===================== Product Identification =====================
MSDS NAME:METHYL SALICYLATE, S80082
NIIN:00N092913
Status Code:A
MSDS Number: CJVVQ
=== Responsible Party ===
Company:FISHER SCIENTIFIC
Address:1 REAGENT LANE
City:FAIRLAWN
State:NJ
ZIP:07410
Country:US
Info Phone Num:201-796-7100
Emergency Phone Num:201-796-7100
Chemtrec Ind/Phone:(800)424-9300
CAGE:1B464
=== Contractor Identification ===
Company:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464
============= Composition/Information on Ingredients =============
Name:METHYL SALICYLATE. LD50:(ORAL,RAT) 887 MG/KG.
CAS:119-36-8
RTECS #:VO4725000
> Wt:99.
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS & TOXICOLOGICAL INFO.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE: MAY CAUSE IRRITATION.
SKIN: CAUSES MODERATE IRRITATION. MAY BE ABSORBED THROUGH SKIN IN
HARMFUL AMOUNTS. INGESTION: MAY CAUSE NAUSEA AND VOMITING. MAY BE
HARMFUL IF SWALLOWED. SYSTEMIC EFF ECTS OF EXPOSURE INCLUDE INITIAL
STIMULATION AND LATER CENTRAL NERVOUS SYSTEM DEPRESSION. SYMPTOMS
INCLUDE CONVULSIONS, RESPIRATORY FAILURE, CARDIAC COLLAPSE, AND
POSSIBLE DEATH. INHALATION: CAUSES RE SPIRATORY TRACT IRRITATION.
IRRITATION MAY LEAD TO CHEMICAL PNEUMONITIS AND PULMONARY EDEMA.
MAY CAUSE EFFECTS SIMILAR TO THOSE DESCRIBED FOR INGESTION. MAY
CAUSE LUNG DAMAGE. CHRONIC: MAY CAUSE LIVER AND KIDNEY DAMAGE.
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT LISTED BY ACGIH, IARC, NIOSH, NTP OR
OSHA.
Effects of Overexposure:HLTH HAZ: REPEATED EXPOSURE MAY CAUSE METABOLIC
DISTURBANCES. CAUTION! THIS SUBSTANCE HAS CAUSED ADVERSE
REPRODUCTIVE AND FETAL EFFECTS IN ANIMALS. TARGET ORGANS: KIDNEYS,
HEART, CENTRAL NERVOUS SYSTE M, LIVER.
======================= First Aid Measures =======================
Eyes: IMMED FLUSH WITH PLENTY OF WATER FOR AT LST 15 MINS,
OCCASIONALLY LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. SKIN:
IMMED FLUSH WITH PLENTY OF SOAP & WATER FOR AT LST 15 MINS WHILE
REMOVING C ONTAM CLTHG & SHOES. GET MED AID IF IRRIT DEVELOPS OR
PERSISTS. INGEST: IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS
OF MILK OR WATER. GET MED AID IMMED. INDUCE VOMIT BY GIVING 1 TSP
OF SYRUP OF I PECAC. CALL POIS CTL CTR. INHAL: REMOVE FROM EXPOS TO
FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT,
GIVE OXYG. GET MED AID. NOTES TO MD: TREAT SYMPTOMATICALLY &
SUPPORTIVELY. ANTID OTE: NO SPECIFIC ANTIDOTE EXISTS.
===================== Fire Fighting Measures =====================
Flash Point:=96.1C, 205.F
Autoignition Temp:=454.4C, 850.F
Lower Limits:NOT AVAIL
Upper Limits:NOT AVAIL
Extinguishing Media:WATER OR FOAM MAY CAUSE FROTHING. USE CARBON
DIOXIDE OR DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . VAPORS CAN TRAVEL TO A SOURCE OF IGNITION AND FLASH
BACK.
Unusual Fire/Explosion Hazard:NFPA RATING: HEALTH - 1; FLAMMABILITY -
1; REACTIVITY - 0.
================== Accidental Release Measures ==================
Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS
INDICATED IN EXPOSURE CONTROLS, PERSONAL PROTECTION SECTION. SWEEP
UP, THEN PLACE INTO A SUITABLE CONTAINER FOR DISPOSAL. REMOVE ALL
SOURCES OF IGNITION. AB SORB SPILL USING AN ABSORBENT,
NON-COMBUSTIBLE MATERIAL SUCH AS EARTH, SAND OR VERMICULITE.
====================== Handling and Storage ======================
Handling and Storage Precautions:USE WITH ADEQUATE VENTILATION. KEEP
FROM CONTACT WITH OXIDIZING MATERIALS. STORE IN A COOL, DRY,
WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES.
Other Precautions:GROUND AND BOND CONTAINERS WHEN TRANSFERRING
MATERIAL. DO NOT GET ON SKIN OR IN EYES. DO NOT INGEST OR INHALE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR
EUROPEAN STANDARD EN APPROVED RESPIRATOR WHEN NECESSARY.
Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP
AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES & FULL LENGTH
FACESHIELD .
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN
EXPOSURE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE
CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
Supplemental Safety and Health
PHYSICAL AND CHEMICAL PROPERTIES: VAP DENS: 5.24 (AIR=1). MOLECULAR
FORMULA: C8H8O3.
================== Physical/Chemical Properties ==================
Boiling Pt:=223.3C, 433.9F
Melt/Freeze Pt:=-8.6C, 16.5F
Decomp Temp:Decomp Text:NOT AVAILABLE
Vapor Pres:0.1 MM HG @ 20C
Vapor Density:SUPP DATA
Spec Gravity:1.18 (WATER=1)
pH:NOT AVAILABLE
Viscosity:NOT AVAILABLE
Solubility in Water:SLIGHTLY SOLUBLE
Appearance and Odor:COLORLESS TO YELLOW-RED LIQUID; WINTERGREEN ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG BASES.
Stability Condition to Avoid:STABLE AT ROOM TEMPERATURE IN CLOSED
CONTAINERS UNDER NORMAL STORAGE AND HANDLING CONDITIONS. AVOID
INCOMPATIBLE MATERIALS.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
SALICYCLIC ACID.
Conditions to Avoid Polymerization:HAS NOT BEEN REPORTED.
=================== Toxicological Information ===================
Toxicological Information:CAS # 119-36-8: RTECS # VO4725000:
LD50:(ORAL,MOUSE) 1110 MG/KG; LD50:(ORAL,RABBIT) 1300 MG/KG.
EPIDEMIOLOGY: NO INFORMATION AVAILABLE. TERATOGENICITY: EFFECTS ON
NEWBORN: LIVER BIRTH INDEX & VIABILIT Y INDEX, ORAL-RAT TDLO=36450
MG/KG. SPECIFIC DEVELOPMENTAL ABNORMALITIES: CENTRAL NERVOUS
SYSTEM, CRANIOFACIAL & MUSCULOSKELETAL, SUBCUTANEOUS- RAT TDLO=500
MG/KG. REPRODUCTIVE EFFECTS: NO INFORMATION AVAILABLE.
NEUROTOXICITY: NO INFORMATION AVAILABLE. MUTAGENICITY: NO
INFORMATION AVAILABLE. OTHER STUDIES: NONE.
===================== Ecological Information =====================
Ecological:ECOTOXICITY: NO INFORMATION AVAILABLE. ENVIRONMENTAL FATE:
NO INFORMATION REPORTED. PHYSICAL/CHEMICAL: NO INFORMATION
AVAILABLE. OTHER STUDIES: NONE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE AND LOCAL REGULATIONS. RCRA: D-SERIES MAXIMUM CONCENTRATION
OF CONTAMANTS; D-SERIES CHRONIC TOXICITY REFERENCE LEVELS;
F-SERIES; P-SERIES; & U-SER IES: NONE LISTED.
=================== MSDS Transport Information ===================
Transport Information:U.S. DOT: SHIPPING NAME: NO INFORMATION
AVAILABLE. IATA: SHIPPING NAME: NO INFORMATION AVAILABLE. RID/ADR:
SHIPPING NAME: NO INFORMATION AVAILABLE. IMO: SHIPPING NAME: NO
INFORMATION AVAILABLE. CANADA TDG: SHIPPING NAME: NO INFORMATION
AVAILABLE.
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302 (RQ): NONE OF THE CHEMICALS IN
THIS MATERIAL HAVE AN RQ. SECTION 302 (TPQ): NONE OF THE CHEMICALS
IN THIS PRODUCT HAVE A TPQ. SARA CODES: CAS # 119-36-8: ACUTE,
CHRONIC. SECTION 313: NO CH EMICALS ARE REPORTABLE UNDER SECTION
313.
Federal Regulatory Information:TSCA: CAS # 119-36-8 IS LISTED ON THE
TSCA INVENTORY. HEALTH & SAFETY REPORTING LIST: NONE OF THE CHEMS
ARE ON THE HEALTH & SAFETY REPORTING LIST. CHEM TEST RULES: NONE OF
THE CHEMS IN THIS PROD ARE U NDER A CHEM TEST RULE. SECTION 12B:
NONEOF THE CHEMS ARE LISTED UNDER TSCA SECTION 12B. TSCA
SIGNIFICANT NEW USE RULE: NONE OF THE CHEMS IN THIS MATL HAVE A
SNUR UNDER TSCA. CLEAN AIR ACT: THIS MATL D OES NOT CONTAIN ANY HAZ
AIR POLLUTANTS. THIS MATL DOES NOT CONTAIN ANY CLASS 1 OZONE
DEPLETORS. THIS MATL DOES NOT CONTAIN ANY CLASS 2 OZONE DEPLETORS.
CLEAN WATER ACT: NONE OF THE CHEMS IN THIS PROD ARE LISTED AS(STATE
REGULATORY INFO)
State Regulatory Information:CAS # 119-36-8 CAN BE FOUND ON THE
FOLLOWING STATE RIGHT TO KNOW LISTS: PENNSYLVANIA. CALIFORNIA NO
SIGNIFICANT RISK LEVEL: NONE OF THE CHEMICALS IN THIS PRODUCT ARE
LISTED. -- FEDERAL REGULATORY: HAZ SUBSTANCES UNDER THE CWA. NONE
OF THE CHEMS IN THIS PROD ARE LISTED AS PRIORITY POLLUTANTS UNDER
THE CWA. NONE OF THE CHEMS IN THIS PROD ARE LISTED AS TOXIC
POLLUTANTS UNDER THE CWA. OSHA: NONE OF TH E CHEMS IN THIS PROD ARE
CONSIDERED HIGHLY HAZ BY OSHA. EUROPEAN/INTERNATIONAL REGS:
EUROPEAN LABELI NG I/A/W EC DIRECTIVES: HAZ SYMBOLS: XN. RISK
PHRASES: R 22 - HARMFUL IF SWALLOWED; R 36/38 - IRRITATING TO EYES
& SKIN. SAFETY (OTHER INFO)
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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