===================== Product Identification =====================
MSDS NAME:CUPRIC BROMIDE, 0459
NIIN:00N092119
Status Code:A
MSDS Number: CJLWS
=== Responsible Party ===
Company:MALLINCKRODT BAKER INC
Address:222 RED SCHOOL LANE
City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Info Phone Num:800-582-2537
Emergency Phone Num:908-859-2151
Resp. Party Other MSDS Num.:C5841
Chemtrec Ind/Phone:(800)424-9300
CAGE:70829
=== Contractor Identification ===
Company:MALLINCKRODT BAKER, INC.
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:800-582-2537
CAGE:70829
============= Composition/Information on Ingredients =============
Name:CUPRIC BROMIDE
CAS:7789-45-9
= Wt:100.
Other REC Limits:N/K
OSHA PEL:1 MG/M3
OSHA STEL:N/K
ACGIH TLV:1 MG/M3
ACGIH STEL:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NO INFORMATION FOUND.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:LIMITED HLTH HAZ INFO WAS FOUND FOR
THIS MATL. ITS HAZS ARE ASSUMED TO BE SIMILAR TO OTHER SOLUBLE
COPPER & BROMINE SALTS. ACUTE: INHAL: CAUSES IRRIT TO RESP TRACT,
SYMPS MAY INCL COUGHING, SORE THROA T, & SHORTNESS OF BREATH. MAY
RSLT IN ULCERATION & PERFORATION OF RESP TRACT. WHEN HEATED, THIS
CMPD MAY GIVES OFF COPPER FUME, WHICH CAN CAUSE SYMPS SIMILAR TO
COMMON COLD, INCL CHILLS & STUFFINESS O F HEAD. INGEST: SINGLE
DOSE OF BROMIDE/COPPER SALTS CAN CAUSE BURNING PAIN IN MOUTH,
ESOPHAGUS, & STOM. HEMORRHAGIC GASTRITIS, NAUS, VOMIT, ABDOM PAIN,
METALLIC TASTE, & DIARR MAY OCCUR. (EFTS OF OVE REXP)
Effects of Overexposure:HLTH HAZ: IF VOMIT DOES NOT OCCUR IMMED,
SYSTEMIC POIS CAN OCCUR. FOR COPPER SALTS, SYMPS MAY INCL CAPILLARY
DMG, HDCH, COLD SWEAT, WEAK PULSE, KIDNEY & LIVER DMG, CNS
EXCITATION FOLLOWED BY DEPRESS, BLOOD EFTS, JAUN, PARAL & COMA.
DEATH MAY OCCUR FROM SHOCK/RENAL FAILURE. FROM BROMIDE SALTS, SYMPS
OF SYSTEMIC POIS MAY INCL DROW, IRRITABILITY, DIZZ, CONFUSION, SKIN
RASH, BLURRED VISION & OTHER EYE EFTS, MANIA & COMA. SKIN: MAY ACT
AS IRRITANT, PRODUCING ITCHING EZCEMA, REDNESS & PAIN. EYES: COPPER
SALTS MAY PRDCE CONJ/EVEN ULCERATION OF CORNEA. (SUP DAT)
Medical Cond Aggravated by Exposure:PERS SUFFERING FROM SKIN DISORDERS,
IMPAIRED LIVER, KIDNEY/PULM FUNC, GLUCOSE-6-PHOSPHATE DEHYDROGENASE
DEFICIENCY, DEBILITATION, DEPRESS, ALCOHOLISM, NEURO/PSYCHOLOGICAL
DISORDERS OR (OTHER INFO)
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL MD.
INGEST: INDUCE VOMITING IMMED AS DIRECTED BY MEDICAL PERSONNEL.
NEVER GIVE A NYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL MD
IMMED. SKIN: WIPE OFF EXCESS MATERIAL FROM SKIN THEN IMMED FLUSH
SKIN W/PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE CONTAMINATED
CLOTHING & SHOES . WASH CLOTHING BEFORE REUSE. CALL MD. EYES: IMMED
FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINUTES, LIFTING LOWER &
UPPER EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION IMMED.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING
SURROUNDING FIRE. WATER SPRAY MAY BE USED TO KEEP FIRE-EXPOSED
CONTAINERS COOL.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE A FIRE HAZARD.
REACTIONS WITH INCOMPATIBLES MAY POSE AN EXPLOSION HAZARD.
================== Accidental Release Measures ==================
Spill Release Procedures:VENT AREA. KEEP UNNEC & UNPROT PEOPLE AWAY
FROM AREA OF SPILL. WEAR APPROP PERS PROT EQUIP AS SPECIFIED IN CTL
MEASURES SECTION. SPILLS: PICK UP & PLACE IN SUITABLE CONTR FOR
RECLAMATION/DISP, USING M ETH THAT DOES NOT GENERATE DUST. US REGS
(CERCLA) REQUIRE REPORTING SPILLS & RELEASES TO SOIL, WATER & AIR
IN EXCESS OF REPORTABLE QTYS. US COAST GUARD NATL RESPONSE CTR TOLL
FREE #: (800) 424-8802.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP IN TIGHTLY CLOSED CONTAINER,
STORED IN COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL
DAMAGE. SEPARATE FROM INCOMPATIBILITIES. CONTAINERS OF THIS
MATERIAL MAY BE HAZARDOUS WHEN EMPTY SINCE THEY RETAIN PRODUCT
RESIDUES (DUST, SOLIDS); OBSERVE ALL WARNINGS & PRECAUTIONS LISTED
FOR PRODUCT.
Other Precautions:AVOID BREATHING DUST. KEEP CONTAINER CLOSED. USE ONLY
WITH ADEQUATE VENTILATION. AVOID CONTACT WITH EYES, SKIN AND
CLOTHING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOS LIM IS EXCEEDED, A NIOSH APPRVD
FALF-FACE DUST/MIST RESP MAY BE WORN FOR UP TO 10 TIMES EXPOS
LIM/MAX USE CONC SPECIFIED BY APPROP REGULATORY AGENCY/RESP
SUPPLIER, WHICHEVER IS LOWEST. A NIOS H APPRVD FULL-FACE PIECE
DUST/MIST RESP MAY BE WORN UP TO 50 TIMES EXPOS LIM/MAX USE CONC
SPECIFIED BY APPROP REGULATORY AGENCY/RESP SUPPLIER, (OTHER INFO)
Ventilation:A SYS OF LOC &/OR GEN EXHST IS REC TO KEEP EMPLOYEES EXPOS
BELOW AIRBORNE EXPOS LIMS. LOC EXHST VENT IS GEN PREF BECAUSE IT
CAN CTL EMISSIONS OF (TOX INFO)
Protective Gloves:WEAR PROTECTIVE GLOVES. WEAR IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER . WEAR CLEAN BODY-COVERING CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EFTS OF OVEREXP: CHRONIC: PRLNG/RPTD SKIN EXPOS TO COPPER SALTS MAY
CAUSE DERM. PRLNG/RPTD EXPOS TO DUST OF COPPER SALTS MAY CAUSE
DISCOLORATION OF SKIN/HAIR, LIVER DMG, BLOOD EFTS, ULCERATION &
PERFO RATION OF NASAL SEPTUM, RUNNY NOSE, METALLIC TASTE, &
ATROPHIC CHANGES & IRRIT OF MUC MEMBS. (TOX INFO)
================== Physical/Chemical Properties ==================
Boiling Pt:=900.C, 1652.F
Melt/Freeze Pt:=497.8C, 928.F
Spec Gravity:4.71
Appearance and Odor:GLISTERING, GRAYISH BLACK CRYSTALS; SLIGHT ODOR OF
BROMINE.
Percent Volatiles by Volume:0 @ 21C/70F
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS; BASES, ACETYLENE, SODIUM HYPOBROMITE,
NITROMETHANE.
Stability Condition to Avoid:INCOMPATIBLES.
Hazardous Decomposition Products:OXIDES OF THE CONTAINED METAL AND
HALOGEN, POSSIBLY ALSO FREE, OR IONIC HALOGEN.
=================== Toxicological Information ===================
Toxicological Information:NO LD50/LC50 INFORMATION FOUND RELATING TO
NORMAL ROUTES OF OCCUPATIONAL EXPOSURE. VENTILATION: CONTAMINANT AT
ITS SOURCE, PREVENTING DISPERSION OF IT INTO THE GENERAL WORK AREA.
PLEASE REFER TO THE A CGIH DOCUMENT, INDUSTRIAL VENTILATION, A
MANUAL OF RECOMMENDED PRACTICES, MOST RECENT EDITION, FOR DETAILS.
SUP DAT: SYMPTOMS OF CHRONIC BROMIDE POISONING MAY INCLUDE SKIN
RASHES, CENTRAL NERVOUS SYST EM DEPRESSION, ATAXIA, PSYCHOSES,
MEMORY LOSS, APPETITE LOSS AND COMA. SOLUBILITY: SOLUBLE IN WATER
(126 PARTS/100 PARTS WATER), ALCOHOL, ACETONE, AMMONIA; INSOLUBLE
IN BENZENE.
===================== Ecological Information =====================
Ecological:ENVIRONMENTAL FATE: WHEN RELEASED INTO THE SOIL, THIS
MATERIAL IS NOT EXPECTED TO BIODEGRADE; IT MAY LEACH INTO
GROUNDWATER. WHEN RELEASED INTO WATER, THIS MATERIAL IS NOT
EXPECTED TO BIODEGRADE, OR E VAPORATE SIGNIFICANTLY. THIS MATERIAL
ISEXPECTED TO SIGNIFICANTLY BIOACCUMULATE. THIS MATERIAL HAS AN
EXPERIMENTALLY-DETERMINED BIOCONCENTRATION FACTOR (BCF) OF GREATER
THAN 100. BIOACCUMULATION DATA FOR COPPER. ENVIRONMENTAL TOXICITY:
THIS MATERIAL IS EXPECTED TO BE VERY TOXIC TO AQUATIC LIFE. THE
LC50/96-HOUR VALUES FOR FISH ARE LESS THAN 1 MG/L. THE IC50/72-HOUR
VALUES FOR ALGAE ARE LESS THAN 1 MG/L. TOXICITY DATA FOR COPPER.
==================== Disposal Considerations ====================
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING
SHOULD BE MANAGED IN APPROP & APPRVD WASTE FACILITY. PROCESSING,
USE/CONTAM OF THIS PROD MAY CHANGE WASTE MANAGEMENT OPTIONS. STATE
& LOC DISP REGS MAY DIFFER FROM FED DISP REGS. DISPOSE OF CONTR &
UNUSED CONTENTS I/A/W FED, STATE & LOC REQS.
=================== MSDS Transport Information ===================
Transport Information:NOT REGULATED.
===================== Regulatory Information =====================
SARA Title III Information:SARA 302 RQ/TPQ: NO INGREDIENTS LISTED. SARA
313 LIST: NO INGREDIENTS LISTED. SARA 313 CHEMICAL CATEGORY: COPPER
COMPOUND (CUPRIC BROMIDE, CAS # 7789-45-9). SARA 311/312: ACUTE:
YES; CHRONIC: YES; FIR E: NO; PRESSURE: NO; REACTIVITY: NO
(PURE/SOLID).
Federal Regulatory Information:CUPRIC BROMIDE (CAS # 7789-45-9) IS
LISTED IN TSCA, EC, JAPAN, AUSTRALIA, KOREA, CANADA DSL, AND THE
PHILIPPINES. NOT LISTED IN CANADA NDSL. CERCLA: NOT LISTED. RCRA
261.33: NOT LISTED. TSCA 8 (D): NO T LISTED. CHEMICAL WEAPONS
CONVENTION: NO. TSCA 12 (B): NO. CDTA: NO. AUSTRALIAN HAZCHEM CODE:
NO INFORMATION FOUND. POISON SCHEDULE: NO INFORMATION FOUND. WHMIS:
THIS MSDS HAS BEEN PREPARED ACCORDING TO THE HAZARD CRITERIA OF
THE CONTROLLED PRODUCTS REGULATIONS (CPR) AND THE MSDS CONTAINS ALL
OF TH E INFORMATION REQUIRED BY THE CPR.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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