decomposition Products:CHLORINE CONTAINING GASES CAN BE
PRODUCED AND FLUORINE CONTAINING GASES CAN BE PRODUCED.
=================== Toxicological Information ===================
Toxicological Information:ACUTE ORAL LD50: (RAT)>6.8 G/KG. ACUTE DERMAL
LD50: (RABBIT)>2.7 G/KG. ACUTE INHALATION LC50 (RAT)=4479 PPM.
PRIMARY SKIN IRRITATION: (RABBIT), NON-IRRITATING. PRIMARY EYE
IRRITATION: (RABBIT), NON-IR RITATING.
===================== Ecological Information =====================
Ecological:AQUATIC ECOTOX DATA: FISH: LC50 (96 HR) (RAINBOW TROUT) 13.5
MG/L. LC50 (96 HOUR) (BLUEGILL SUNFISH) 12.0 MG/L. MATC (31 DAY)
(FATHEAD MINNOW) >0.54<1.4 MG/L * TRIETHYLENE GYLCOL USED AS
SOLVENT CARR IER. BCF (48 HR) (BLUEGILL SUNFISH) 121.8 & 202.0.
INVERTEBRATES: LC50 (48 HR) (WATER FLEA) 12.4 MG/L. MATC (21 DAY)
(WATER FLEA) >0.03<0.05 M/L *ACETONE USED AS SOLVENT CARRIER.
AMPHIBIANE: NO DATA AVAILABLE. PLANTS: IC50 (72 HR) (GREEN-BLUE
ALGAE) 500 MG/L.
==================== Disposal Considerations ====================
Waste Disposal Methods:SHIPMENTS OF WASTE MATERIAL MAY BE SUBJECT TO
MANIFESTING REQUIREMENTS PER APPLICABLE REGULATIONS. APPROPIATE
DISPOSAL WILL DEPEND ON THE NATURE OF EACH WASTE MATERIAL AND
SHOULD BE DONE BY A COMPONE NT AND PROPERLY PERMITTED CONTRACTOR.
=================== MSDS Transport Information ===================
Transport Information:DOT PROPER SHIPPING NAME:
CHLOROBENZOTRIFLUORIDES, HAZARD CLASS 3, IDENTIFICATION NUMBER
UN2234, PACKING GROUP III.
===================== Regulatory Information =====================
SARA Title III Information:SARA/TITLE III HAZARD CATEGORIES: IMMEDIATE
(ACUTE) HEALTH: NO, DELAYED (CHRONIC) HEALTH: YES. FIRE HAZARD:
YES, REACTIVE HAZARD: NO, SUDDEN RELEASE OF PRESSURE: NO.
Federal Regulatory Information:TSCA: ALL COMPONENTS OF THIS PRODUCT
THAT ARE REQUIRED TO BE ON THE TSCA INVENTORY ARE LISTED ON THE
INVENTORY.
State Regulatory Information:CANADA: WHMIS HAZARD CLASS: B3.
PENNSYLVANIA HAZARDOUS SUBSTANCE. PHILIPPINES INVENTORY (PICCS).
NEW JERSEY REQUIREMENTS - 1% OR GREATER.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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