===================== Product Identification =====================
MSDS NAME:ETHYL ALCOHOL REAGENT, DENATURED, 362808
NIIN:00N092107
Status Code:A
MSDS Number: CJLXC
=== Responsible Party ===
Company:ALDRICH CHEMICAL CO INC
Address:1001 W ST PAUL
City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Info Phone Num:414-273-3850
Emergency Phone Num:414-273-3850
CAGE:60928
=== Contractor Identification ===
Company:ALDRICH CHEMICAL CO INC
Address:1001 WEST ST PAUL AVE
Box:355
City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:60928
============= Composition/Information on Ingredients =============
Name:ETHYL ALCOHOL. LD50:(ORAL,RAT) 7060 MG/KG.
CAS:64-17-5
RTECS #:KQ6300000
OSHA PEL:1900 MG/M3;1000 PPM
ACGIH TLV:1880 MG/M3;1000 PPM
Name:METHYL ALCOHOL. ACGIH TLV: 260 MG/M3 - TWA; 310 MG/M3 -
STEL (M).
CAS:67-56-1
RTECS #:PC1400000
= Wt:5.
OSHA PEL:260 MG/M3;200 PPM
OSHA STEL:310 MG/M3;250 PPM
ACGIH TLV:262 MG/M3;200 PPM
ACGIH STEL:328 MG/M3;250 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:2-PROPANOL (ISOPROPYL ALCOHOL). OSHA PEL: 983 MG/M3 - 8H
TWA; 1225 MG/M3 - STEL (M).
CAS:67-63-0
RTECS #:NT8050000
OSHA PEL:980 MG/M3;400 PPM
ACGIH TLV:983 MG/M3;400 PPM
ACGIH STEL:1230 MG/M3;500 PPM
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS & TOXICOLOGICAL INFO.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL IF INHALED OR
SWALLOWED. MAY BE HARMFUL IF ABSORBED THROUGH SKIN. VAPOR OR MIST
IS IRRITATING TO EYES, MUCOUS MEMBRANES AND UPPER RESPIRATORY
TRACT. CAUSES SKIN IRRITATION. CAN CAUSE CE NTRAL NERVOUS SYSTEM
DEPRESSION. EXPOSURE CAN CAUSE: GASTROINTESTINAL DISTURBANCES;
NAUSEA, DIZZINESS AND HEADACHE; NARCOTIC EFFECT. PROLONGED OR
REPEATED EXPOSURE TO SKIN CAUSES DEFATTING AND DERMATI TIS. MAY
CAUSE CONVULSIONS. CHRONIC: TARGET ORGAN(S): NERVES, EYES, LIVER,
KIDNEYS, HEART, CARDIOVASCULAR SYSTEM, GASTROINTESTINAL SYSTEM. TO
THE BEST OF MANUFACTURER'S KNOWLEDGE, THE CHEMICAL, PHYSIC AL AND
TOXICOLOGICAL (EFTS OF OVEREXP)
Effects of Overexposure:HLTH HAZ: PROPERTIES HAVE NOT BEEN THOROUGHLY
INVESTIGATED. RTECS DATA AND SYNONYMS SUPPLIED ARE FOR THE MOST
ABUNDANT HAZARDOUS COMPONENT OF THIS PRODUCT.
======================= First Aid Measures =======================
Eyes: IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT
LEAST 15 MINUTES. ASSURE ADEQUATE FLUSHING BY SEPARATING EYELIDS
WITH FINGERS. SKIN: IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER
FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING &
SHOES. WASH CONTAMINATED CLOTHING BEFORE REUSE. INHALATION: REMOVE
TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. INGESTION: WASH OUT MOUTH
WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL MD.
===================== Fire Fighting Measures =====================
Flash Point:=8.9C, 48.F
Autoignition Temp:=422.8C, 793.F
Lower Limits:3.3%
Upper Limits:19% @ 60C
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE
FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS.
FLAMMABLE LIQUID.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION &
FLASH BACK. CONTAINER EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:SHUT OFF ALL SOURCES OF IGNITION. EVACUATE
AREA. WEAR NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS,
RUBBER BOOTS & HEAVY RUBBER GLOVES. ABSORB ON SAND OR VERMICULITE &
PLACE IN CLOSED CONTAINERS FOR DISPOSAL. USE NON-SPARKING TOOLS.
VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS
COMPLETE.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT BREATHE VAPOR. DO NOT GET IN
EYES, ON SKIN, ON CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE.
HARMFUL LIQUID. IRRITANT. KEEP CONTAINER TIGHTLY CLOSED. KEEP AWAY
FROM HEAT, SPARKS & OPEN FLAME. STORE IN A COOL, DRY PLACE.
Other Precautions:FLAMMABLE (U.S.A.). HIGHLY FLAMMABLE (EU). KEEP AWAY
FROM SOURCES OF IGNITION - NO SMOKING. AVOID CONTACT WITH SKIN. IN
CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE
IMMEDIATELY (SHOW LA BEL WHERE POSSIBLE). HYGROSCOPIC. HANDLE &
STORE UNDER NITROGEN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WEAR OTHER PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
OTHER INFO: (B) CHEM INVENTORY; (D) UNPUBLISHED HLTH/SFTY STUDIES. EPA
TSCA TEST SUBMISSION (TSCATS) DATA BASE, DECEMBER 1998. NIOSH
ANALYTICAL METHOD, 1994: ETHANOL IN BLOOD, 8002 & ALCOHOLS I, 1400.
NTP CARCINOGENESIS STUDIES; ON TEST (2 YR STUDIES), NOVEMBER 1998.
================== Physical/Chemical Properties ==================
Boiling Pt:=78.C, 172.4F
Melt/Freeze Pt:=-130.C, -202.F
Vapor Pres:40 MM @ 19C
Vapor Density:1.59
Spec Gravity:0.785
Appearance and Odor:COLORLESS LIQUID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, PEROXIDES, ACIDS, ACID CHLORIDES, ACID ANHYDRIDES,
ALKALI METALS, AMMONIA.
Stability Condition to Avoid:PROTECT FROM MOISTURE.
Hazardous Decomposition Products:TOXIC FUMES OF CARBON MONOXIDE, CARBON
DIOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:ETHYL ALCOHOL:IRRIT DATA:SKN-RBT 400 MG OPEN
MLD - UCDS** 7/22/1970. SKN-RBT 20 MG/24H MOD - 85JCAE -,189,1986.
EYE-RBT 500 MG SEV - AJOPAA 29,1363,1946. EYE-RBT 500 MG/24H MLD -
85JCAE -,189,1986. EY E-RBT 100 MG/4S RINSE MOD - FCTOD7
20,573,1982. TOX DATA:LDL0:(ORL,CHD) 2 GM/KG - ATXKA8 17,183,1958.
LDL0:(ORL,HMN) 1400 MG/KG - NPIRI* 1,44,1974. LDL0:(SCU,INF) 19440
MG/KG - AJCPAI 5,466,1935. LC50 :(IHL,RAT) 20000 PPM/10H - NPIRI*
1,44,1974. LD50:(ORL,RAT) 7060 MG/KG - TXAPA9 16,718,1970.
LD50:(IPR,RAT) 3600 UG/KG - PHMGBN 2,27,1969. LD50:(IVN,RAT) 1440
MG/KG - TXAPA9 18,60,1971. LD50:(IAT,RAT) 11 MG/KG- (ECOLOGICAL
INFO)
===================== Ecological Information =====================
Ecological:DATA NOT YET AVAIL. -- TOX INFO: TXAPA9 18,60,1971.
LD50:(ORL,MUS) 3450 MG/KG - GISAAA 32(3), 31,1967. LC50:(IHL,MUS)
39 GM/M3/4H - GTPZAB 26(8), 53,1982. LD50:(IPR,MUS) 528 MG/KG -
STRAAA 127,245,196 5. LD50:(SCU,MUS) 8285 MG/KG - FAONAU
48A,99,1970. LD50:(IVN,MUS) 1973 MG/KG - HBTXAC 1,128,1955.
LD50:(ORL,RBT) 6300 MG/KG - HBTXAC 1,130,1955. LD50:(IPR,RBT) 963
MG/KG - EVHPAZ 61,321,1985. LD50:(IV N,RBT) 2374 MG/KG - EVHPAZ
61,321,1985. LD50:(ORL,GPG) 5560 MG/KG - JIHTAB 23,259,1941.
LD50:(IPR,GPG) 3414 MG/KG - EVHPAZ 61,321,1985. LD50:(IPR,HAM) 5068
MG/KG - EVHPAZ 61,321,1985. LD50:(IPR,MAM) 4 300 MG/KG - TXAPA9
(TRANSPORT INFO)
==================== Disposal Considerations ====================
Waste Disposal Methods:BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS
MATERIAL IS HIGHLY FLAMMABLE. OBSERVE ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGUL ATIONS.
=================== MSDS Transport Information ===================
Transport Information:CONT MFR FOR TRANSPORTATION INFO. -- ECOLOGICAL
INFO: 13,358,1968. TARGET ORGAN DATA: BEHAVIORAL (SLEEP; CHANGE IN
MOTOR ACTIVITY; ATAXIA; ANTIPSYCHOTIC; HDCH; CHANGE IN
PSYCHOPHYSIOLOGICAL TESTS). LU NGS, THORAX/RESP (CHRONIC PULM
EDEMA/CONGESTION; DYSP; OTHER CHANGES). GI (ALTERATION IN GASTRIC
SECRETION; HYPERMOTILITY, DIARR; NAUS/VOMIT; OTHER CHANGES). LIVER
(FATTY LIVER DEGENERATION; TUMORS). BLOOD (OTHER CHANGES; LYMPHOMA
INCL HODGKIN'S DISEASE). PATERNAL EFTS (TESTES, EPIDIDYMIS, SPERM
DUCT). EFTS ON FERTILITY (FEMALE/MALE FERTILITY INDEX;
POST-IMPLANTATION MORTALITY; OTHER MEASURES OF F ERTILITY). (EFTS
ON (SARA TITLE III)
===================== Regulatory Information =====================
SARA Title III Information:METHANOL - 67-56-1 - 5.0%:THIS PROD IS
SUBJECT TO SARA SECTION 313 REPORTING REQUIREMENTS. -- TRANSPORT
INFO:EMBRYO/FETUS (EXTRA EMBRYONIC STRUCTURES; CYTOLOGICAL CHANGES;
FETOTOXICITY; FETAL DEATH; O THER EFTS TO EMBRYO/FETUS). SPECIFIC
DEVEL ABNORMS (EYE, EAR; CRANIOFACIAL; MUSCULOSKELETAL SYS; RESP
SYS). EFTS ON NEWBORN (GROWTH STATISTICS). TUMORIGENIC (EQUIVOCAL
TUMORIGENIC AGENT BY RTECS CRITE RIA). ONLY SELECTED RTEC'S DATA IS
PRESENTED HERE. SEE ACTUAL DATA ENTRY IN RTECS FOR COMPLETE INFO.
Federal Regulatory Information:EU INFO:603-002-00-5; R11, R20/22, S7,
S16, S24, S45 (SEE OTHER PREC SECTION). REVIEWS, STDS &
REGS:OEL=MAK. ACGIH TLV:NOT CLASSIFIABLE AS HUMAN CARCIN; TWA 1880
MG/M3 (1000 PPM) - DTLVS* TLV/BEI,1997 . IARC CANCER REVIEW:ANIMAL
INADEQ EVID - IMEMDT 44,35,1988. EPA FIFRA 1988 PESTICIDE SUBJECT
TO REGISTRATION/RE-REGISTRATION - FEREAC 54,7740,1989. MSHA
STD-AIR: TWA 1000 PPM (1900 MG/M3) - DTLVS* 3, 103,1971. OSHA PEL:
8H TWA 1000 PPM (1900 MG/M3) (GEN INDU) - CFRGBR 29,1910.1000,1994;
(CONSTRUC) - CFRGBR 29,1926.55,1994; (SHIPYARD) - CFRGBR
29,1915.1000,1993; (FED CONT) - CFRGBR 41,50-2-4.50,1994. OEL-
(STATE REGULATORY INFO)
State Regulatory Information:FED REGULATORY:AUSTRALIA, DENMARK,
GERMANY, THE NETHERLANDS, THE PHILIPPINES, SWEDEN, SWITZERLAND,
THAILAND, TURKEY, UNITED KINGDOM:TWA 1000 PPM (1900 MG/M3) JAN
1993. OEL-BELGIUM:TWA 1000 PPM (1880 M G/M3) JAN 1993.
OEL-FINLAND:TWA 1000 PPM (1900 MG/M3); STEL 1250 PPM (2400 MG/M3)
JAN 1993. OEL-FRANCE:TWA 1000 PPM (1900 MG/M3); STEL 5000 PPM JAN
1993. OEL-HUNGARY:TWA 1000 MG/M3; STEL 3000 MG/M3 JA N 1993.
OEL-POLAND:TWA 1000 MG/M3 JAN 1993. OEL-RUSSIA:STEL 1000 MG/M3 JAN
1993. OEL IN BULGARIA, CO LOMBIA, JORDAN, KOREA, NEW ZEALAND,
SINGAPORE, VIETNAM CHECK ACGIH TLV. NIOSH REL TO ETHYL
ALCOHOL-AIR:10 H TWA 1000 PPM - (OTHER INFO)
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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