===================== Product Identification =====================
MSDS NAME:EAT-A BUBBLE, 6101-08
NIIN:00N092892
Status Code:A
MSDS Number: CJVTX
=== Responsible Party ===
Company:CLEAR COTE CORP
Address:4242 31ST STREET NORTH
City:ST PETERSBURG
State:FL
ZIP:33174
Country:US
Info Phone Num:813-823-6230
Emergency Phone Num:813-823-6230
CAGE:0WTR8
=== Contractor Identification ===
Company:CLEAR COTE CORP
Address:4242 31ST STREET NORTH
Box:City:ST PETERSBURG
State:FL
ZIP:33174
Country:US
Phone:813-823-6230
CAGE:0WTR8
============= Composition/Information on Ingredients =============
Name:METHYL ALCOHOL
CAS:67-56-1
RTECS #:PC1400000
= Wt:100.
OSHA PEL:260 MG/M3;200 PPM
ACGIH TLV:262 MG/M3;200 PPM
ACGIH STEL:328 MG/M3;250 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL,RAT): 6200 MG/KG
Routes of Entry: Inhalation:NO Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: CONTACT WITH EYES CAUSES
IRRITATION, REDNESS AND DISCOMFORT WHICH IS TRANSIENT. CONTACT WITH
THE SKIN MAY CAUSE DRYNESS (DEFATTING), ITCHING AND/OR RASH.
PRODUCT IS ABSORBED THROUGH THE SKIN AN D MAY CAUSE NAUSEA,
HEADACHE AND GENERALDISCOMFORT. INHAL OF VAPORS MAY CAUSE CYANOSIS,
LETHARGY, LOSS OF CONSCIOUSNESS AND DEATH. INGESTION MAY CAUSE
MALAISE, DISCOMFORT, DEATH UNLESS TREATED PROMPTL Y. SIGNS AND
SYMPTOMS OF EXPOSURE (POSSIBLE LONGER TERM EFFECTS): EFFECTS FROM
INHALATION OF VAPORS MAY BE DELAYED. REPEATED AND/OR PROLONGED
EXPOSURES MAY RESULT IN: ADVERSE SKIN EFFECTS (SUCH AS DEF ATTING,
RASH, (EFTS OF OVEREXP)
Effects of Overexposure:HLTH HAZ: IRRITATION OR CORROSION), ADVERSE
EFFECTS (SUCH AS CONJUNCTIVITIS OR CORNEAL DAMAGE).
CHRONIC/SUBCHRONIC DATA: CHRONIC EXPOSURES IN TESTS ANIMALS HAS
CAUSED CHANGES IN CENTRAL NERVOUS SYSTEM , BLOOD. IRRITATION
EFFECTS DATA: MODERATE IRRITANT TO THE EYES OF A RABBIT. MODERATE
IRRITANT TO THE SKIN OF A RABBIT.
Medical Cond Aggravated by Exposure:SKIN DISORDERS AND ALLERGIES, LIVER
DISORDERS, EYE DISEASE.
======================= First Aid Measures =======================
First Aid:EYE: HOLD EYELIDS APART & IMMED FLUSH W/PLENTY OF H*2O FOR AT
LEAST 15 MIN. CALL MD: SKIN: WASH AFFECTED AREA W/SOAP & H*2O.
INHAL: MOVE PATIENT TO FRESH AIR. IF BRTHG HAS STOPPED/ IS
LABORED, GIVE A SSISTED RESP (E.G. MOUTH-TO-MOUTH). SUPP OXYGEN MAY
BE INDICATED. CALL MD. THERE HAS BEEN NO CLINICAL EXPERIENCE
W/OVEREXP VIA RESP ROUTE. INGEST: IF SWALLOWED, CALL MD IMMED.
REMOVE STOMACH CONTENTS BY GASTRIC SUCTION/INDUCE VOMIT ONLY AS
DIRECTED BY MED PERS. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERS.
MED CARE MUST EMPHASIZE CONTROL OF ACIDOSIS & USE OF INTRAVENOUS
BICARBONATE HAS BEEN LIFESAVI NG. (SUPDAT)
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:=12.C, 53.6F
Lower Limits:6%
Upper Limits:36%
Extinguishing Media:IGNITION WILL GIVE RISE TO A CLASS B FIRE. IN CASE
OF FIRE USE: WATER SPRAY, CARBON DIOXIDE (CO*2), DRY CHEMICAL,
ALCOHOL FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . RETAIN EXPENDED LIQUIDS FROM FIRE FIGHTING FOR LATER
DISPOSAL. WATER SPRAY IS ALSO USEFUL IN COOLING FIRE-EXPOSED TANKS
AND IN DISPERSING VA PORS. FIRE HAZ CLASSIFICATION (OSHA/NFPA) FLAM
LIQ, CLASS 1B.
Unusual Fire/Explosion Hazard:MAT GENERATE TOX/IRRIT COMBUSTION PROD.
SUDDEN REACTION & FIRE MAY RESULT IF PRODUCT IS MIXED WITH
OXIDIZING AGENT. VAPOR FORMS EXPLOSIVE MIXTURES WITH AIR. VAPORS
MAY TRAVEL ALONG GROUND TO A SOURCE OF IGNITION AND FLASH BACK.
VAPORS MAY COLLECT IN CLOSED SPACES SUCH AS SEWERS, CAVES OR CLOSED
STRUCTURES.
================== Accidental Release Measures ==================
Spill Release Procedures:CONTAINMENT TECHNIQUES (REMOVAL OF IGNITION
SOURCES, DIKING ETC): VENT SPACE INVOLVED. SHUT OFF/REMOVE ALL
IGNIT SOURCES. CLEAN-UP PROC: IF RECOVERY IS NOT FEASIBLE, ADMIX
W/DRY SOIL, SAND/NON-REACTIV E ABSORBENT & PLACE IN CNTNR/DUMPSTER
PENDING DISP. CLEAN-UP PERS MUST BE EQUIPPED W/SCBA & BUTYL RUB
PROT CLTHG. OTHER EMER ADVICE: VAPS TEND TO REMAIN CLOSE TO GROUND
& COLLECT (OTHER INFO)
====================== Handling and Storage ======================
Handling and Storage Precautions:STOR KEEP AWAY FROM OXIDIZERS,
HEAT/FLAMES. STORE AWAY FROM IGNIT SOURCES. GROUND ALL CNTNRS
DURING TRANSFER. ELECTRICAL INSTALLATIONS SHOULD BE I/A/W/ARTICLE
501 OF NATIONAL ELECTRICAL CODE FOR CLAS S I DIVISION 2 LOCATIONS.
KEEP CNTNRS CLSD. AVOID CONTACT W/SKIN/EYES.
Other Precautions:EMPTY CNTNRS MAY CNTN EXPLOSIVE VAPS. FLUSH EMPTY
CNTNRS W/H*2O TO REMOVE RESIDUAL FLAMM LIQ & VAPS. SMOKING IN AREA
IS PROHIBITED. SEE NFPA NO. 30, NATIONAL FIRE PROTECTION
ASSOCIATION, BOSTON, MA. R EMOVE ALL EQUIP WHICH MAY BE SOURCE OF
IGNIT FROM VICINITY WHILE HANDLING. WORK AREAS MUST BE WELL ( OTHER
INFO)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IN POORLY VENTILATED AREAS, A CARTRIDGE MASK
NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH (NIOSH)
APPROVED FOR ORGANIC VAPORS IS RECOMMENDED.
Ventilation:EXPLOSION PROOF AND GENERAL LOCAL EXHAUST WITH 12-30 AIR
CHANGES PER HOUR.
Protective Gloves:RUBBER GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . APPROPRIATE PROTECTIVE CLOTHING; LONG SLEEVE
CLOTHING.
Work Hygienic Practices:WASH AT THE END OF EACH WORKSHIFT AND BEFORE
EATING, SMOKING OR USING THE TOILET. LAUNDER OR DISCARD
CONTAMINATED CLOTHING.
Supplemental Safety and Health
FIRST AID PROC: EVID IS GOOD THAT TREATMENT OF METHANOL ABSORPTION IS
ENHANCED THROUGH ADMIN OF ETHANOL, WHICH SHOULD BE GIVEN TO PRODUCE
BLOOD LEVEL OF AT LEAST 0.1%. ETHANOL DIMINISHES PROD OF TOX
METABOLITES OF METHANOL. BLOOD METHANOL LEVEL OF 50 MG/100ML IS
INDICATION FOR HEMODIALYSIS, (OTHER INFO)
================== Physical/Chemical Properties ==================
Boiling Pt:=64.7C, 148.5F
Melt/Freeze Pt:=-97.8C, -144.F
Vapor Pres:TOXIC INFO
Vapor Density:1.11AIR=1
Spec Gravity:TOXIC INFO
pH:NEUTRAL
Viscosity:NO DATA
Evaporation Rate & Reference:12 (BUTYLACETATE =1)
Solubility in Water:TOXIC INFO
Appearance and Odor:CLEAR COLORLESS MOBILE LIQUID; MILD ALCOHOL ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALKALIS (I.E. SODIUM OR POTASSIUM HYDROXIDE ETC) OXIDIZING AGENTS (I.E.
PERCHLORATES, NITRATES ETC.)
Stability Condition to Avoid:NOT APPLICABLE.
Hazardous Decomposition Products:(FROM BURNING, HEATING OR REACTION
WITH OTHER MATERIALS) CARBON MONOXIDE IN A FIRE, CARBON DIOXIDE IN
A FIRE, WATER, ALDEHYDES, ORGANIC ACIDS VAPORS.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:ACUTE TOX EFTS DATA: DERMAL LD50(RABBIT):
16000 MG/KG. INHAL LC50 (RAT):100000 PPM/HR. PHYSICAL DATA: VP (MM
HG): 40 @ 5C, 100 @ 21C, 400 @ 50C. SOL IN H*2O: MISCIBLE IN ALL
PROPORTIONS. SPEC GRAV ( WATER =1): 0.79609 15/4C, 0.78208 30/4C.
MOLECULAR WT: 32.04. CRITICAL TEMP: 240C. SPECIFIC HEAT (LIQUID)
0.594-0.600 CAL/G @ 15-20C 0.605-0.609 CAL/G @ 25-30C. SPECIFIC
HEAT (VAPOR): 10.76 CAL/G-MOLE @ 25C 12.20 CAL/G-MOLE @ 100C. HEAT
OF VAPORIZATION: 8430 CAL/MOLE @ 64.7C. HEAT OF COMBUST OF LIQUID:
-173650 CAL/MOLE @ 25C (GROSS).
===================== Ecological Information =====================
Ecological:WASTE DISP: TO SM QTY EXCLUSION DEFINED IN 40 CFR 261.5Y(A)
& (B). HAZ WASTE NO FOR METHANOL IS U154. FED REG: EUROPEAN
ECONOMIC COMMUNITY (EEC): EINICS MASTER INVENTORY INCL ON
INVENTORY. EEC SYMBOL HARMFUL (XN): EEC COUNCIL DIRECTIVES
RELATING TO THE CLASSI, PACKAGING & LABELING OF DANGEROUS
SUBSTANCES & PREPARATION RISK(R) & SAFETY(S) PHASES FLAMM (R10).
HARMFUL BY INHAL & IF SWALLOWED (R20/22 ). IN USE, MAY FORM
FLAMM/EXPL VAPOR-AIR MIX (R18). KEEP AWAY FROM SOURCES OF IGNIT -
NO SMOKING (S16). AVOID CONT W/SKIN & EYES (S24/25). WEAR SUITABLE
PROTECTIVE CLOTHING, GLOVES AND EYE/FACE PROTEC TION (S36/37/39).
==================== Disposal Considerations ====================
Waste Disposal Methods:COMPLY W/ALL FED, STATE & LOCAL REGS. INCINERATE
IN SUITABLE COMBUST CHAMBER. INCINERATE IN AN OPEN CNTNR. DISPOSE
OF IN A PERMITTED WASTE MANAGEMENT FACILITY IF
INCINERATION/LANDFILL IS NOT PRACTICAB LE. EMVIRONMENTAL EFTS:
METHANOL IS HAZ WASTE ACCORD TO RCRA REGS (40 CFR 261.33F) SUBJECT
(ECOL IN FO)
=================== MSDS Transport Information ===================
Transport Information:DOT SHIPPING NAME: METHANOL; FLAMMABLE LIQUID; UN
1230. DOT BULK SHIPPING NAME: RQ METHYL ALCOHOL FLAMMABLE LIQUID UN
1230. IMO SHIPPING DATA: NETHANOL, CLASS 3.2 FLAMMABLE LIQUID;
SUBSIDIARY RISK: PO ISON: UN 1230; IMDG. CODE PAGE: 3251; PACKAGING
GROUP II. IACO/IATA SHIPPING DATA: METHANOL, CLASS 3 FLAMMABLE
LIQUID; UN 1230; SUBSIDIARY RISK: POISON; PACKAGING GROUP II.
===================== Regulatory Information =====================
SARA Title III Information:EPA SARA TITLE III SECTION 312 (40CFR 370)
HAZARD CLASS: IMMEDIATE HEALTH HAZARD. FIRE HAZARD. EPA SATA TITLE
III SECTION 313 (40 CFR 372) TOXIC CHEMICALS ABOVE "DEMINIMIS"
LEVEL ARE 67-56-1 METHYL AL COHOL.
Federal Regulatory Information:TOXIC SUBSTANCES CONTROL ACT (TSCA): ALL
COMPONENTS ARE INCLUDED IN THE EPA TOXIC SUBSTANCES CONTROL ACT
(TSCA) CHEMICAL SUBSTANCE INVENTORY. OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200) HAZA RD CLASS(ES) FLAMMABLE. TOXIC BY
INHALATION AND INGESTION. INTERNATIONAL REGULATIONS: CANADIAN: DS -
INCLUDED ON INVENTORY. WHMIS HAZARD CLASSIFICATION: CLASS B
DIVISION 2. CLASS D DIVISION 1B. WHMIS TRADE SECRET REGISTRY
NUMBER(S): NONE. WHMIS HAZARD INGREDIENTS: INCLUDED IN SECTION 2.
WHMIS SYMBOL S: FLAMES, STYLIZED T. (ECOLOGICAL INFO)
State Regulatory Information:PROPOSITION 65 SUBSTANCE(S) LISTED BY THE
STATE OF CALIFORNIA UNDER THE "SAFE DRINKING WATER AND TOXIC
ENFORCEMENT ACT OF 1986": NONE. NEW JERSEY TRADE SECRET REGISTRY
NUMBER(S): NONE.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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