===================== Product Identification =====================
MSDS NAME:NITRIC ACID 10% RS, H262
NIIN:00N092120
Status Code:A
MSDS Number: CJLWZ
=== Responsible Party ===
Company:MALLINCKRODT BAKER INC
Address:222 RED SCHOOL LANE
City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Info Phone Num:800-582-2537
Emergency Phone Num:908-859-2151
Resp. Party Other MSDS Num.:NITAC
Chemtrec Ind/Phone:(800)424-9300
CAGE:70829
=== Contractor Identification ===
Company:MALLINCKRODT BAKER, INC.
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:800-582-2537
CAGE:70829
============= Composition/Information on Ingredients =============
Name:NITRIC ACID
CAS:7697-37-2
RTECS #:QU5775000
= Wt:10.
Other REC Limits:N/K
OSHA PEL:5 MG/M3;2 PPM
OSHA STEL:N/K
ACGIH TLV:5.2 MG/M3;2 PPM
ACGIH STEL:10 MG/M3;4 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
= Wt:90.
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:NITRIC ACID IS EXTREMELY HAZARDOUS; IT
IS CORROSIVE, REACTIVE, AN OXIDIZER, & A POISON. ACUTE: INHALATION:
CORROSIVE! MAY CAUSE IRRITATION OF NOSE, THROAT, & RESPIRATORY
TRACT INCLUDING COUGHING & CHO KING. HIGHER
CONCENTRATIONS/PROLONGED EXPOSURE TO VAPORS OF NITRIC ACID MAY LEAD
TO PNEUMONIA/PULMONARY EDEMA. INGESTION: CORROSIVE! MAY CAUSE
IMMEDIATE PAIN & BURNS OF MOUTH, THROAT, ESOPHAGUS & GAST
ROINTESTINAL TRACT. SKIN: CORROSIVE! MAY CAUSE REDNESS, PAIN, &
SEVERE SKIN BURNS. EYES: CORROSIVE! VAPORS ARE IRRITATING & MAY
CAUSE DAMAGE TO EYES. CONTACT MAY CAUSE SEVERE BURNS & PERMANENT
EYE DAM AGE. (EFFECTS OF OVEREXPOSURE)
Effects of Overexposure:HEALTH HAZARDS: CHRONIC: LONG-TERM EXPOSURE TO
CONCENTRATED VAPORS MAY CAUSE EROSION OF TEETH. LONG-TERM EXPOSURES
SELDOM OCCUR DUE TO THE CORROSIVE PROPERTIES OF THE ACID.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS, EYE DISEASE, OR CARDIOPULMONARY DISEASES MAY BE MORE
SUSCEPTIBLE TO THE EFFECTS OF THIS SUBSTANCE.
======================= First Aid Measures =======================
First Aid:IMMEDIATE FIRST AID TREATMENT REDUCES HEALTH EFFECTS OF THIS
SUBSTANCE. INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
CALL MD. INGE ST: DO NOT INDUCE VOMITING! GIVE LARGE QUANTITIES OF
WATER/MILK IF AVAILABLE. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. GET MEDICAL ATTENTION IMMED. SKIN: IMMED FLUSH
W/PLENTY OF WATER FO R AT LEAST 15 MINUTES WHILE REMOVING
CONTAMINATED CLOTHING & SHOES. WASH CLOTHING BEFORE REUSE. CALL MD.
EYES: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINUTES,
LIFTING LOWER & UPPER EYELIDS OCCA SIONALLY. GET MEDICAL ATTENTION
IMMED.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER OR WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . INCREASES THE FLAMMABILITY OF COMBUSTIBLE, ORGANIC AND
READILY OXIDIZABLE MATERIALS.
Unusual Fire/Explosion Hazard:NOT COMBUST, BUT SUBSTANCE IS A STRONG
OXIDIZER & ITS HEAT OF RXN W/REDUCING AGENTS/COMBUSTIBLES MAY CAUSE
IGNIT. CAN REACT W/METALS TO RELEASE FLAMM HYDROGEN GAS. MAY REACT
EXPLOSIVELY W/COMBUST ORG/ READILY OXIDIZABLE MATLS SUCH AS
ALCOHOLS, TURPENTINE, CHARCOAL, ORGANIC REFUSE, METAL POWDER,
HYDROGEN SULFIDE, ETC.
================== Accidental Release Measures ==================
Spill Release Procedures:VENT AREA OF LEAK/SPILL. WEAR APPROP PERS PROT
EQUIP AS SPECIFIED IN CTL MEASURES SECTION. ISOLATE HAZ AREA. KEEP
UNNEC & UNPROT PERS FROM ENTERING. CONTAIN & RECOVER LIQ WHEN POSS.
NEUT W/ALKALINE MA TL (SODA ASH, LIME), THEN ABSORB W/INERT MATL
(E.G., VERMICULITE, DRY SAND, EARTH), & PLACE IN CHEM WASTE CONTR.
DO NOT USE COMBUST MATLS, SUCH AS SAWDUST. DO NOT FLUSH TO SEWER!
(SUP DAT)
Neutralizing Agent:ALKALINE MATERIAL (SODA ASH, LIME).
====================== Handling and Storage ======================
Handling and Storage Precautions:CONTAINERS OF THIS MATERIAL MAY BE
HAZARDOUS WHEN EMPTY SINCE THEY RETAIN PRODUCT RESIDUES (VAPORS,
LIQUID); OBSERVE ALL WARNINGS AND PRECAUTIONS LISTED FOR THE
PRODUCT. KEEP IN A TIGHTLY CLOSED CONTA INER, STORED IN A COOL,
DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL DAMAGE.
Other Precautions:SEPARATE FROM COMBUSTIBLE, ORGANIC, OR ANY OTHER
READILY OXIDIZABLE MATERIALS. PROTECT FROM FREEZING. DO NOT GET IN
EYES, ON SKIN, OR ON CLOTHING. DO NOT BREATHE VAPOR OR MIST. USE
ONLY WITH ADEQUATE VENTILATION. STORE IN A TIGHTLY CLOSED
CONTAINER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF THE EXPOSURE LIMIT IS EXCEEDED, WEAR A NIOSH
APPROVED SUPPLIED AIR, FULL-FACEPIECE RESPIRATOR, AIRLINED HOOD, OR
FULL-FACEPIECE SELF-CONTAINED BREATHING APPARATUS. CANISTER-TYPE
RESPIRATORS USING S ORBENTS ARE INEFFECTIVE.
Ventilation:A SYS OF LOC &/OR GEN EXHST IS REC TO KEEP EMPLOYEES EXPOS
BELOW AIRBORNE EXPOS LIMS. LOC EXHST VENT IS GEN PREF BECAUSE IT
CAN CTL EMISSIONS OF (OTHER INFO)
Protective Gloves:WEAR IMPERVIOUS PROTECTIVE GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES AND FULL LENGTH
FACESHIELD .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER . WEAR IMPERVIOUS PROTECTIVE CLOTHING, INCLUDING BOOTS, LAB
COAT, APRON OR COVERALLS, AS APPROPRIATE, TO PREVENT SKIN CONTACT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE AND WASH
CONTAMINATED CLOTHING PROMPTLY.
Supplemental Safety and Health
SPILL PROC: US REGS (CERCLA) REQUIRE REPORTING SPILLS & RELEASES TO
SOIL, WATER & AIR IN EXCESS OF REPORTABLE QTYS. TOLL FREE # FOR US
COAST GUARD NATL RESPONSE CTR IS (800) 424-8802. WASTE DISP METH:
STATE & LOC DISP REGS MAY DIFFER FROM FED DISP REGS. DISPOSE OF
CONTR & UNUSED CONTENTS I/A/W FED, STATE & LOC REQS.
================== Physical/Chemical Properties ==================
Boiling Pt:=101.1C, 214.F
Melt/Freeze Pt:=-2.8C, 27.F
Spec Gravity:1.41
Solubility in Water:INFINITELY SOLUBLE
Appearance and Odor:CLEAR TO PALE YELLOW SOLUTION; SUFFOCATING, ACRID
ODOR.
Percent Volatiles by Volume:OTHER INFO
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG BASES, METALLIC POWDERS, CARBIDES, HYDROGEN SULFIDE, TURPENTINE,
AND COMBUSTIBLE ORGANICS.
Stability Condition to Avoid:HEAT AND INCOMPATIBLES.
Hazardous Decomposition Products:WHEN HEATED TO DECOMPOSITION, EMITS
TOXIC NITROGEN OXIDES FUMES AND HYDROGEN NITRATE.
=================== Toxicological Information ===================
Toxicological Information:FOR NITRIC ACID: INVESTIGATED AS A MUTAGEN
AND REPRODUCTIVE EFFECTOR.
===================== Ecological Information =====================
Ecological:ENVIRONMENTAL FATE: NO INFORMATION FOUND. ENVIRONMENTAL
TOXICITY: NO INFORMATION FOUND.
==================== Disposal Considerations ====================
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING
SHOULD BE MANAGED IN APPROP & APPRVD WASTE FACILITY. ALTHOUGH NOT A
LISTED RCRA HAZ WASTE, THIS MATL MAY EXHIBIT ONE/MORE CHARACTS OF
HAZ WASTE & REQUIR E APPROP ANALYSIS TO DETERMINE SPECIFIC DISP
REQS. PROCESSING, USE/CONTAM OF PROD MAY CHANGE WASTE M ANAGEMENT
OPTIONS. (SUP DAT)
=================== MSDS Transport Information ===================
Transport Information:DOMESTIC (LAND, D.O.T.) AND INTERNATIONAL (WATER,
I.M.O.): PROPER SHIPPING NAME: NITRIC ACID (WITH 10% NITRIC ACID);
HAZARD CLASS: 8; UN/NA: UN2031; PACKING GROUP: II; INFORMATION
REPORTED FOR PRODUCT /SIZE: 20L.
===================== Regulatory Information =====================
SARA Title III Information:SARA SECTION 302 RQ AND TPQ: 1000 LBS NITRIC
ACID (CAS # 7697-37-2). WATER (CAS # 7732-18-5) NOT LISTED IN SARA
SECTION 302. NITRIC ACID IS LISTED IN SARA SECTION 313; NOT LISTED
IN SARA 313 CHEMICAL CATEGORY. WATER NOT LISTED IN SARA 313 LIST
OR CHEMICAL CATEGORY. SARA 311/312: ACUTE: YES; CHRONIC: YES; FIRE:
NO; PRESSURE: NO; REACTIVITY: YES (MIXTURE/LIQUID).
Federal Regulatory Information:NITRIC ACID AND WATER ARE LISTED IN
TSCA, EC, JAPAN, AUSTRALIA, KOREA, CANADA DSL, AND THE PHILIPPINES.
NOT LISTED IN CANADA NDSL. CERCLA: NITRIC ACID: 1000 LBS; WATER:
NO. RCRA 261.33: NO INGREDIENTS LISTED. TSCA 8 (D): NO INGREDIENTS
LISTED. CHEMICAL WEAPONS CONVENTION: NO. TSCA 12 (B): NO. CDTA: NO.
AUSTRALIAN HAZCHEM CODE: 2PE. POISON SCHEDULE: S6. WHMIS: THIS MSDS
HAS BEEN PREPARED ACCORDING TO THE HAZARD CRITERIA OF THE
CONTROLLED PRODUCTS REGULATIONS (CPR) AND THE MSDS CONTAINS ALL OF
THE INFORMATION REQUIRED BY THE CPR.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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