===================== Product Identification =====================
MSDS NAME:SODIUM SULFIDE, S426212
NIIN:00N092909
Status Code:A
MSDS Number: CJVVR
=== Responsible Party ===
Company:FISHER SCIENTIFIC
Address:ONE REAGENT LANE
City:FAIRLAWN
State:NJ
ZIP:07410
Country:US
Info Phone Num:201-796-7100
Emergency Phone Num:201-796-7100
Chemtrec Ind/Phone:(800)424-9300
CAGE:1B464
=== Contractor Identification ===
Company:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464
============= Composition/Information on Ingredients =============
Name:SODIUM SULFIDE EINECS/ELINCS: 215-211-5.
CAS:1313-82-2
RTECS #:WE1905000
Minumum % Wt:60.
Maxumum % Wt:62.
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
Name:WATER; (WATER OF CRYSTALLIZATION) EINECS/ELINCS:
231-791-2.
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:38.
Maxumum % Wt:40.
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE TOXICOLOGICAL INFORMATION.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: CAUSES EYE BURNS. MAY
CAUSE IRREVERSIBLE EYE INJURY. MAY CAUSE BLINDNESS. SKIN: MAY BE
ABSORBED THROUGH THE SKIN IN HARMFUL AMOUNTS. PROLONGED AND/OR
REPEATED CONTACT MAY CAUSE IRRITATION AND/OR DERMATITIS. CONTACT
WITH SKIN CAUSES IRRITATION AND POSSIBLE BURNS, ESPECIALLY IF THE
SKIN IS WET OR MOIST. INGESTION: MAY CAUSE CARDIAC DISTURBANCES.
CAUSES DIGESTIVE TRACT BURNS WITH IMMEDIA TE PAIN, SWELLING OF THE
THROAT, CONVULSIONS, AND POSSIBLE COMA. MAY CAUSE DIZZINESS,
DROWSINESS, CONFUSION, WEAKNESS, IRREGULAR BREATHING, AND
UNCONSCIOUSNESS. (EFFECTS OF OVEREXPOSURE)
Explanation of Carcinogenicity:NOT LISTED BY ACGIH, IARC, NIOSH, NTP,
OR OSHA.
Effects of Overexposure:EFFECTS OF OVEREXPOSURE: CONTACT WITH STOMACH
ACIDS CAN LIBERATE TOXIC HYDROGEN SULFIDE GAS. INHALATION: MAY
CAUSE SEVERE IRRITATION OF THE RESPIRATORY TRACT WITH SORE THROAT,
COUGHING, SHORTNESS OF B REATH AND DELAYED LUNG EDEMA. MAY CAUSE
EFFECTS SIMILAR TO THOSE DESCRIBED FOR INGESTION. CHRONIC: NOT
AVAILABLE.
======================= First Aid Measures =======================
Eyes: IMMED FLUSH EYES W/PLENTY OF WATER FOR AT LST 15 MINS,
OCCASIONALLY LIFTING UPPER & LOWER LIDS. GET MEDICAL AID IMMED.
SKIN: GET MEDICAL AID IMMED. IMMED FLUSH SKIN W/PLENTY OF SOAP &
WATER FOR AT LST 15 MINS WHILE REMOVING CONTAM CLTHG & SHOES.
DESTROY CONTAM SHOES. INGEST: DO NOT INDUCE VOMITING. IF VICTIM IS
CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. NEVER GIVE
ANYTHING BY MOUTH T O UNCON PERS. GET MED AID IMMED. INHAL: GET MED
AID IMMED. REMOVE FROM EXPOSURE TO FRESH AIR IMMED. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. NOTES TO MD: TREAT SYMPTOMATICALLY & SUPPORTIVELY.
===================== Fire Fighting Measures =====================
Extinguishing Media:FOR SMALL FIRES, USE DRY CHEMICAL, CARBON DIOXIDE,
WATER SPRAY OR ALCOHOL-RESISTANT FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NFPA RATING: NOT PUBLISHED.
================== Accidental Release Measures ==================
Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS
INDICATED IN CONTROL MEASURES SECTION. VACUUM OR SWEEP UP MATERIAL
AND PLACE INTO A SUITABLE DISPOSAL CONTAINER. AVOID GENERATING
DUSTY CONDITIONS.
====================== Handling and Storage ======================
Handling and Storage Precautions:USE ONLY IN A WELL-VENTILATED AREA. DO
NOT GET IN EYES, ON SKIN, OR ON CLOTHING. KEEP CONTAINER TIGHTLY
CLOSED. AVOID CONTACT WITH HEAT, SPARKS AND FLAME. DO NOT INGEST OR
INHALE. STORE IN A COOL, DRY PLACE. STORE IN A TIGHTLY CLOSED
CONTAINER. KEEP FROM CONTACT WITH OXIDIZING MATERIALS.
Other Precautions:KEEP AWAY FROM STRONG ACIDS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR
EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY.
Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP
AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS.
Protective Gloves:WEAR APPROPRIATE GLOVES. WEAR IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES AND FULL LENGTH
FACESHIELD .
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING TO MINIMIZE
CONTACT WITH SKIN.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. WASH HANDS
BEFORE EATING.
Supplemental Safety and Health
MOLECULAR FORMULA: MIXT; PH: ALKALINE IN SOLN. EMER OVERVIEW: APPEAR:
WHITE TO YELLOW WHITE. DANGER! CORR. HYGROSCOPIC. MAY CAUSE CNS
EFTS. MAY CAUSE CARD DISTURBS. PRLNG EXPOS MAY CAUSE PULM EDEMA. C
AUSES EYE & SKIN BURNS. CAUSES DIGESTIVE & RESP TRACT BURNS. TARGET
ORGANS: CNS, CARDIOVASCULAR SYS.
================== Physical/Chemical Properties ==================
Boiling Pt:=174.4C, 346.F
Melt/Freeze Pt:=91.7C, 197.F
Spec Gravity:1.858
pH:SUP DAT
Solubility in Water:15% @ 20C
Appearance and Odor:WHITE TO YELLOW WHITE SOLID; ROTTEN EGG-LIKE, WEAK
ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS, OXIDIZING AGENTS, CARBON, M-CHLOROANILINE, DIAZONIUM SALT,
4-CHLORO-O-TOLUIDINE, DIAZONIUM CHLORIDE SALT, DIAZONIUM SALTS AND
DIAZONIUM CHLORIDE SALTS, DIAZONIUM SALTS, N,N-DICHLOROMETHANE
AMINE, O-NITROANILINE, DIAZ
Stability Condition to Avoid:STABLE AT ROOM TEMPERATURE IN CLOSED
CONTAINERS UNDER NORMAL STORAGE AND HANDLING CONDITIONS. AVOID
INCOMPATIBLE MATERIALS, LIGHT, EXPOSURE TO AIR.
Hazardous Decomposition Products:OXIDES OF SULFUR, HYDROGEN SULFIDE.
=================== Toxicological Information ===================
Toxicological Information:RTECS # CAS # 1313-82-2: WE1905000; CAS #
7732-18-5: ZC110000. LD50/LC50: CAS # 1313-82-2: LD50 (ORAL, MOUSE)
= 205 MG/KG; LD50 (ORAL, RAT) = 208 MG/KG. CAS # 7732-18-5: LD50
(ORAL, RAT) = >90 ML/KG. EPIDEMIOLOGY, TERATOGENICITY,
REPRODUCTIVE EFFECTS, NEUROTOXICITY, MUTAGENICITY, OTHER STUDIES:
NO DATA AVAILABLE.
===================== Ecological Information =====================
Ecological:ECOTOXICITY: NOT AVAILABLE. ENVIRONMENTAL FATE: NOT
AVAILABLE. PHYSICAL/CHEMICAL: NOT AVAILABLE. OTHER: NOT AVAILABLE.
--OTHER INFORMATION: WGK (WATER DANGER/PROTECTION): CAS #
1313-82-2: 2; CAS # 773 2-18-5: NO INFORMATION AVAILABLE. CANADA:
CAS # 1313-82-2 IS LISTED ON CANADA'S DSL/NDSL LIST. CAS #
7732-18-5 IS LISTED ON CANADA'S DSL/NDSL LIST. THIS PRODUCT HAS A
WHMIS CLASSIFICATION OF D1B, E. C AS # 1313-82-2 IS NOT LISTED ON
CANADA'S INGREDIENT DISCLOSURE LIST. CAS # 7732-18-5 IS NOT LISTED
ON CANADA'S INGREDIENT DISCLOSURE LIST.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE, AND LOCAL REGULATIONS. RCRA D-SERIES MAXIMUM CONCENTRATION
OF CONTAMINANTS: NONE LISTED. RCRA D-SERIES CHRONIC TOXICITY
REFERENCE LEVELS: NONE LI STED. RCRA F-SERIES: NONE LISTED. RCRA
P-SERIES: NONE LISTED. RCRA U-SERIES: NONE LISTED.
=================== MSDS Transport Information ===================
Transport Information:US DOT: SHIPPING NAME: SODIUM SULFIDE, HYDRATED;
HAZARD CLASS: 8; UN NUMBER: UN1849; PACKING GROUP: II. IATA,
RID/ADR, IMO: NO INFORMATION AVAILABLE. CANADA TDG: SHIPPING NAME:
SODIUM SULFIDE 60%; HAZ ARD CLASS: 8; UN NUMBER: UN1849; PACKING
GROUP: II; ADDITIONAL INFORMATION: LOAD SEPARATE FROM ACIDS.
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302 (RQ): NONE OF THE CHEMICALS IN
THIS MATERIAL HAVE AN RQ. SECTION 302 (TPQ): NONE OF THE CHEMICALS
IN THIS PRODUCT HAVE A TPQ. SARA CODES: CAS # 1313-82-2: ACUTE,
REACTIVE. SECTION 313: NO CHEMICALS ARE REPORTABLE UNDER SECTION
313.
Federal Regulatory Information:TSCA:BOTH INGS LISTED ON TSCA INVENTORY.
HLTH & SFTY REPORTING LIST: NONE OF CHEMS ARE ON HLTH & SFTY
REPORTING LIST. CHEM TEST RULES: NONE OF CHEMS IN PROD ARE UNDER
CHEM TEST RULE. SECTION 12B: NONE OF CHEMS ARE LISTED UNDER TSCA
SECTION 12B. TSCA SIGNIFICANT NEW USE RULE: NONE OF CHEMS IN MATL
HAVE SNUR UNDER TSCA. CLEAN AIR ACT: THIS MATL DOES NOT CONTAIN ANY
HAZ AIR POLLUTANTS, ANY CLASS 1 OZ ONE DEPLETORS/ANY CLASS 2 OZONE
DEPLETORS. CLEAN WATER ACT: NONE OF CHEMS IN PROD ARE LISTED AS HAZ
SUBSTANCES UNDER CWA, AS PRIORITY POLLUTANTS UNDER CWA/AS TOX
POLLUTANTS UNDER CWA. (OTHER INFO)
State Regulatory Information:CAS # 1313-82-2 CAN BE FOUND ON THE
FOLLOWING STATE RIGHT-TO-KNOW LISTS: NEW JERSEY, MASSACHUSETTS. CAS
# 7732-18-5 IS NOT PRESENT ON STATE LISTS FROM CA, PA, MN, MA, FL,
OR NJ. CALIFORNIA NO SIGNIFIC ANT RISK LEVEL: NONE OF THE CHEMICALS
IN THIS PRODUCT ARE LISTED.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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