===================== Product Identification =====================
MSDS NAME:MAPS REGENERATION BUFFER 5X, 9700776
NIIN:00N092877
Status Code:A
MSDS Number: CJVVP
=== Responsible Party ===
Company:BIO-RAD LABORATORIES, LIFE SCIENCE RESEARCH
Address:2000 ALFRED NOBEL DRIVE
City:HERCULES
State:CA
ZIP:94547
Country:US
Info Phone Num:510-741-1000
Emergency Phone Num:800-424-9300 (CHEMTREC)
Chemtrec Ind/Phone:(800)424-9300
CAGE:0UCZ8
=== Contractor Identification ===
Company:BIO-RAD LABORATORIES, LIFE SCIENCE RESEARCH
Address:2000 ALFRED NOBEL DRIVE
Box:City:HERCULES
State:CA
ZIP:94547
Country:US
Phone:510-741-1000
CAGE:0UCZ8
============= Composition/Information on Ingredients =============
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:50.
Maxumum % Wt:100.
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
Name:METHANOL
CAS:67-56-1
RTECS #:PC1400000
Minumum % Wt:35.
Maxumum % Wt:50.
Other REC Limits:N/K
OSHA PEL:260 MG/M3;200 PPM
OSHA STEL:N/K
ACGIH TLV:262 MG/M3;200 PPM
ACGIH STEL:328 MG/M3;250 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:NON-HAZARDOUS ADDITIONS
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT): 13000 MG/KG (METHANOL)
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: SKIN: NO IRRITANT EFFECT. EYES:
NO IRRITANT EFFECT. SENSITIZATION: NO SENSITIZING EFFECTS KNOWN.
THE PRODUCT SHOWS THE FOLLOWING DANGERS ACCORDING TO THE
CALCULATION METHOD OF THE GENERAL EU CL ASSIFICATION GUIDELINES FOR
PREPARATIONS AS ISSUED IN THE LATEST VERSION: POISONOUS.
Effects of Overexposure:SEE HEALTH HAZARDS.
======================= First Aid Measures =======================
First Aid:GENERAL INFORMATION: IMMEDIATELY REMOVE ANY CLOTHING SOILED
BY THE PRODUCT. REMOVE BREATHING APPARATUS ONLY AFTER CONTAMINATED
CLOTHING HAVE BEEN COMPLETELY REMOVED. IN CASE OF IRREGULAR
BREATHING/RES PIRATORY ARREST PROVIDE ARTIFICIAL RESPIRATION.
INHALATION: SUPPLY FRESH AIR/OXYGEN; CALL FOR DOCTOR. IN CASE OF
UNCONSCIOUSNESS PLACE PATIENT STABLY IN SIDE POSITION FOR
TRANSPORTATION. SKIN: IMMEDIA TELY WASH WITH WATER & SOAP & RINSE
THOROUGHLY. IMMEDIATELY RINSE WITH WATER. EYES: RINSE OPENE EYE FOR
AT LEAST 15 MINUTES UNDER RUNNING WATER. THEN CONSULT A DOCTOR.
INGESTION: DO NOT INDUCE VOMITIN G; IMMEDIATELY CALL FOR MEDICAL
HELP.
===================== Fire Fighting Measures =====================
Flash Point:<21.C, 69.8F
Autoignition Temp:=455.C, 851.F
Lower Limits:5.5%
Upper Limits:44.0%
Extinguishing Media:CARBON DIOXIDE, EXTINGUISHING POWDER OR WATER
SPRAY. FIGHT LARGER FIRES WITH WATER SPRAY OR ALCOHOL RESISTANT
FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:PRODUCT IS NOT SELF-IGNITING. PRODUCT
DOES NOT PRESENT AN EXPLOSION HAZARD.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED
PERSONS AWAY. PREVENT SEEPAGE INTO SEWAGE SYSTEM, WORKPITS &
CELLARS. DILUTE WITH PLENTY OF WATER. DO NOT ALLOW TO ENTER
SEWERS/SURFACES OR GROUND WATER. AB SORB WITH LIQUID-BINDING
MATERIAL (SAND, DIATOMITE, ACID BINDERS, UNIVERSAL ABINDERS,
SAWDUST). DISPOSE CONTAMINATED MATERIAL AS WASTE ACCORDING TO WASTE
DISPOSAL SECTION. ENSURE ADEQUATE VENTILATION.
====================== Handling and Storage ======================
Handling and Storage Precautions:ENSURE GOOD VENTILATION/EXHAUSTION AT
THE WORKPLACE. OPEN AND HANDLE RECEPTACLE WITH CARE. NO SPECIAL
PRECAUTIONS ARE NECESSARY IF USED CORRECTLY. KEEP IGNITION SOURCES
AWAY - DO NOT SMOKE. PROTECT AG AINST ELECTROSTATIC CHARGES. KEEP
NIOSH APPROVED RESPIRATORY PROTECTIVE DEVICE AVAILABLE.
Other Precautions:STORE IN A COOL LOCATION. KEEP RECEPTACLE TIGHTLY
SEALED. STORE IN COOL, DRY CONDITIONS IN WELL-SEALED RECEPTACLES.
CLASS ACCORDING TO REGULATION ON FLAMMABLE LIQUIDS: B.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IN CASE OF BRIEF EXPOSURE OR LOW POLLUTION, USE
NIOSH APPROVED RESPIRATORY FILTER DEVICE. IN CASE OF INTENSIVE OR
LONGER EXPOSURE, USE NIOSH APPROVED RESPIRATORY PROTECTIVE DEVICE
THAT IS INDEPENDENT OF CIRCULATING AIR.
Protective Gloves:PROTECTIVE GLOVES. SYNTHETIC GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA .
Work Hygienic Practices:KEEP AWAY FROM FOODSTUFFS, BEVERAGES AND FEED.
IMMEDIATELY REMOVE ALL SOILED AND CONTAMINATED CLOTHING. WASH HANDS
BEFORE BREAKS AND AT THE END OF WORK. STORE PROTECTIVE CLOTHING
SEPARATELY.
Supplemental Safety and Health
PHYSICAL/CHEMICAL PROPERTIES: DENSITY: 0.904 G/CM3 @ 20C; ORGANIC
SOLVENTS: 40.0%; WATER: 60.0%. TRANSPORTATION INFORMATION: PACKING
GROUP: II; PROPER SHIPPING NAME: METHANOL (METHYL ALCOHOL), SOLUTIO
N.
================== Physical/Chemical Properties ==================
Boiling Pt:=64.C, 147.2F
Vapor Pres:128.0 HPA @ 20C
Solubility in Water:FULLY MISCIBLE
Appearance and Odor:COLORLESS FLUID WITH CHARACTERISTIC ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NO DANGEROUS REACTIONS KNOWN.
Stability Condition to Avoid:NO DECOMPOSITION IF USED ACCORDING TO
SPECIFICATIONS.
Hazardous Decomposition Products:NO DANGEROUS DECOMPOSITION PRODUCTS
KNOWN.
===================== Ecological Information =====================
Ecological:GENERAL NOTES: WATER HAZARD CLASS 1 (GERMAN REGULATION)
(SELF-ASSESSMENT): SLIGHTLY HAZARDOUS FOR WATER. DO NOT ALLOW
UNDILUTED PRODUCT OR LARGE QUANTITIES OF IT TO REACH GROUND WATER,
WATER COURSE OR SEWAGE SYSTEM.
==================== Disposal Considerations ====================
Waste Disposal Methods:MUST NOT BE DISPOSED OF TOGETHER WITH HOUSEHOLD
GARBAGE. DO NOT ALLOW PRODUCT TO REACH SEWAGE SYSTEM. HAND OVER TO
HAZARDOUS WASTE DISPOSERS. DISPOSAL MUST BE MADE ACCORDING TO
OFFICIAL REGULATIONS. R ECOMMENDED CLEANSING AGENT: WATER, IF
NECESSARY WITH CLEANSING AGENTS. DISPOSE OF IN ACCORDANCE WITH
LOCAL, STATE, AND FEDERAL REGULATIONS .
=================== MSDS Transport Information ===================
Transport Information:DOT REGS: HAZ CLASS: 3; IDENTIFICATION #: UN1230;
PACKING GROUP: II; PROPER SHIPPING NAME (TECHNICAL NAME): METHANOL
(METHYL ALCOHOL), SOLUTION; REMARKS: ERG 131. LAND TRANSPORT
ADR/RID (CROSS-BORDER) : ADR/RID CLASS: 3 FLAMM LIQS; ITEM: 17B;
DANGER CODE (KEMLER): 336; UN #: 230; LABEL: 3+6.1; DESCRIPTION OF
GOODS: METHANOL (METHYL ALCOHOL), SOLUTION. MATITIME TRANSPORT
IMDG: IMDG CLASS: 3.2; PAGE: 3251; UN #: 1230; PACKING GROUP: II;
EMS #: 3-06; MFAG: 306; MARINE POLLUTANT: NO; PROPER SHIPPING NAME:
METHANOL (METHYL ALCOHOL), SOLUTION. AIR TRANSPORT ICAO-TI &
IATA-DGR: ICAO/IATA CLASS: 3; UN/ ID #: 1230; (SUP DAT)
===================== Regulatory Information =====================
SARA Title III Information:SARA (SUPERFUND AMENDMENTS AND
REAUTHORIZATION ACT OF 1986 - USA) SECTION 302/304 (40 CFR 35.30/40
CFR 355.40): NONE OF THE INGREDIENTS IS LISTED. SECTION 313 (40 CFR
372.65): 67-56-1 METHANOL.
Federal Regulatory Information:TSCA (TOX SUBSTANCES CTL ACT): 7732-18-5
WATER; 67-56-1 METHANOL. MARKINGS ACCORDING TO EU GUIDELINES: THE
PROD HAS BEEN CLASSIFIED & MARKED I/A/W EU DIRECTIVES/ORDINANCE ON
HAZ MATLS. CODE LETTER & H AZ DESIGNATION OF PROD: T TOX; F HIGHLY
FLAMM. HAZ-DETERMINING COMPONENTS OF LABELLING: METHANOL. RISK
PHRASES: 11 - HIGHLY FLAMM. 23/25 - TOX BY INHAL & IF SWALLOWED.
SFTY PHRASES: 4 - KEEP AWAY FROM LIVING QUARTERS. 7/9 KEEP CONTR
TIGHTLY CLSD & IN WELL-VENTILATED PLACE. 16 KEEP AWAY FROM SOURCES
OF IGNIT - NO SMKNG. 36/37/39 - IN CASE OF ACCIDENT/IF YOU FEEL
UNWELL, SEEK MED ADVICE IMMED. (OTHER INFO)
State Regulatory Information:CALIFORNIA PROPOSITION 65: CHEMICALS KNOWN
TO CAUSE CANCER: THE PRODUCT DOES NOT CONTAIN LISTED COMPONENTS.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY: THE PRODUCT DOES
NOT CONTAIN LISTED COMPONEN TS.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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